Organometallic Syntheses
Nontransition-Metal Compounds
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Nontransition-Metal Compounds is the second volume in the series Organometallic Syntheses and presents various procedures for the nontransition-metal compounds. Topics also covered in this volume include sensitive liquids, sample transfer, and inert atmosphere provision. The text is divided into two major parts. Part I is mostly procedural as it offers directions and suggestions in different processes such as (a) establishment of an inert atmosphere and solvent medium; (b) evaluation of purity, mode of mixing, and solvent type; and (c) isolation and purification of reaction products. Organometallic products, particularly its physical and chemical characteristics, are also tackled. In Part II, around 85 nontransition-metal organometallic compounds and the reliable procedures used for their synthesis are presented. This particular volume will be of help to students both in the fields of chemistry and biology.
Table of Contents
Foreword
Preface
Part I General Experimental Techniques in the Organometallic Chemistry of Nontransition Metals
A. Establishment of Anhydrous and Anaerobic Reaction Media
1. General Reactivity Considerations for σ-Bonded Organometallics
2. Inert Gases
3. Inert Solvents
4. Drying and Deoxygenating the Reaction Zone
5. Storage and Transfer of Organometallic Compounds
B. Execution of Organometallic Reactions
1. Purity of Reagents
2. State of Subdivision
3. Solvent
4. Mode of Admixing
5. Temperature Control
6. Catalysts and Promoters
7. Precipitation and Filtration
8. Gas Evolution
9. Monitoring the Course of Reaction
C. Purification of Organometallic Products
1. Consideration of Thermal and Light Instability
2. Complex Formation
3. Extraction
4. Chromatography
5. Recrystallization
6. Distillation
D. Characterization of Organometallic Compounds
1. Physical Properties
2. Elemental Analysis
3. Molecular Weight
4. Hydrolysis and Other Carbon-Metal Bond Cleavages
5. Spectroscopy
?. Safety Measures
1. General Precautions
2. Toxicity Dangers
3. Fire Hazards
4. Explosions
Part II Specific Preparations of Nontransition-Metal Organometallic Compounds
A. Introduction
1. Criteria Governing the Choice of Procedures
2. General Procedural Observations
B. Compounds of Group IA
1. General Preparative and Analytical Methods
2. Allyllithium
3. p-Bromophenyllithium
4. Benzyllithium
5. Phenoxymethyllithium
6. Diphenylmethyllithium
7. Triphenylmethyllithium
8. (E,E)-1,2,3,4-Tetraphenyl-1,3-butadien-1,4-ylidenedilithium
C. Compounds of Group IIA
1. General Preparative and Analytical Methods
2. α-Deuteriovinylmagnesium Chloride
3. Allylmagnesium Bromide
4. Diallylmagnesium
5. 3-(1-Bromomagnesiooxy-1-cyclohexyl)-propylmagnesium Bromide
6. (E)-2-Phenyl-1-phenylsulfonylvinyllithium and (E)-2-Phenyl-1-phenylsulfonylvinylmagnesium Bromide
D. Compounds of Group IIB
1. General Preparative and Analytical Methods
2. Ethylzinc Halide
3. Diethylzinc
4. Di-1-alkynylmercury
5. Bis(trimethylsily)mercury
6. Phenylmercuric Bromide
7. Diphenylmercury
8. Bis[(E)-stilbenyl]mercury and Bis[(Z)-stilbenyl]mercury
E. Compounds of Group IIIA
1. General Preparative and Analytical Methods
2. 1-Methyl-4,5-dihydroborepin and 1-Chloro-4,5-dihydroborepin
3. Phenylborane-Triethylamine
4. Phenylboron Dibromide and Diphenylboron Bromide
5. 1-Phenylboracyclopentane
6. Triphenylborane
7. Diphenyl(phenylethynyl)borane-Pyridine
8. Pentaphenylborole
9. Heptaphenyl-7-borabicyclo[2.2.1]heptadiene
10. Heptaphenylborepin
11. Salts of the Bis(2,2'-biphenylene)borate Anion
12. Diisobutylaluminum Deuteride
13. Diisobutyl[(Z)-1-trimethylsilyl-2-phenylethenyl]aluminum
14. Diphenylaluminum Chloride and Phenylaluminum Dichloride
15. Triphenylaluminum
16. Diphenyl(phenylethynyl)aluminum
17. Tribenzylaluminum
18. Diethylgallium Chloride
19. Diethylgallium Ethoxide
20. Triethylgallium
21. Triisobutylgallium
22. Triphenylgallium
23. Tri-n-decylgallium
24. Diethylindium Chloride
25. Triethylindium
26. Triisobutylindium
27. Triphenylindium
28. Thallium(I) Cyclopentadienide
29. Diphenylthallium Halide
30. Triphenylthallium
F. Compounds of Group IVA
1. General Preparative and Analytical Methods
2. 1,1-Dimethyl-2,5-dihydrobenzo[c]silole
3. Trimethyl(phenylethynyl)silane
4. Trimethyl(cis-β-styryl)silane and Trimethyl(trans-?-styryl)silane
5. Triphenylsilylpotassium and Triphenylsilyllithium
6. Hexaphenyldisilane
7. 1,4-Bis(triphenylsilyl)butane
8. Bromo(triphenyl)germane and Chloro(triphenyl)germane
9. Triphenyl(vinyl)germane
10. Tetraphenylgermane
11. Hexamethylditin
12. Di-n-butyltin Dihydride
13. Trimethyl(phenylethynyl)tin
14. Tri-n-butyl(iodomethyl)tin
15. 1,1-Di-n-butyl-4,5-dihydrostannepin
16. Chloro(triphenyl)tin and Dichloro(diphenyl)tin
17. Triphenyltin Hydride
18. Tri-n-butyl(phenoxymethyl)tin
19. Allyl(triphenyl)tin and Diallyl(diphenyl)tin
20. Triphenyl(trans-β-styryl)tin
21. 1,1-Dimethyl-2,3,4,5-tetraphenylstannole
22. Halo(triphenyl)lead and Dihalo(diphenyl)lead
23. Allyl(triphenyl)lead
24. Tetraphenyllead
Appendix I. Bibliography of Compilations on Organometallic Chemistry
Appendix II. Suppliers of Reagents for Organometallic Chemistry
Appendix III. Special Solvents for Organometallic Reagents
Appendix IV. Periodic Table of the Main-Group Elements
Index of Compounds
Product details
- No. of pages: 208
- Language: English
- Copyright: © Academic Press 1981
- Published: August 28, 1981
- Imprint: Academic Press
- eBook ISBN: 9780323160179