New Frontiers in Rare Earth Science and Applications - 1st Edition - ISBN: 9780127676616, 9780323142724

New Frontiers in Rare Earth Science and Applications

1st Edition

Editors: Xu Guangxian
eBook ISBN: 9780323142724
Imprint: Academic Press
Published Date: 1st January 1985
Page Count: 748
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New Frontiers in Rare Earth Science and Applications, Volume I consists of extended abstracts of the lectures, papers, and posters presented at the International Conference on Rare Earth Development and Applications held in Beijing on September 10-14, 1985.

This compilation discusses rare earth chemical and physical metallurgy, geology of rare earth mineralization in China, and study of hydroxamic acids for the floatation of rare earth minerals. The reactions of organolanthanoid complexes, use of lanthanide ions in the study of calmodulin structure, and influence of the weak magnetic field on red blood cell electrophorisis in mice bodies are also deliberated.

This publication is a good source for researchers and scientists of disciplines related to earth science.

Table of Contents

Plenary Speech

AWelcoming Speech at the Opening Ceremony of the International Conference on Rare Earth Development and Applications in Beijing

Rare Earth Chemical and Physical Metallurgy

The Electronic Structure, Chemical Bonding and Coordination Chemistry of Lanthanide Compounds

The Rare Earths as Optical Probes in Solid State Chemistry

Geochemistry and Ore Dressing

Theoretical and Practical Aspects of a Rational Systematics of Minerals (Invited Paper)

A Brief Account on Geology of Rare Earth Mineralization in China (Invited Paper)

Advances in the Studies of Rare-Earth Geochemistry in China

On the REE-Rich Carbonatites

Some Main Mineralogical Characteristics of Rare-Earth Minerals of China

Rare-Earth Concentrations in Igneous Rocks and Ores

Preliminary Study of Magma Evolution of RE-bearing Igneous Rocks in the East Section of Nanlin

Rare Earth Element Differentiation Trends in Rhyolites from the Western United States and Mexico

Synthesis Experiments of the Mineral of Fergusonite Group—On the Paragenic Relationship Between Niobium and Rare-Earth Minerals in Baiyun-ebo Ore Deposit

The Rare Earth Niobium Mineral Series and the Direction of Comprehensive Utilization of the Ores at the West Region of Baiyun-ebo Deposit, China

Selective Flotation of Rare-Earth Minerals from Fluorite, Barite and Calcite

A Study of Hydroxamic Acids for the Floatation of Rare-Earth Minerals

A New Collector for Bastnaesite-804#and a Preliminary Analysis of Its Flotation Capabilities

Flotation of Rare-Earth Minerals from Baiyun-ebo Complex Iron Ore

Organometallic Chemistry, Bioinorganic Chemistry and Coordination Chemistry

Structural Effects of Organic Ligands in Lanthanide Extraction

"Saturate Packing" and "Uniform Packing", Structural Characters in Lanthanide Coordination Compounds (Invited Paper)

Application of Cone Packing Model in Lanthanide Chemistry

Sterically Strongly Congested Organolanthanoid (III) Complexes

Syntheses and Reactivities of Light Lanthanocene Complexes Containing σ-Bonds

Reactions of Organolanthanoid Complexes

Eu-ATP, a Probe of Enzyme Structure

The Synthesis and Structural Investigation of Some Binuclear Organometallic Complexes with Rare Earth-to-Metal Bond

Europium (III) Complexes with a Tricyclic Ligand Containing Two 1, 10-Diaza-4,7,13, 16-Tetraoxacyclooctadecane Units

Mixed Ligand Lanthanide Complexes. Paramagnetic Shifts Induced by Eu(fod)3pz and Yb(fod)3pz in the NMR Spectrum of DI-1-Butyl Ether

Determination of the Stability Constants of Rare Earth-Tetracycline-Citric (Malic, Tartaric, Salicylic) Acide Mixed Ligand Complexes

Investigation of the Calcium-Binding Sites of α-Lactalbumine Using Eu(III) as a Luminescent Probe

Synthesis of Mixed Ligand Lanthanide Organometallics Involving Cyclopentadienyl and β-Diketo Chelate Ligands

Comparative Studies on Kinetic Behaviour of Cerium Complexes of EDTA and EDTA Derivatives

Thermodynamics of the Complexes of Lanthanides with O-, M-, and P-Methoxybenzoic Acids

Structural and Biological Aspects of the Azomethine Derivatives of Some of the Lanthanons

Use of Lanthanide Ions in the Study of Calmodulin Structure

Lanthanide Complexes with Ionophores: Properties and Applications (Invited Paper)

