The Determination of Organic Peroxides

The Determination of Organic Peroxides

Monographs in Organic Functional Group Analysis

1st Edition - January 1, 1970

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  • Authors: R. M. Johnson, I. W. Siddiqi
  • eBook ISBN: 9781483160191

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Monographs in Organic Functional Group Analysis, Volume 4: The Determination of Organic Peroxides focuses on the analytical chemistry of organic peroxides. The monograph first offers information on the compositions, properties, and reactions of lipid peroxides, polymers, and petrochemicals. The text then reviews the iodometric methods, including choice of solvents, reaction conditions, and titration with thiosulfate. The ferrous ion methods are also discussed. Considerations include choice of reagents and solvents and titration with titanous, dichromate, and mercurous ions. The book also focuses on titrimetric methods, including arsenious, stannous, and titanous methods, titration with anions, and sulfides and mercaptans. Numerical representations are provided. The text puts emphasis on colorimetric and polarographic methods. Polarographic techniques for peroxides; nature and concentration of peroxides; leuco base of methylene blue; and ferrous ions are described. The book also discusses paper, thin-layer, and gas chromatography. The monograph is an important guide for readers interested in the analytical chemistry of organic peroxides.

Table of Contents

  • Contents


    1. Introduction

    1. Lipid Peroxides

    2. Polymers

    3. Petrochemicals

    4. Irradiation

    5. Miscellaneous


    2. Structure and Reactivity

    1. Classification of Peroxides

    2. Reactivity


    3. Iodometric Methods

    1. General Comments

    2. Choice of Solvent

    3. Reaction Conditions

    4. Titration with Thiosulphate


    4. Ferrous Ion Methods

    1. Introduction

    2. Choice of Reagent

    3. Choice of Solvent

    4. Titration with Titanous Ions

    5. Titration with Dichromate Ions

    6. Titration with Mercurous Ions


    5 . Futher Titrimetric Reagents

    1. Introduction

    2. Arsenious Methods

    3. Stannous Methods

    4. Titanous Methods

    5. Titration with Anions

    6. Sulphides and Mercaptans


    6 . Colorimetric Methods

    1. Introduction

    2. Ferrous Ions

    3. Leuco Base of Methylene Blue

    4. Iodine

    5. N, N'-Dimethyl-p-Phenylenediamine

    6. Other Colorimetric Reagents


    7. Polarographic Methods

    1. Introduction

    2. Electrode Reaction

    3. Polarographic Techniques For Peroxides

    4. Nature And Concentration of Peroxide

    5. Solvents And Supporting Electrolytes


    8. Spectroscopic Techniques

    1. Introduction

    2. Ultraviolet And Visible Absorption

    3. Infrared Absorption

    4. Raman Spectroscopy


    9. Chromatographic Methods. (A) Column Chromatography

    1. Introduction

    2. Column Techniques

    3. Solvent Medium

    4. Stationary Phase

    5. Type of Peroxide


    10. Chromatographic Methods. (B) Paper Chromatography

    1. Introduction

    2. Choice Of Paper

    3. Mobile Phase

    4. General Techniques

    5. Chemical Structure

    6. Detection

    7. Class of Peroxide


    11. Chromatographic Methods. (C) Thin-Layer Chromatography

    1. Introduction

    2. Adsorbents

    3. Solvent Systems

    4. Detection

    5. Techniques

    6. Applications


    12. Chromatographic Methods. (D) Gas Chromatography

    1. Introduction

    2. Solid Support

    3. Stationary Phase

    4. Column Temperature

    5. Functional Groups

    6. Quantitative Analysis


    13. Choice of Method

    1. Introduction

    2. Concentration of Peroxide

    3. Reactivity of Peroxide

    4. Nature of The Sample


Product details

  • No. of pages: 130
  • Language: English
  • Copyright: © Pergamon 1970
  • Published: January 1, 1970
  • Imprint: Pergamon
  • eBook ISBN: 9781483160191

About the Authors

R. M. Johnson

I. W. Siddiqi

About the Editors

R. Belcher

D. M. W. Anderson

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