Ions and Ion Pairs and Their Role in Chemical Reactions

Ions and Ion Pairs and Their Role in Chemical Reactions

Invited Lectures Presented at the Symposium on Ions and Ion Pairs and Their Role in Chemical Reactions, Syracuse, NY, USA, 30 May - 2 June 1978

1st Edition - January 1, 1979

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  • Editor: J. Smid
  • eBook ISBN: 9781483284576

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Description

Ions and Ion Pairs and their Role in Chemical Reactions covers a wide spectrum of ion pairing phenomena. This book focuses on the structure, dynamics, and energetics of ions and ion pairs and their complexes with solvent molecules and ion coordinating ligands in the solid, liquid, and gaseous state. Organized into 12 chapters, this book begins with an overview of the theory and complications involved in dipole moment measurements in slightly conductive polar solvents. This text then explores the measurement of gas phase ion-molecule equilibria by special spectrometric methods. Other chapters consider the NMR experiments on potassium biphenyl, sodium biphenyl, and rubidium biphenyl, dissolved in different solvents. This book discusses as well the ion pair formation of some cyclic conjugated carbanions and nitranions. The final chapter deals with the information obtained from relaxation measurements on processes such as ionic dissociation, aggregation, and solvent separation. This book is a valuable resource for chemists, organic chemists, and quantum chemists.

Table of Contents


  • Contents

    Published in Pure and Applied Chemistry, Volume 51, No. 1 (1979)

    Preface

    Dr. Michael Szwarc

    Structure of Solvated Ion Pairs From Electric Dipole Moments

    Information on Ion-Solvent Interactions Obtained From the Study of Isolated Complexes Containing the Ion and A Small Number of Solvent Molecules

    Structure of Alkali Biphenyl Ion Pairs in Solution and in the Solid State

    Optical and NMR Investigations on Alkali Ion Pairs of Carbanions and Nitranions

    Multinuclear NMR Studies of Alkali Ions in Nonaqueous Solvents

    Macrocyclic Ligands on Polymers

    Fast Reaction Studies of Carbocations in Solution

    Ion Pairing and Reactivity of ß-Keloenolates

    Stereochemical Effects of Ion Pairing in Anionic Vinyl Oligomerization and Related Carbanion Reactions

    The Reaction of Cations With Anions in Solution

    Formation and Reactivities of Free Ions in Cationic Polymerization

    Published in Pure and Applied Chemistry, Volume 51, No. 4 (1979)

    The Dynamics of Electric Field Effects in Ion Pairing Processes


Product details

  • No. of pages: 858
  • Language: English
  • Copyright: © Pergamon 1979
  • Published: January 1, 1979
  • Imprint: Pergamon
  • eBook ISBN: 9781483284576

About the Editor

J. Smid

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