Determination of Organic Structures by Physical Methods V5

Determination of Organic Structures by Physical Methods V5

1st Edition - January 1, 1973

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  • Editor: F.C. Nachod
  • eBook ISBN: 9780323152846

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Determination of Organic Structures by Physical Methods, Volume 5 is a seven-chapter text that discusses the improvements of some established physical methods for organic structure determination. Each chapter of this book examines specific physical method, including electron diffraction, spin saturation labeling, chemically and electro-magnetically induced dynamic nuclear polarization, ion cyclotron resonance spectroscopy, nuclear quadrupole resonance, Mössbauer spectroscopy, and automated analysis systems. The historical developments, principles, instrumentation, and applications to organic chemistry of these methods are discussed. This work will be of value to organic and analytical chemists and researchers.

Table of Contents

  • List of Contributors


    Contents of Other Volumes

    1. Electron Diffraction

    I. Introduction

    II. Instrumentation

    III. Theory and Analysis

    IV. Reading an Electron Diffraction Paper

    V. Regularity of Bond Lengths

    VI. Single Bonds

    VII. Single and Double Bonds

    VIII. Conjugated Systems

    IX. Triple Bonds

    X. Conformers

    XI. A Variety of Topics

    XII. Conclusions


    2. Spin Saturation Labeling

    I. Introduction

    II. Theory

    III. Applications and Examples

    IV. Measurement Techniques

    V. Sources of Error

    VI. Practical Aspects


    3. Chemically and Electromagnetically Induced Dynamic Nuclear Polarization

    I. Introduction

    II. Overhauser and Related Effects

    III. Chemically Induced Dynamic Nuclear Polarization (CIDNP)


    4. Ion Cyclotron Resonance Spectroscopy

    I. Basic Principles of Ion Detection

    II. The Ion Cyclotron Double Resonance Technique for Studying Ion-Molecule Reactions

    III. Interpretation of the Double Resonance Experiment

    IV. Applications

    V. Thermochemical Quantities

    VI. Proton Transfer Reactions. Double Resonance Spectra

    VII. Acidities from Proton Transfer

    VIII. Reaction Pathways

    IX. Structures of Ions

    X. Concluding Remarks


    5. Nuclear Quadrupole Resonance in Organic and Metalloorganic Chemistry

    I. Introduction

    II. Distribution and Assignment of Frequencies in the Spectral Bandwidth

    III. The Nature of the Chemical Bond

    IV. The Correlation of NQR Frequencies of the Type RX, RZX, and RR'R"MX with Substituent Inductive Constants and with Chemical and Physical Properties

    V. Transmission of Electronic Effects Across Saturated Carbon and Heteroatomic Systems

    VI. Electronic Effects of Alkyl Groups

    VII. Alicyclic Compounds

    VIII. Aromatic Systems

    IX. Araliphatic Compounds

    X. Heterocyclic Compounds

    XI. Phosphorus Compounds

    XII. Sulfur Compounds

    XIII. Intra- and Intermolecular Coordination in Metalloorganic Compounds

    XIV. Molecular Complexes

    XV. Polymeric Compounds

    XVI. Some Other Areas of Application of the NQR Method

    XVII. Conclusion


    6. Mössbauer Spectra of Organometallics

    I. Theory

    II. Applications


    7. Automated Chemical Structure Analysis Systems

    I. Introduction

    II. Structure Determination of Alkanes with Monomethyl Side Chain

    III. Structure Determination of Oligopeptides

    IV. Structure Determination of Aliphatic Ketones

    V. Structure Determination of Aliphatic Ethers

    VI. Construction of Molecular Structure from Suitable Fragments


    Appendix to Chapter 5. Newest Reports on NQR Applications in Organic and Metalloorganic Chemistry



    Author Index

    Subject Index

Product details

  • No. of pages: 384
  • Language: English
  • Copyright: © Academic Press 1973
  • Published: January 1, 1973
  • Imprint: Academic Press
  • eBook ISBN: 9780323152846

About the Editor

F.C. Nachod

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