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Organic Functional Group Analysis - 1st Edition - ISBN: 9780080099002, 9781483155159

Organic Functional Group Analysis

1st Edition

International Series of Monographs on Analytical Chemistry, Volume 8

Author: F. E. Critchfield
Editors: R. Belcher L. Gordon
eBook ISBN: 9781483155159
Imprint: Pergamon
Published Date: 1st January 1963
Page Count: 196

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Description

International Series of Monographs on Analytical Chemistry, Volume 8: Organic Functional Group Analysis focuses on the application of versatile and reliable chemical methods for determining most of the more common organic functional groups. The publication first offers information acids and bases and nitrogen compounds, including differentiations, indicators, methods, amines, and amides. The text then examines carbonyl compounds and derivatives and hydroxyl compounds. Discussions focus on hydroxylamine hydrochloride-triethanolamine methods, hydroxylammonium formate, mercurimetric determination of aldehydes, acylation methods, and bromination method for aromatic hydroxyl compounds. The text takes a look at unsaturated compounds, esters, and carboxylic acid anhydrides. The manuscript also ponders on peroxides and sulfur compounds. Topics include ceric ammonium sulfate method, titration of mercaptans with mercuric perchlorate, and potassium bromate method for sulfides and disulfides. The book is a dependable reference for readers interested in the study of functional groups.

Table of Contents


Preface

1. Introduction

Techniques

2. Acids and Bases

Selection of Acid-Base Method

Differentiations

Indicators

Methods

References

3. Nitrogen Compounds

Amines

Amides

Miscellaneous

References

4. Carbonyl Compounds and Derivatives

Hydroxylamine Hydrochloride-Triethanolamine Methods

Hydroxylamine Hydrochloride-Dimethylethanolamine Method

Hydroxylammonium Formate

Mercurimetric Determination of Aldehydes

2,4,-Dinitrophenylhydrazine Colorimetric Method

Summary

References

5. Hydroxyl Compounds

Acylation Methods

Cleavage of 1,2-Glycols

Hydrogen Bromide Method for Tertiary Alcohols (and Diols)

Bromination Method for Aromatic Hydroxyl Compounds

Colorimetric Methods

Summary

References

6. Unsaturated Compounds

Halogenation Methods

Morpholine Method

Mercuric Acetate Method

Silver Perchlorate Method

Summary

References

7. 1,2-Epoxy Compounds

Indirect Hydrogen Bromide Method

Direct Hydrogen Bromide Method

Pyridine Hydrochloride Method

Morpholine Method

Colorimetric Method

Summary

References

8. Esters

Saponification with Aqueous Potassium Hydroxide

Saponification in the Presence of Phenylhydrazine

Saponification with Potassium Hydroxide in Diethylene Glycol

Hydroxamic Acid Colorimetric Method

Summary

References

9. Carboxylic Acid Anhydrides

Aniline-Sodium Hydroxide Method

Morpholine Method

Morpholine-Carbon Disulfide Method

Hydroxamic Acid Colorimetric Method

Summary

References

10. Peroxides

Sodium Iodide-Acetic Anhydride Method

Hydrogen Iodide-Acetic Acid Method

Ceric Ammonium Sulfate Method

Colorimetric Sodium Iodide-Acetic Anhydride Method

Summary

References

11. Sulfur Compounds

Titration of Mercaptans with Mercuric Perchlorate

Iodometric Method for Mercaptans

Potassium Bromate Method for Sulfides and Disulfides

Acid Hydrolysis of Alkyl Sulfates

Titration of Surface Active Sulfates and Sulfonates with Cetyl Pyridinium Bromide

Colorimetric Method for Surface Active Sulfates and Sulfonates

References

Index

Details

No. of pages:
196
Language:
English
Copyright:
© Pergamon 1963
Published:
1st January 1963
Imprint:
Pergamon
eBook ISBN:
9781483155159

About the Author

F. E. Critchfield

About the Editors

R. Belcher

L. Gordon

Ratings and Reviews