Organosilicon Chemistry - 1st Edition - ISBN: 9780080208077, 9781483284460

Organosilicon Chemistry

1st Edition

Special Lectures Presented at the International Symposium on Organosilicon Chemistry

Authors: Sam Stuart
eBook ISBN: 9781483284460
Imprint: Butterworth-Heinemann
Published Date: 1st January 1966
Page Count: 338
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Organosilicon Chemistry provides information pertinent to the fundamental aspects and application of organosilicon chemistry. This book discusses the exact manner and extent of d-orbital involvement in organosilicon compounds in ground, electronic, and transition excited states. Organized into two parts encompassing 21 chapters, this book begins with an overview of preparing stable organosiliconium ions. This text then discusses the use of fused salts as reaction media in the preparative chemistry. Other chapters consider a detailed investigation on the molecular association and volatility of alkoxides of group (IV) elements. This book discusses as well the reaction between dimethyldichlorosilane and ethylene glycon, which has been shown to produce a dimeric ten-membered ring compound. The final chapter deals with the results of the investigations concerning the properties of the contact mass and of the non-volatile silicon-free products, which are produced in the direct synthesis of phenylhalogenosilanes. This book is a valuable resource for chemists and research workers.

Table of Contents

Special Lectures


Plenary Lectures

Recent Advances on Two Classical Problems of Organosilicon Chemistry

Analogien Und Unterschiede Zwischen Organometallischen Verbindungen Des Siliziums, Germaniums Und Zins

Silatranes : Intra-Complex Heterocyclic Compounds of Pentacordinated Silicon

Sur Quelques Aspects de la Reactivite des Hydrogenosilanes en Chimie Organique

Über Einige Heterocyclische Ringsysteme der Silicium Chemie

Main Lectures

Preparation of Organosilicon Halides in Molten Salts As Reaction Media

Spreading Behaviour and Acidolysis of the Siloxane Linkage as Varying with the Donor-Acceptor Properties of the Organic Substituents

Synthesis and Properties of Alkoxy- and Acyloxysilanes

Silane Addition Reactions—Their Synthetic Utility and Mechanism

Hydrosilation in the Synthesis of Organosilanes

Steric Effects and Π-Bonding in Organosilicon Chemistry: Their Assessment by Means of Comparative Organic Chemistry of Carbon and Silicon

Recent Researches On Organopolysilanes

Structural Chemistry of Si-H Compounds

Neue Spektroskopische Untersuchungen Von Bindungen in Organosiliciumverbindungen

Reactions and Rearrangements of Carbon-Functional Organosilicon Compounds

Problems of Bond Utilization of Silicon D-Orbitals

Polymeric Methylsilazanes

Novel Ways in the Preparation of Cyclic Silicon-Nitrogen Compounds

Bildung Und Eigenschaften Von Garbosilanen

The Radiation Chemistry of Silicon Compounds

Direct Synthesis of Organohalogenosilanes


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© Butterworth-Heinemann 1966
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About the Author

Sam Stuart

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