Organic Sulfur Compounds - 1st Edition - ISBN: 9781483199825, 9781483224855

Organic Sulfur Compounds

1st Edition

Editors: N. Kharasch
eBook ISBN: 9781483224855
Imprint: Pergamon
Published Date: 1st January 1961
Page Count: 634
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Description

Organic Sulfur Compounds, Volume I deals with the chemistry of organic sulfur compounds such as disulfides, polysulfides, olefins, acetylenes, and chloroethylenes. Topics covered range from the inorganic acids of sulfur and the thermodynamics of organic sulfur compounds to some applications of isotopic sulfur and the stereochemistry of disulfides and polysulfides. The mechanism of oxidation of thiols to disulfides is also discussed.

Comprised of 40 chapters, this volume first considers the precise structures of elemental sulfur in relation to the reactions of sulfur compounds, followed by an analysis of the inorganic acids of sulfur. The reader is then introduced to the thermodynamics of organic sulfur compounds and the bonding characteristics of the sulfur atom, as well as the infrared spectra of organosulfur compounds. Subsequent chapters focus on the ionic scission of the sulfur-sulfur bond; nucleophilic reactions of thiols with acetylene and chloroethylene; reactions of sulfur with olefins; and the chemistry of isothiocyanates.

This book should prove useful to advanced students, practitioners, and research workers in the field of organic chemistry.

Table of Contents


1. The Structures of Elemental Sulfur


2. The Inorganic Acids of Sulfur


3. Thermodynamics of Organic Sulfur Compounds


4. Bonding Characteristics of the Sulfur Atom


5. Some Applications of Isotopic Sulfur


6. Infrared Spectra of Organo Sulfur Compounds


7. Ultraviolet Absorption Spectra of Organic Sulfur Compounds


8. Stereochemistry of Disulfides and Polysulfides


9. Ionic Scission of the Sulfur-Sulfur Bond


10. The Mechanism of Oxidation of Thiols to Disulfides


11. Sulfur Nucleophiles in Aromatic SN Reactions


12. Nucleophilic Reactions of Thiols with Acetylenes and Chloroethylenes


13. Additions of Thiols and Related Substances to Bridged Bicyclic Olefins


14. Addition of Thiols or Hydrogen Sulfide to Carbonyl Compounds


15. The Sulfonyl Group and its Effects in Organic Compounds


16. Chemistry of the Sulfoxide Group


17. Dimethyl Sulfoxide


18. Sultones and Sultams


19. Dithiols


20. Reactions of Sulfur with Olefins


21. Oxidation of Organic Sulfides


22. The Chemistry of 1,4-Dithiadiene and Related Compounds


23. Some Aspects of the Chemistry of Organic Sulfides


24. Progress in Polysulfide Polymers


25. Ortho-Mercaptoazo Compounds


26. Extrusion of Sulfur


27. Thiocyanates, Thiocyanogen and Related Compounds


28. The Chemistry of Isothiocyanates


29. The Properties of Some N-Chloroamides (Chloroamines) and Sulfilimines


30. The Alkanesulfenyl Chlorides and Related Compounds


31. Trichloromethanesulfenyl Chloride and Trichloromethanesulfonyl Chloride


32. Sulfenium Ions and Sulfenyl Compounds


33. The Contributions of Professor Claude Fromageot and his Co-Workers to the Study of Enzymic Reactions of Sulfur Compounds


34. Naturally Occurring Zsothiocyanates and their Parent Glycosides


3

Details

No. of pages:
634
Language:
English
Copyright:
© Pergamon 1961
Published:
Imprint:
Pergamon
eBook ISBN:
9781483224855

About the Editor

N. Kharasch

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