Organometallic Polymers

1st Edition - January 1, 1978
Editor: Charles E. Jr. Carraher
Language: English
eBook ISBN:
9 7 8 - 0 - 3 2 3 - 1 5 3 9 0 - 4

Organometallic Polymers focuses on the synthesis, characterization, and potential applications of organometallic polymers. The discussion is organized around seven themes: vinyl… Read more

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Organometallic Polymers focuses on the synthesis, characterization, and potential applications of organometallic polymers. The discussion is organized around seven themes: vinyl polymerization of organometallic monomers; condensation polymerization of organometallic monomers; polymer-bound catalysts; applications of organotin polymers; developments in organosilicon polymers; phosphonitrile and sulfur nitride polymers; and coordination polymers. This book is comprised of 33 chapters and begins with a general review of polymerized vinyl monomers containing transition metals, as well as the reactivity of such monomers in addition to homo- and copolymerizations. The following chapters explore the participation of the ferrocene nucleus in the polymerization of vinylferrocene and its effect on polymer properties; thermomechanical transitions of ferrocene-containing polymers; photocrosslinkable organometallic polyesters; and supported catalysts for ethylene polymerization. The remaining sections discuss antifouling applications of various tin-containing organometallic polymers; structure and applications of polyphosphazenes and polymeric sulfur nitride; and coordination of inorganic ions to polymers. This monograph will be a useful resource for organic chemists and research workers in the field.

List of Contributors

Preface

Vinyl Polymerization of Organometallic Monomers Containing Transition Materials

Vinyl Polymerization of Organometallic Monomers Containing Transition Metals

Participation of the Ferrocene Nucleus in the Polymerization of Vinylferrocene and Its Effect on Polymer Properties

Synthesis and Polymerization of Some Ferrocene Derivatives

Real and Proposed Organometallic π-Monomers

Thermomechanical Transitions of Ferrocene-Containing Polymers

The Preparation, Polymerization, and Copolymerization of Substituted Derivatives of Cynichrodene (n5-C5H5)Cr(CO)2NO

Organometallic Condensation Polymers

Organometallic Condensation Polymers

Synthesis and Properties of Polymers Containing Cobalticinium 1,1'-Dicarboxylic Acid

Poly(Cobalticinium Carboxamides)

Lead (IV) Polyesters from a New Solution System

Reactions of Triphenylantimony Dichloride with Polyacrylic Acid

Photocrosslinkable Organometallic Polyesters

Synthesis and Properties of Polymer-Bound Transition Metal Catalysts

Organometallic Polymers as Catalysts

Supported Catalysts for Ethylene Polymerization

Rhodium Elution from Polymer-Bonded Hydroformylation Catalysts

Catalytic Properties of Photochemically Attached Metal Clusters on Polyvinylpyridine

Photoacoustic Spectroscopy of Organometallic Compounds with Applications in the Fields of Quasi-One-Dimensional Conductors and Catalysts

Antifouling Applications of Tin Containing Organometallic Polymers

Antifouling Applications of Various Tin Containing Organometallic Polymers

Copolymerization of tri-n Butyltin Acrylate and Methacrylate with Functional Group Monomers—Crosslinking and Biotoxicity of Copolymers

Infrared and Nuclear Magnetic Resonance Analysis of Organotin Toxicants for Marine Antifouling Coatings

Determination of Organotin Structures on Antifouling Coatings by Mössbauer Spectroscopic Techniques

New Developments in Organosilicon Polymers

Production of Biomedical Polymers I. Silicone/Urethane Synergy in Avcothane® Elastomers

New Polyorganosiloxanes Prepared from Inorganic Mineral Silicates

Methyl- and 3,3,3,-Trifluoropropyl-Substituted m-Xylylenesiloxanylene Polymers

Thermal Stability—Structure Correlations in Arylenesiloxanylene Polymers

Polyphosphazenes and Polymeric Sulfur Nitride, Structure and Applications

Polyphosphazenes: Structure and Applications

Transition to the Mesomorphic State in Polyphosphazenes

Poly(organophosphazenes) Designed for Biomedical Uses

Biocompatability of Eight Poly(organophosphazenes)

Polymeric Sulfur Nitride (SN)X, and Its Halogen Derivatives

Coordination Polymers and Coordination of Inorganic Ions to Polymers

Coordination Polymers and Their Uses

Thallium NMR as a Probe of Alkali Ion Interactions and of Covalency in Organothallium Compounds

Complexes of Phosphoramides and Polyphosphoramides with Co(II) and Thiocyanate in Aqueous Solution

Author Index

Subject Index