The Chemistry of Nonaqueous Solvents VB

The Chemistry of Nonaqueous Solvents VB

Acid and Aprotic Solvents

1st Edition - April 28, 1978

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  • Editor: J.J. Lagowski
  • eBook ISBN: 9780323153324

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The Chemistry of Nonaqueous Solvents, Volume V: Acidic and Aprotic Solvents, Part B covers the theoretical aspects of individual solvents in nonaqueous solution chemistry. This volume is divided into five chapters. The first two chapters discuss the purification, structure, physical properties, electrochemistry, solubilities, and reactions of specific solvents, including trifluoroacetic and halosulfuric acids. Chapter 3 deals briefly with the preparations and properties of the interhalogens, principally in the liquid state. This chapter emphasizes their uses as nonaqueous solvents, especially through extensive study of their acid-base reactions. Spectroscopic data and their contribution to the understanding of their solution chemistries are also considered. Chapter 4 surveys the autoionization, purification methods, solubilities, solvolytic reactions, conductivity, conductometric, potentiometric, spectrophotometric, and visual titrations, as well as the isolation of solid complexes in inorganic halides and oxyhalides. Chapter 5 describes the solubility, reactivity, and spectroscopic data of molten salts. This book is of value to analytical chemists, and analytical chemistry teachers and students.

Table of Contents

  • List of Contributors


    Contents of Other Volumes

    1. Trifluoroacetic Acid

    I. Introduction

    II. Solvent Purification

    III. Physical Properties and Solvent Structure

    IV. Electrochemistry

    V. Solubilities

    VI. Reactions in Trifluoroacetic Acid


    2. Halosulfuric Acids

    I. Fluorosulfuric Acid

    II. Chlorosulfuric Acid


    3. The Interhalogens

    I. Introduction

    II. Preparations and Problems of Purity

    III. Physical Properties

    IV. Chemical Properties—Halogenation

    V. Solvent Properties

    VI. Spectroscopic and Structural Studies of Some Halogen Fluorides


    4. Inorganic Halides and Oxyhalides as Solvents

    I. Introduction

    II. Antimony Halides

    III. Arsenic Halides

    IV. Nitrosyl and Nitryl Halides

    V. Phosphoryl and Thiophosphoryl Halides

    VI. Seleninyl Chloride

    VII. Sulfur Halides and Oxyhalides

    VIII. Tin(IV) Chloride


    5. Molten Salts as Nonaqueous Solvents

    I. Introduction

    II. Halide Melts

    III. Nitrate Melts

    IV. Conclusions


    Author Index

    Subject Index

Product details

  • No. of pages: 378
  • Language: English
  • Copyright: © Academic Press 1978
  • Published: April 28, 1978
  • Imprint: Academic Press
  • eBook ISBN: 9780323153324

About the Editor

J.J. Lagowski

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