Oxidation in Organic Chemistry 5-C - 1st Edition - ISBN: 9780126972528, 9780323152433

Oxidation in Organic Chemistry 5-C

1st Edition

Editors: Walter Trahanovsky
eBook ISBN: 9780323152433
Imprint: Academic Press
Published Date: 28th January 1978
Page Count: 394
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Description

Organic Chemistry, A Series of Monographs, Volume 5-C: Oxidation in Organic Chemistry covers the preparative use and the mechanistic aspects of the various oxidation reactions. This book contains five chapters that particularly consider oxidations that involve organoselenium intermediates. Chapter I describes the developments of selenium in organic chemistry, particularly the organoselenium reagents for performing selective oxidative transformations under unusually mild conditions. Chapter II deals with the problems encountered in oxygenation reactions carried out by several microorganisms, with an emphasis on a variety of fermentation techniques. Chapter III examines the oxidation of various organic peroxy acids and other peroxides, while Chapter IV discusses the oxidation with nitric acid or nitrogen oxides. Chapter V focuses on the properties of various oxidants and their application to hypohalite oxidation. This text will be of value to organic chemists, researchers, teachers, and students who are interested in oxidation of organic compounds.

Table of Contents


Contributors

Preface

Contents of Part A and Part Β

Chapter I Organoselenium Oxidations

I. Introduction

II. Oxidation-Reduction Reactions of Organoselenium Compounds

III. The Selenoxide syn Elimination as a Double Bond Forming Reaction

IV. Sigmatropic Rearrangements of Organoselenium Compounds

V. Organoselenium Intermediates in Selenium Dioxide Oxidations and Related Reactions

VI. Miscellaneous Selenium-Based Transformations

Chapter II Oxygenations with Microorganisms

I. Introduction

II. Methods

III. Oxygenation at Nonactivated Carbon

IV. Oxygenation at Allylic Carbon

V. Oxygenation of Olefins

VI. Oxygenation of Aromatic Rings

Chapter III Oxidations with Peroxy Acids and Other Peroxides

I. Introduction

II. Reagents

III. Oxidation of Carbon-Carbon Double and Triple Bonds

IV. Oxidation of Organic Carbonyl Compounds

V. Oxidation of Organic Nitrogen Compounds

VI. Oxidation of Organic Sulfur Compounds

VII. Oxidation of Organic Iodine Compounds

VIII. Oxidation of Allylic and Other Activated Carbon-Hydrogen Bonds with Peroxy Esters

Chapter IV Oxidations with Nitric Acid or Nitrogen Oxides

I. Introduction

II. Alkanes and Arylalkanes

III. Carbon-Carbon Multiple Bonds

IV. Alcohols and Ethers

V. Alkyl Halides

VI. Aldehydes

VII. Ketones

VIII. Organonitrogen Compounds

IX. Organosulfur Compounds

Chapter V Alkaline Hypohalite Oxidations

I. Introduction

II. The Chemical Nature of the Oxidant

III. The Haloform Reaction

IV. Oxidation of Methyl and Methylene Groups

V. Oxidation of Saturated Carbocyclic Compounds

VI. Ruthenium-Catalyzed Oxidation of Carbocyclic Compounds

VII. Reaction with Other Active Hydrogen Compounds

VIII. Cleavage of Aromatic Rings

Index




Details

No. of pages:
394
Language:
English
Copyright:
© Academic Press 1978
Published:
Imprint:
Academic Press
eBook ISBN:
9780323152433

About the Editor

Walter Trahanovsky