Lanthanide Trifluoroacetate Complexes with Crown Ethers

Preparation and Characterization of Complexes of Rare Earths with Propenoic Acid

Synthesis and Characterization of Rare Earth Complexes with Isomers of Dicyclohexyl-18-Crown-6

Studies on Rare Earth Complexes of Crown Ether VII Complexes of the Light Rare Earth Perchlorates with 2,3,11, 12-Tetraphenyl-l , 4 , 7 , 10,13,16-Hexaoxo-2, 11-Cyclooctadecadiene

New Type of Europium Chelates of β- Diketone

Adducts of Lanthanide Hexafluoroarsenates and Hexamethylphosphoramide

Synthesis and Characterization of Some Carboxylated of Lanthanides

New Synthetic Routes of Organo-Complexes of Ce, Nd

Studies on Rare Earth-Allyl Compounds (I) Synthesis of Allyl Compounds of La, Ce, Pr, Nd,Sm,and Y

The Reaction of H (B12 H1 1 NH2 COCH3) with Ln2 O3

Syntheses of Rare Earth Chelates Containing Ferrocenyl Group

Studies on Organolanthanide Complexes VI. The Synthesis of 2,2'-Bipyridyl Coordinated Dicyclopentadienyl Light Lanthanide Chlorides and Their Carboxylates

Studies on the Rare Earth Complexes with Pyridine Derivatives and Their N-Oxide(II)— Synthesis and Properties of Fluorescent Solid Complexes of Samarium, Europium, Gadolium and Terbium Chlorides with 2,2'-Bipyridine-N, N'-Dioxide

Preparation and Properties of Acetylacetonate-Meso-Tetra-(O-Chlorophenyl)-, -Tetra-(M-Chlorophenyl) Porphyrin Rare Earth Complexes

A Study on Hydrolytic Polymerization of Eu3+ and Gd3+

Studies on the Coordination Compounds of Benzo-15-C-5 and 4-Nitro-Benzo-15-C-5 with Rare Earths

Calorimetric Studies of the Synergistic Effect: The Reaction of UO2 (TTA)2,Nd(TTA)3 and Th(TTA)4 with TBP and TOPO in Benzene

Fourier Transform Far Infrared Spectra and Normal Coordinate Analysis of Fifteen Rare Earth Oxalate Hydrates

The Absorption Spectra of Europium Tetrakis-(β-Diketonates) in Infrared and Ultraviolet

Ultrasonic Studies on ErCl3 in Aqueous Acetonitrile

Spectrophotometric Investigation of Er(III) Complexation in Water

The Preparation and Spectroscopic Investigation of Rare Earth Metalloporphyrins

Quantum Chemistry, Structural Chemistry and Spectroscopy

Stability Trends of the Rare Earth Complexes (Invited Paper)

Theoretical Method of Ligand Field Theory and Its Application (Invited Paper)

Interaction Between Ln(III) and Nitrate Ions in Non-Aqueous Solution: A Quantitative FT IR Investigation

Perturbation Theory for Mixed Valent Systems

Valence Mixing in Rare Earth Compounds

Electronic Structure and Chemical Bonding of Trisindenyl Samarium

Electronic Structure and Chemical Bonding of Tetrakis (2,6-Dimethylpenyl) Lutetiate Anion [Lu(C8H9)4]

The Electronic Structure of Adducts Derived from Tris (Cyclopentadienyl)-Lanthanide(III) (Invited Paper)

Electronic Structure of Rare Eatrh Metals and Intermetallics (Invited Paper)

Lanthanide (III) f-f Transition Probabilities

The Electronic Structure of the Complexes of Lanthanide ions with Crown Ethers

X-ray Photoelectron Spectra of Lanthanide Complexes of Crown Ethers I. 3d5/2 Spectra and Satellite Phenomena for Ln(NO3)3.C14H20O5 and Ln(NO3)3.C20H24O6

Luminescence of Crown Ether Complexes with Divalent Europium

The Molecular Structure of Rare-Earth Isothiocyanate Hydrates

Crystal Structures and Bonds

The Synthesis and Structural Determination of Tetrakis (Trimethyl-Hexadecyl Ammonium) Decanitrato Dineodymate, [(CR3)3 C16H33N]4 Nd2(NO3)10

Crystal Growth and Structure of KLnP4O12

Investigation on Rare Earth-Bismuth Double Oxide System

Investigation on the Preparation and Properties of Rare Earth Monophosphides

Formation Mechanism of Tml2 in Tm-Hgl2 System

Study on Electric Property and Structure of Fluorescein, Dibromofluorescein and Their Rare Earth Complexes

The Structure of High-Temperature Phase of Sml2

An Investigation of High-Temperature,High-Pressure Synthesis for the Compounds PrTmO3 and NdYbC3

