Thermodynamic and Transport Properties of Organic Salts - 1st Edition - ISBN: 9780080223780, 9781483152318

Thermodynamic and Transport Properties of Organic Salts

1st Edition

International Union of Pure and Applied Chemistry

Authors: Paolo Franzosini Manlio Sanesi
eBook ISBN: 9781483152318
Imprint: Pergamon
Published Date: 1st January 1980
Page Count: 380
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Thermodynamic and Transport Properties of Organic Salts is concerned with the thermodynamic and transport properties of organic salts, namely, pure salts, mixtures, and solutions. The transport properties of pure molten salts and binary mixtures of molten salts with organic ions are given, along with the transport properties of organic salts in aqueous solutions. This book is divided into three sections and opens with a discussion on the statistical treatment and of computer simulation methods for molten salts as well as their results for pressure-volume-temperature (PVT) data. The PVT data for organic molten salts determined experimentally are considered, and the thermal properties as well as the melting mechanism of pure salts are described. A method by which PVT data at high pressure can be estimated from those at low pressure with sufficiently high accuracy is also outlined. The next section deals with salt mixtures, their phase diagrams, and their transport properties. The final section looks at the transport properties of organic salts in aqueous solutions; thermodynamic quantities of micelle formation; and formation of lyotropic liquid crystals by organic salts. Two appendixes showing the structure of the pure solids and the use of the melts in electrochemical studies are included. This monograph will be a useful resource for organic chemists.

Table of Contents

Commission on Thermodynamics





Part 1-Pure Salts

Chapter 1.1-PVT Relationships

Chapter 1.2—Thermal Properties

Chapter 1.3—Melting Mechanism of Pure Salts

Chapter 1.4—Transport Properties of Pure Molten Salts with Organic Ions

Part 2-Salt Mixtures

Chapter 2.1—Phase Diagrams

Chapter 2.2—Transport Properties of Binary Mixtures of Molten Salts with Organic Ions

Part 3-Solutions

Chapter 3.1—Transport Properties of Organic Salts in Aqueous Solutions

Chapter 3.2—Thermodynamic Quantities of Micelle Formation

Chapter 3.3—Formation of Lyotropic Liquid Crystals by Organic Salts


Appendix 1—Aspects of the Structure of Pure Solid Organic Salts

Appendix 2—Electrochemical Studies in Molten Organic Salts


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About the Author

Paolo Franzosini

Manlio Sanesi

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