Determination of Organic Structures by Physical Methods V5
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Determination of Organic Structures by Physical Methods, Volume 5 is a seven-chapter text that discusses the improvements of some established physical methods for organic structure determination. Each chapter of this book examines specific physical method, including electron diffraction, spin saturation labeling, chemically and electro-magnetically induced dynamic nuclear polarization, ion cyclotron resonance spectroscopy, nuclear quadrupole resonance, Mössbauer spectroscopy, and automated analysis systems. The historical developments, principles, instrumentation, and applications to organic chemistry of these methods are discussed. This work will be of value to organic and analytical chemists and researchers.
Table of Contents
List of Contributors
Preface
Contents of Other Volumes
1. Electron Diffraction
I. Introduction
II. Instrumentation
III. Theory and Analysis
IV. Reading an Electron Diffraction Paper
V. Regularity of Bond Lengths
VI. Single Bonds
VII. Single and Double Bonds
VIII. Conjugated Systems
IX. Triple Bonds
X. Conformers
XI. A Variety of Topics
XII. Conclusions
References
2. Spin Saturation Labeling
I. Introduction
II. Theory
III. Applications and Examples
IV. Measurement Techniques
V. Sources of Error
VI. Practical Aspects
References
3. Chemically and Electromagnetically Induced Dynamic Nuclear Polarization
I. Introduction
II. Overhauser and Related Effects
III. Chemically Induced Dynamic Nuclear Polarization (CIDNP)
References
4. Ion Cyclotron Resonance Spectroscopy
I. Basic Principles of Ion Detection
II. The Ion Cyclotron Double Resonance Technique for Studying Ion-Molecule Reactions
III. Interpretation of the Double Resonance Experiment
IV. Applications
V. Thermochemical Quantities
VI. Proton Transfer Reactions. Double Resonance Spectra
VII. Acidities from Proton Transfer
VIII. Reaction Pathways
IX. Structures of Ions
X. Concluding Remarks
References
5. Nuclear Quadrupole Resonance in Organic and Metalloorganic Chemistry
I. Introduction
II. Distribution and Assignment of Frequencies in the Spectral Bandwidth
III. The Nature of the Chemical Bond
IV. The Correlation of NQR Frequencies of the Type RX, RZX, and RR'R"MX with Substituent Inductive Constants and with Chemical and Physical Properties
V. Transmission of Electronic Effects Across Saturated Carbon and Heteroatomic Systems
VI. Electronic Effects of Alkyl Groups
VII. Alicyclic Compounds
VIII. Aromatic Systems
IX. Araliphatic Compounds
X. Heterocyclic Compounds
XI. Phosphorus Compounds
XII. Sulfur Compounds
XIII. Intra- and Intermolecular Coordination in Metalloorganic Compounds
XIV. Molecular Complexes
XV. Polymeric Compounds
XVI. Some Other Areas of Application of the NQR Method
XVII. Conclusion
References
6. Mössbauer Spectra of Organometallics
I. Theory
II. Applications
References
7. Automated Chemical Structure Analysis Systems
I. Introduction
II. Structure Determination of Alkanes with Monomethyl Side Chain
III. Structure Determination of Oligopeptides
IV. Structure Determination of Aliphatic Ketones
V. Structure Determination of Aliphatic Ethers
VI. Construction of Molecular Structure from Suitable Fragments
References
Appendix to Chapter 5. Newest Reports on NQR Applications in Organic and Metalloorganic Chemistry
Text
References
Author Index
Subject Index
Product details
- No. of pages: 384
- Language: English
- Copyright: © Academic Press 1973
- Published: January 1, 1973
- Imprint: Academic Press
- eBook ISBN: 9780323152846
About the Editor
F.C. Nachod
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