Polymer Syntheses V2 - 1st Edition - ISBN: 9780126185027, 9780323151405

Polymer Syntheses V2

1st Edition

Authors: Stanley Sandler
eBook ISBN: 9780323151405
Imprint: Academic Press
Published Date: 28th September 1977
Page Count: 414
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Description

Polymer Syntheses, Volume II presents detailed laboratory instructions for the preparation of different types of polymers. This book provides information pertinent to useful polymer synthesis.

Organized into 10 chapters, this volume begins with an overview of resins derived from urea, melamine, or benzoguanamine. This text then examines the reaction of formaldehyde with hydrogen chloride, which has been shown to lead to the spontaneous production of carcinogen bis(chloromethyl) ether. Other chapters consider the topic of silicone resins or polyorganosiloxanes, as well as the uses of vinyl ether polymers in lacquer resins, adhesives, plasticizers, paints, and copolymer compositions. This book discusses as well the methods of polymerization of acrylic and of methacrylic acid. The final chapter deals with the health and safety aspects of the production of the monomer vinyl chloride.

This book is a valuable resource for industrial and polymer chemists. Students of polymer chemistry will also find this book useful.

Table of Contents


Preface

Contents of Volume I

Chapter 1. Urea, Melamine, Benzoguanamine-Aldehyde Resins (Amino Resins or Aminoplasts)

1. Introduction

2. Urea-Aldehyde Condensations

3. Melamine-Aldehyde Condensations

4. Benzoguanamine-Aldehyde Condensations

5. Miscellaneous Preparations

References

Chapter 2. Phenol-Aldehyde Condensations

1. Introduction

2. Condensation of Phenol with Aldehydes

3. Miscellaneous Preparations and Applications

References

Chapter 3. Epoxy Resins

1. Introduction

2. Condensation-Elimination Reactions

3. Oxidation Reactions

4. Free Radical Reactions

5. Curing-Polymerization Reactions of Epoxy Compounds and Resins

6. Miscellaneous Methods

References

Chapter 4. Silicone Resins (Polyorganosiloxanes or Silicones)

1. Introduction

2. Polyorganosiloxanes

3. Miscellaneous Silicone Resin Preparations and Compositions

References

Chapter 5. Alkyd Resins

1. Introduction

2. Unmodified Alkyds

3. Modified Alkyds

4. Alkyds Modified with Vinyl Monomers

5. Alkyds Modified with Other Thermosetting Resins

6. Miscellaneous Alkyd Preparations

References

Chapter 6. Polyacetals and Poly(vinyl acetals)

1. Introduction

2. Polyacetals from Formaldehyde

3. Polyacetals from Substituted Aldehydes

4. Polyacetals with Other Functional Groups

5. Polyketals

6. Polythioacetals and Polythioketals

7. Poly(vinyl acetals)

8. Miscellaneous Preparations

References

Chapter 7. Poly (vinyl ethers)

1. Introduction

2. Cationic Polymerization

3. Free-Radical Polymerization

4. Coordination-Catalyzed Polymerization

5. Miscellaneous Methods and Preparations

References

Chapter 8. Poly(N-vinylpyrrolidone)

1. Nomenclature and Molecular Weight Relationships

2. Introductory Remarks

3. Polymerization Procedures

4. Miscellaneous Preparations

References

Chapter 9. Polymerization of Acrylic Acids and Related Compounds

1. Introduction

2. Polymer Preparations

3. Polymerization of Itaconic Acid

4. Polymerization of Salts of the Acrylic Acids

5. Miscellaneous Preparations

References

Chapter 10. Poly(vinyl chloride)

1. Introduction

2. Bulk Polymerization

3. Suspension Polymerization

4. Emulsion Polymerization

5. Solution Polymerization

6. Radiation-Initiated Polymerization

7. Polymerization with Organometallic Initiators

8. Miscellaneous

References

Author Index

Subject Index

Details

No. of pages:
414
Language:
English
Copyright:
© Academic Press 1977
Published:
Imprint:
Academic Press
eBook ISBN:
9780323151405

About the Author

Stanley Sandler