The Organic Chemistry of Nickel

Organic Synthesis

1st Edition - January 1, 1975
Author: P.W. Jolly
Language: English
eBook ISBN:
9 7 8 - 0 - 3 2 3 - 1 5 1 3 0 - 6

The Organic Chemistry of Nickel, Volume II: Organic Synthesis describes the chemistry of the organonickel complexes and the use of nickel in organic synthesis. Composed of six… Read more

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The Organic Chemistry of Nickel, Volume II: Organic Synthesis describes the chemistry of the organonickel complexes and the use of nickel in organic synthesis. Composed of six chapters, this volume starts with discussions on the oligomerization, co-oligomerization, and polymerization of olefins, followed by short accounts of the mechanistically related isomerization and hydrogenation of olefins, as well as the hydrosilylation and hydrocyanation reactions. Chapter II examines the oligomerization of acetylene and substituted alkynes, the co-oligomerization of alkynes with olefins, the related oligomerization of allene, including a number of telomerization reactions involving alkynes or allenes. Chapters III and IV describe the oligomerization, co-oligomerization, and polymerization of butadiene and substituted 1,3-dienes. Chapter V explores the coupling of organic halides in the presence of stoichiometric amounts of zerovalent nickel complexes, and the nickel-catalyzed cross-coupling reaction between organic halides and Grignard reagents. Lastly, Chapter VI emphasizes the carbonylation of alkynes, olefins, and organic halides using nickel complexes. This book will be of great value to organic chemists and researchers who are interested in the application of nickel complexes to organic synthesis.

Preface Introduction Contents of Volume l Chapter I. The Oligomerization of Olefins and Related Reactions I. Introduction II. The Nickel Effect III. The Oligomerization and Co-oligomerization of Olefins IV. The Oligomerization of Strained Olefins and Alkanes V. The Polymerization of Olefins VI. The Isomerization of Olefins VII. The Hydrogenation of Olefins VIII. The Hydrosilylation and Hydrocyanation of Olefins References Patents Reviews Chapter II. The Oligomerization of Alkynes and Related Reactions I. Introduction II. The Oligomerization of Alkynes III. The Co-oligomerization of Alkynes with Olefins IV. The Hydrosilylation of Alkynes V. The Oligomerization of 1,2-Dienes VI. The Co-oligomerization of 1,2-Dienes with Alkynes and Olefins VII. The Telomerization of Aliène References Patents Reviews Chapter III. The Oligomerization and Co-oligomerization of Butadiene and Substituted 1,3-Dienes I. Introduction II. The Cyclotrimerization of 1,3-Dienes III. The Cyclodimerization of 1,3-Dienes IV. The Preparation of Macrocyclic Polyenes V. The Co-oligomerization of 1,3-Dienes with Olefins and Alkynes VI. The Linear Oligomerization and Telomerization of 1,3-Dienes References Patents Reviews Chapter IV. The Polymerization of Butadiene and Related Reactions I. Introduction II. The Polymerization of Butadiene III. The Polymerization of Isoprene and Related Dienes IV. Copolymerization References Patents Chapter V. Coupling Reactions and Related Processes I. Introduction II. The Coupling of Organic Halides and Related Reactions III. The Reaction of Organic Halides with Grignard Reagents References Patents Chapter VI. Carbonylation and Related Reactions I. Introduction II. The Carbonylation of Alkynes, Olefins, Alcohols, and Related Compounds III. The Carbonylation of Organic Halides and Related Compounds IV. Decarbonylation V. Isonitrile Insertion References Patents Reviews Subject Index Catalyst Index