Rheology. Concepts, Methods, and Applications

2nd Edition

Authors: Alexander Ya. Malkin Avraam I. Isayev
Hardcover ISBN: 9781895198492
eBook ISBN: 9781895198812
Imprint: ChemTec Publishing
Published Date: 15th September 2011
Page Count: 528

Institutional Access


The pursuit of the golden balance between oversimplification and overload with theory has always been the primary goal of every author of book on rheology. Rheology. Concepts, Methods, and Applications, 2nd Ed. is a tool for chemists and chemical engineers to solve many practical problems. They have to learn what to measure, how to measure, and what to do with the data. But, the learning process should not take users away from their major goals, such as manufacturing quality products, developing new materials, analysis of material durability.

In the book various aspects of theoretical rheology as well as methods of measurement and raw data treatment and how to use rheological methods in different groups of products are discusses.

The authors share their experiences of many years of experimental studies and teaching to show use of rheology in studies of materials. They and were very meticulous in giving historical background of contributors to rheology as a science and as the method of solving many practical problems.

This book is very useful as a teaching tool in universities and colleges because it is consistent with programs of rheology courses. Practicality of this book will prepare students for typical tasks in industry. Equally it serves the industry and accomplished rheologists because it contains expert advice of two very famous and accomplished scientists and teachers who know discoveries first-hand because they may have taken part in some of them.

Key Features

  • introductory rheology for students and scientists
  • easy to understand
  • many practical examples


Students of material science, chemical engineering, chemistry, biology, medicine;

Scientists in polymer, plastics, pharmaceutical, construction, coatings industries and medicine

Table of Contents


Introduction. Rheology: Subject and Goals

1 Continuum Mechanics as a Foundation of Rheology

1.1 Stresses

1.1.1 General theory

1.1.2 Law of equality of conjugated stresses

1.1.3 Principal stresses

1.1.4 Invariants of a stress tensor

1.1.5 Hydrostatic pressure - spherical tensor and deviator

1.1.6 Equilibrium (balance) equations

1.2 Deformations

1.2.1 Deformations and displacements Deformations Displacements

1.2.2 Infinitesimal deformations: principal values and invariants

1.2.3 Large (finite) deformations

1.2.4 Special cases of deformations - uniaxial elongation and simple shear Uniaxial elongation and Poisson's ratio Simple shear and pure shear

1.3 Kinematics of deformations

1.3.1 Rates of deformation and vorticity

1.3.2 Deformation rates when deformations are large

1.4 Summary - continuum mechanics in rheology

1.4.1 General principles

1.4.2 Objects of continuum as tensors


Questions for Chapter 1

2 Viscoelasticity

2.1 Basic experiments

2.1.1 Creep (retarded deformation)

2.1.2 Relaxation

2.1.3 Fading memory

2.2 Relaxation and creep - spectral representation. Dynamic functions

2.2.1 Retardation and relaxation spectra - definitions

2.2.2 Dynamic functions

2.3 Model interpretations

2.3.1 Basic mechanical models

2.3.2 Complicated mechanical models - differential rheological equations

2.3.3 Non-mechanical models

2.4 Superposition - The Boltzmann-Volterra principle

2.4.1 Integral formulation of the superposition principle

2.4.2 Superposition principle expressed via spectra

2.4.3 Simple transient modes of deformation Relaxation after sudden deformation


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About the Author

Alexander Ya. Malkin

Prof. Dr. Alexander Yakovelich Malkin is the Principal Research Fellow at the Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow. He has written five monographs and more than 100 papers in English, including three books on the subject of rheology. He has also taken part as an invited plenary or keynote speaker at numerous international conferences and meetings on rheology, polymer processing and physics.

Affiliations and Expertise

Principal Research Fellow, Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia

Avraam I. Isayev

Prof. Dr. Avraam I. Isayev is a Distinguished Professor Emeritus in the Department of Polymer Engineering at the University of Akron, USA. He has been a member of the Society of Rheology since 1981, and a Senior Member of the Society of Plastics Engineers since 1984. His interests include polymer processing, rheology of polymers, and the injection, co-injection, transfer, compression and gas-assisted injection molding of polymers.

Affiliations and Expertise

Distinguished Professor Emeritus, Department of Polymer Engineering, University of Akron, USA