Optical Spectra, Energy Levels and Crystal-Field Analysis of Pr3+, Nd3+, Er3+ in Li, K LnP4O12 Crystals

On the Vibrational Spectra of Lanthanide Thenoyltrifluoroacetonate Compounds

Chemical NMR Spectroscopy with Lanthanide Nuclei

Site-Selection Spectroscopy of Eu3+ Ions in Glass Hosts

Single Crystal Absorption, CD and MCD Spectra of EuAl3(BO3)4

Two- Photon Transitions in Lanthanide Systems

Solid Chemistry and Physics

Magnetochemistry of Rare Earth Compounds

Oxysulfides in Sheet Formed by Rare Earths and Second Metals-Crystal Structures, Magnetic and Non Linear Properties

Sulfides of Rare Earths with IIB and 3d Elements

Valence Instabilities in Amorphous Ce Films

Valence Fluctuation in Rare Earth Alloys

Heavy-Fermion Superconductivity and Electronphonon Coupling in CeCu2Si2

The Influences of Ce Addition on the Growth and Superconducting Properties of Nb-Sn, Nb-Al Diffusion Films

RKKY Interaction and Susceptibility in Mixed Valence Systems

Ternary Rare Earth-Transition Metal-Silicides and Homologues

Effects of Additive Ce on Reaction Diffusion Process and Superconducting Properties of Nb3 Sn by TIN-RICH Method

Extraction Chemistry, Countercurrent Extraction Theory and Mathematical Modeling, Hydrometallurgy

Use of Low Grade Ion-Exchange Resin in Separations of RE

The Separation of Heavy Lanthanides from Yttrium by Ion-Exchange Method Using Tiron as an Eluent

Calmodulin-Lanthanide Ion Exchange Kinetics

Extraction Technology for Rare Earths From Raw Ores by Reverse Osmosis

Studies on Liquid Membrane Extraction of Rare Earths

Extraction of Mixed Rare Earths from Aqueous Solution with Emulsion Liquid Membrane

Separation of Yttrium and Erbium by CL-P507 Resin

Theory of Countercurrent Extraction and Its Applications in Rare Earth Extraction Industry (Invited Paper)

Theory of Countercurrent Extraction VII. Dynamic Equilibrium in Three-Component System

Experimental Verification of Countercurrent Extraction Theory Separation of La and Ce by HEH(EHP)

A Modified Mathematical Model of Countercurrent Extraction for Rare Earth Separation

Study on the Selection of Optimization Extraction Process by Mathematical Simulation for the System TbCl3-DyCl3-HCl-H2O-1.5M HEH(EHP) (Kerosene)

Studies on the Synthesis of Octyl Phosphonic Acid Monooctyl Esters and Their Structure-Reactivity Relationship in Lanthanide Extraction

Chemistry Problems and Extraction Mechanism in Technology of Extraction Separation of Rare Earth Elements(III) with Mono (2-Ethyl Hexyl)2-Ethyl Hexyl Phosphonate

Extraction Mechanism of Rare Earth Elements(III), Iron(III) and Thorium(IV) from Sulfuric Acid Solutions by Primary Amine N1 9 2 3

Study on the Extraction of Rare Earth Elements by Primary Amine N1 9 2 3 Extraction of Rare Earth Elements from Sulfuric Acid

Extraction Chemistry of Rare Earth by Mono-Alkyl Isopropylphosphonates

Mechanism of the Extraction of Rare Earth by Mono-Tetradecylphosphoric Acid

Studies on the Extraction and Coordination of Rare Earths with β-Ketophosphonates

The Extraction of Rare Earths with P350 and its Mechanism

Separation Process for U, Th, Fe and Rare Earth Elements in Monazite by Extraction with Dmhmp and TBP

Synergistic Extraction of Dysprosium(III) by the Ternary System of TTA-PMBP-DAMP

Preparative Scale Separation of Rare Earths and Transplutonium Elements by High Performance Ion Exchange Chromatography

Complex Formation and Ion Exchange Separation of Terralent F-Elements by Changing the Solvent Composition of a Binary Water-Dioxane Mixture

Analytical Chemistry

Derivative Spectrophotofluorometric Determination of Cerium and Terbium

Studies on Higher Derivation Absorption Spectra of Complexes of the Rare Earths with Tiron and Its Application to Analysis

P538 Extraction-Icp-Aes Determination of Rare Earth-Impurities in High-Purity CeO2

Application of Ion Exchange in Mixed Aqueous-Organic Solvent systems to the Analytical Chemistry of the Rare Earth Elements

Emission Spectrographic Determination of Trace Rare Earth Impurities in High Purity Rare Earth Oxides

