The Organic Chemistry of Nickel

The Organic Chemistry of Nickel

Organic Synthesis

1st Edition - January 1, 1975

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  • Author: P.W. Jolly
  • eBook ISBN: 9780323151306

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Description

The Organic Chemistry of Nickel, Volume II: Organic Synthesis describes the chemistry of the organonickel complexes and the use of nickel in organic synthesis. Composed of six chapters, this volume starts with discussions on the oligomerization, co-oligomerization, and polymerization of olefins, followed by short accounts of the mechanistically related isomerization and hydrogenation of olefins, as well as the hydrosilylation and hydrocyanation reactions. Chapter II examines the oligomerization of acetylene and substituted alkynes, the co-oligomerization of alkynes with olefins, the related oligomerization of allene, including a number of telomerization reactions involving alkynes or allenes. Chapters III and IV describe the oligomerization, co-oligomerization, and polymerization of butadiene and substituted 1,3-dienes. Chapter V explores the coupling of organic halides in the presence of stoichiometric amounts of zerovalent nickel complexes, and the nickel-catalyzed cross-coupling reaction between organic halides and Grignard reagents. Lastly, Chapter VI emphasizes the carbonylation of alkynes, olefins, and organic halides using nickel complexes. This book will be of great value to organic chemists and researchers who are interested in the application of nickel complexes to organic synthesis.

Table of Contents


  • Preface

    Introduction

    Contents of Volume l

    Chapter I. The Oligomerization of Olefins and Related Reactions

    I. Introduction

    II. The Nickel Effect

    III. The Oligomerization and Co-oligomerization of Olefins

    IV. The Oligomerization of Strained Olefins and Alkanes

    V. The Polymerization of Olefins

    VI. The Isomerization of Olefins

    VII. The Hydrogenation of Olefins

    VIII. The Hydrosilylation and Hydrocyanation of Olefins

    References

    Patents

    Reviews

    Chapter II. The Oligomerization of Alkynes and Related Reactions

    I. Introduction

    II. The Oligomerization of Alkynes

    III. The Co-oligomerization of Alkynes with Olefins

    IV. The Hydrosilylation of Alkynes

    V. The Oligomerization of 1,2-Dienes

    VI. The Co-oligomerization of 1,2-Dienes with Alkynes and Olefins

    VII. The Telomerization of Aliène

    References

    Patents

    Reviews

    Chapter III. The Oligomerization and Co-oligomerization of Butadiene and Substituted 1,3-Dienes

    I. Introduction

    II. The Cyclotrimerization of 1,3-Dienes

    III. The Cyclodimerization of 1,3-Dienes

    IV. The Preparation of Macrocyclic Polyenes

    V. The Co-oligomerization of 1,3-Dienes with Olefins and Alkynes

    VI. The Linear Oligomerization and Telomerization of 1,3-Dienes

    References

    Patents

    Reviews

    Chapter IV. The Polymerization of Butadiene and Related Reactions

    I. Introduction

    II. The Polymerization of Butadiene

    III. The Polymerization of Isoprene and Related Dienes

    IV. Copolymerization

    References

    Patents

    Chapter V. Coupling Reactions and Related Processes

    I. Introduction

    II. The Coupling of Organic Halides and Related Reactions

    III. The Reaction of Organic Halides with Grignard Reagents

    References

    Patents

    Chapter VI. Carbonylation and Related Reactions

    I. Introduction

    II. The Carbonylation of Alkynes, Olefins, Alcohols, and Related Compounds

    III. The Carbonylation of Organic Halides and Related Compounds

    IV. Decarbonylation

    V. Isonitrile Insertion

    References

    Patents

    Reviews

    Subject Index

    Catalyst Index

Product details

  • No. of pages: 416
  • Language: English
  • Copyright: © Academic Press 1975
  • Published: January 1, 1975
  • Imprint: Academic Press
  • eBook ISBN: 9780323151306

About the Author

P.W. Jolly

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