Organophosphorus Monomers and Polymers

Organophosphorus Monomers and Polymers

International Series of Monographs on Organic Chemistry

1st Edition - January 1, 1962

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  • Author: Ye. L. Gefter
  • eBook ISBN: 9781483164069

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Description

Organophosphorus Monomers and Polymers is the first attempt at a generalization and systemization of existent knowledge of the methods of synthesis and the basic properties of monomers and polymers of organophosphorus compounds, and also of their fields of application. It contains valuable reference material, collated in tables (physical constants of the monomers, properties of the polymers and copolymers, etc.). The literature used by the author has covered journals, patents and books up to 1958, and in some cases more recent results are included. The monomers and polymers are tabulated according to the particular class of phosphorus-containing compounds to which they belong: acids of phosphorus, their derivatives, phosphines, polymers and co-polymers of unsaturated esters of acids of phosphorus, etc. Groups of monofunctional unsaturated phosphorus-containing compounds (acids, acid chlorides, amides, etc.) are listed in the order of: (a) the distance of the multiple bonds from the phosphorus atom, and (b) the number of multiple bonds. Within each group, the unsaturated substances are listed from simple to complex according to the rules laid down in The Chemist's Handbook. The book is intended for scientists, research workers, engineers, and technologists working on the preparation, manipulation, and investigation of monomers and high molecular weight compounds, and also for students studying related branches of chemistry.

Table of Contents


  • Preface

    Introduction

    Section 1. Starting Materials for the Preparation of High Molecular Weight Organophosphorus Compounds

    Chapter I. Unsaturated Organophosphorus Compounds

    Unsaturated Organophosphorus Acids (Phosphonous, Phosphonic and Phosphonothionic) and Their Derivatives

    Esters of Acids of Phosphorus and Unsaturated Alcohols

    A Discussion of Some Reactions Which Lead to the Formation of Vinyl Esters of Acids of Phosphorus

    The Properties of Unsaturated Esters of Acids of Phosphorus

    Unsaturated Phosphines, Their Oxides and Sulphides, Tetrachlorophosphoranes and Phosphonium Salts

    Chapter II. Saturated Organophosphorus Compounds. Di-Hydroxy-Compounds

    Di-Acid Chlorides of Some Saturated Acids of Phosphorus

    Some Compounds Containing Two Hydroxyl-Groups (Difunctional Alcohols and Phenols)

    Di- and Tri-Carboxylic Acids (And Their Esters) Containing Phosphinyl Groups Phosphorus-Containing Di- and Tri-Isocyanates

    Tetrakis-(Hydroxymethyl)Phosphonium Chloride (THPC) and Tris-(Hydroxymethyl) Phosphine Oxide (THPO)

    Tetrakis-(Hydroxymethyl)Phosphonium Chloride P(CH2OH)4CI (THPC) Dialkyl Hydrogen Phosphites

    Dimethyl Hydrogen Phosphite HPO(OCH3)2

    Cyclic Esters of Some Acids of Phosphorus (Cyclic Esters of Phosphorous, Pyrophosphorous, Phosphoramidous, Phosphorodithious, Phosphorotrithious, Phosphoric, Phosphorothionic, Phosphoramidothionic and Alkyl- and Arylphosphonic Acids)

    Saturated Diesters of Alkyl- and Aryl-Phosphonic Acids

    Amides of Acids of Phosphorus (Di- and Tri-Amides, Mono-, Di- and Tri-Ethylenimides of Phosphorous, Phosphoric, Phosphoramidic, Phosphorothionic, Phosphoramidothionic, And Alkyl- and Aryl-Phosphonic Acids)

    The Ethylenimide of Dipropyl Phosphoric Acid

    Phosphonitrilic Chlorides

    Chapter III. Kefractivities of Certain Atomic Groups in Organophosphorus Compounds

    Section 2 High Molecular Weight Organophosphorus Compounds

    Chapter IV. Carbon-Chain and Hetero-Chain High Molecular Weight Compounds Containing Phosphorus in the Side Chains

    Polymers and Copolymers of Unsaturated Esters of Acids of Phosphorus

    Polymers and Copolymers of Allyl Esters of Acids of Phosphorus

    Polymers and Copolymers of Other Unsaturated Esters of Acids of Phosphorus

    Tables of Polymers and Copolymers of Unsaturated Esters of Acids of Phosphorus

    Polymers and Copolymers of Amides, Amido-Esters and Ethylenimides of Acids of Phosphorus

    Carbochain Products From the Polycondensation of Organophosphorus Compounds

    High Molecular Weight Organophosphorus Compounds Synthesized By the Reaction of Organic Polymers With Phosphorus Containing Compounds

    Chapter V. Heterochain High Molecular Weight Compounds Containing Phosphorus in the Main Chain

    High Molecular Weight Compounds Containing Phosphorus and Carbon in the Main Chain

    High Molecular Weight Compounds Containing Phosphorus, Oxygen and Carbon in the Main Chain (Phosphorus-Containing Polyesters)

    Polyesters Based On Phosphonic Acids

    High Molecular Weight Compounds Containing Phosphorus, Nitrogen and Other Elements in the Main Chain. Polyamides and Polyurethanes Containing Phosphorus

    Polyphosphonitrilic Halides and Their Derivatives

    The Preparation of the Mixture of Trimeric and Tetrameric Phosphonitrilic Chloride

    High Molecular Weight Compounds Based Ontetrakis-(Hydroxymethyl) Phosphonium Chloride (THPC) and Tris-(Hydroxymethyl) Phosphine Oxide (THPO)

    High Molecular Weight Phosphorus-Containing Compounds With Inorganic Skeletons (Besides Polyamides, Polyphosphonitrilic Halides and Their Derivatives)

    High Molecular Weight Compounds Containing Only Phosphorus in the Main Chain

    High Molecular Weight Compounds Containing Phosphorus and Nitrogen in the Main Chain

    High Molecular Weight Compounds Containing Phosphorus, Boron and (Sometimes) Nitrogen in the Main Chain

    High Molecular Weight Compounds Containing Phosphorus Oxygen in the Main Chain (Polyphosphates, Polyphosphoric Acids and Their Derivatives)

    High Molecular Weight Compounds Containing Phosphorus, Oxygen and A Third Element in the Main Chain (Silicon, Nitrogen, Boron, Arsenic and Titanium)

    Chapter VI. Other Organophosphorus Polymers

    Products From Telomerization Reactions Involving Organophosphorus Compounds

    High Molecular Weight Organophosphorus Compounds of Unknown Structure

    Chapter VII. Uses of High Molecular Weight Phosphorus Containing Compounds

    Artificial Glass

    Paints and Lacquers

    Films and Fibers

    Plasticizers

    Glues

    Substances for Increasing the Flame-Resistance of Fibers, Synthetic Resins and Plastics

    The Flame-Proofing of Cotton Articles

    Ion-Exchange Resins and Detergents

    Catalysts for Chemical Reactions

    Lubricant Additives

    Other Fields of Application of High Molecular Weight Organophosphorus Compounds

    Preferences

    List of Tables

    Subject Index Preface




Product details

  • No. of pages: 310
  • Language: English
  • Copyright: © Pergamon 1962
  • Published: January 1, 1962
  • Imprint: Pergamon
  • eBook ISBN: 9781483164069

About the Author

Ye. L. Gefter

About the Editors

D. H. R. Barton

W. Doering

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