The Simultaneous Determination of 15 Trace Rare Earth Elements in Rock by Optical Emission Spectrometry

Synthesis of Lanthanides-2-Thenoyl Trifluoroacetone-2, 4, 6, -Trimethyipyridine Ternary Complexes and Studies on Their Spectra

Studies on Rare Earth Compounds by Photoacoustic Spectroscopy

Studies on the Adsorptive Complexe Waves of the Rare Earths (Invited Paper)

Studies on the Determination of the Ultratrace Amounts of Europium and Samarium by Time Discrimination Laser Fluorimetry

X-ray Fluorescence Spectrometric Determination of Trace Amounts of RE in Ores by Ion-Exchange Paper

Application of Empirical Coefficient Method and Combining Method of Fundamental Parameters with Empirical Coefficient in Analysis Fluorescence Spectrometry

The Study on the Determination of Individual Rare Earth by Rate Differential Kinetic Method

Determination of Rare Earths in Rocks by Instrumental Neutron Activation Analysis

Separation of Yttrium from the Lanthanides by DOSO-NH4SCN Extraction Chromatography

Study on Capillary Gas Chromatographic Behaviour of Rare Earth Chelates of TPM

Syntheses of Unsymmetrical Bis (Arylazo) Derivatives of Chromotropic Acid and Spectrophotometric Studies on Color Reaction with Rare Earths (Invited Paper)

Studies on Synthesis of a Kind of New Color Reagents Bromophosphonobisazo Derivatives of Chromotropic Acid and the Effect of Their Constitution on Colour Behaviours with Rare Earth Elements

Determination of Trace Amounts of Rare Earth Elements in Geological Samples by Direct Current Plasma Source Spectrometry

Study on New Inorganic Ion Exchangers Containing Phosphorus-Preparations, Physicoochemical Properties and Applications of Stannic Pyrophosphate and Stannic Selenopyrophosphate

Applications in Catalysis

Characterization of Lanthanide Oxides by Low Temperature Oxygen Chemisorption (Invited Paper)

Recent Advances in Polymerization Rare Earth Catalysts (Invited Paper)

Rare Earth Oxides as Promoters of Mo-Bi Catalysts for Selective Oxidation of Olefins

Catalytic Properties of Rare Earth Intermetallics Transformed into Active Raney-Type Catalysts

Diene Rubbers Prepared with Rare Earth Catalyst System Their Structure and Properties

The Lanthanides in Heterogeneous Catalysis

Conversion of Methanol to Lower Hydrocarbons by Catalysis of Rare Earth Heteropoly Acid

Application of the Novel Cracking Catalysts Containing Rare Earth Exchanged Zeolite

Kinetics and Mechanism of Polymerization of Acetylene on Rare Earth Coordination Catalysts

Exhaust Purification by Catalysts Containing Mn and Rare Earth Oxides

Rare-Earth Catalysts for Purifying Diesel Exhaust

The Advance in the Investigation of Non-Platinum Catalysts for Purifying Automobile Exhaust

Development and Application of the Rare Earth Catalyst for the Purification of Auto Exhaust Gases

Converson of N-Heptane on Platinum-Rare Earth and Platinum-Rare Earth-Tin Catalysts

IR Study of La2O3-Supported Rh4(CO)12 Catalyst

Study of the Catalytic Properties of Perovskite Oxides-RECoO3

A New Naphtha Steam Reforming Catalyst Containing Nickel and Rare Earth Oxide

A Study of Surface Characteristice of Ni Methanation Catalyst with Added La2O3 by AES, SAM, and XPS

Environmental Protection, Toxicity and Applications in Medicine

Toxicity of Rare Earths (Invited Paper)

The use of PHP in the Radioactive Effluent Treatment in Rare Earth Industry

The Removal of Radioactivity from the Lanthanum Oxide

An Assessment of the Exhaled Thoron Activity of the Miners in Baiyuan Iron Mine

Study on Lowering the Specific Radioactivity of Rare Earth Chlorides

Subchronic Toxicity Study of Rare Earth Nitrates in Rats

Toxicological Studies on Safety Evaluation of Rare Earth Used in Agriculture

Lanthanide Complexes as Contrast Agents in NMR Imaging of the Heart

Elucidation of the Solution Structure of Bile Salt Complexes by NMR, Using Lanthanides

Clinical Observation on Constant-Magnetic-Field the Rapy of Capillary Hemangioma

Studies on 215 Cases Using Magnetic Anesthesia in Cystoscopy and Urological Operation

The Influence of the Weak Magnetic Field on Red Blood Cell Electrophorisis in Mice Bodies


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Xu Guangxian

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