Intercalation Chemistry
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Intercalation Chemistry introduces the specialist reader to the breadth of intercalation chemistry and the newcomer to the diverse research opportunities and challenges available in synthetic and reaction chemistry and also in the controlled modification of physical properties. Topics covered range from graphite chemistry to sheet silicate intercalates, diffusion and shape-selective catalysis in zeolites, organic and organometallic intercalation compounds of the transition metal dichalcogenides, and solvated intercalation compounds of layered chalcogenide and oxide bronzes. This book is comprised of 18 chapters and begins with an introduction to intercalation chemistry. The discussions that follow focus on the intercalation chemistry of graphite and of complex oxides with both two (clays and acid phosphates)- and three (zeolites)-dimensional structures, along with organic conversions that have been discovered using essentially smectite (i.e., montmorillonite- and hectorite-based) intercalates. The next chapters focus on β-aluminas, acid salts of tetravalent metals with layered structure, and layered chalcogenides and halides with simple and hydrated cations as well as organic and organometallic ions. The book also considers the chemistry, thermodynamics, and applications of intermetallic compounds that incorporate hydrogen, intercalation in the context of biological systems, crystallographic shear structures, and intercalation reactions of oxides and chalcogenides of vanadium, molybdenum, and tungsten. The final chapter touches on the physical properties of some intercalation compounds of the dichalcogenides. This book is intended for researchers in the various materials science disciplines.
Table of Contents
List of Contributors
Preface
1 Intercalation Chemistry: An Introduction
I. Introduction
II. Transition Metal Dichalcogenides
III. Graphite
IV. Transition Metal Oxides
V. Aluminum Oxide Hosts
VI. Energy of Intercalation
VII. Summary
References
2 Graphite Chemistry
I. Introduction
II. Graphite
III. Some General Aspects of Graphite Intercalation Compounds
IV. Intercalation with Graphite Reduction
V. Intercalation with Graphite Oxidation
VI. Intercalation without Apparent Oxidation or Reduction of the Graphite
References
3 Sheet Silicate Intercalates: New Agents for Unusual Chemical Conversions
I. Introduction
II. Structural Features
III. Techniques for Elucidating the Nature of Intercalated Clays
IV. Unusual Chemical Conversions of Organic Molecules Using Silicate Intercalates
V. Future Possibilities
References
4 Diffusion and Shape-Selective Catalysis in Zeolites
I. Introduction
II. Structural Aspects of Zeolites
III. Intracrystalline Diffusion in Zeolites
IV. Shape-Selective Catalysis in Zeolites
V. Conclusions
References
5 Intercalation Chemistry of Acid Salts of Tetravalent Metals with Layered Structure and Related Materials
I. Introduction
II. Acid Salts with Layered Structure of the α Type
III. Intercalation Chemistry of α-Zirconium Phosphate
IV. Intercalation Behavior of Other Layered Acid Salts of the α Type
V. Acid Salts with Layered Structure of the γ Type
VI. Organic Derivatives of α- and γ-Zirconium Phosphates and Their Intercalation Behavior
VII. Conclusion
References
6 The Intercalation Chemistry of β-Alumina
I. Introduction
II. Nonstoichiometric β-Aluminas
III. Hydrogen-Containing β-Aluminas
IV. Metastable β-Aluminas
References
7 Organic and Organometallic Intercalation Compounds of the Transition Metal Dichalcogenides
I. Introduction
II. Structures of the Transition Metal Dichalcogenides
III. Organic Intercalation Compounds of the Dichalcogenides
IV. Organometallic Intercalation Compounds
References
8 Intercalation Chemistry of Metal Phosphorus Trichalcogenides
I. Metal Phosphorus Trichalcogenides
II. Intercalation Chemistry of Metal Phosphorus Trichalcogenides
References
9 Structural Aspects of Monovalent Cation Intercalates of Layered Dichalcogenides
I. Introduction
II. Structure and Bonding in the Host Materials
III. The Intercalated Layered Dichalcogenides
References
10 Solvated Intercalation Compounds of Layered Chalcogenide and Oxide Bronzes
I. Introduction
II. General Aspects of Solvation and Polyelectrolyte Properties
III. Transition Metal Dichalcogenides
IV. Related Layered Chalcogenides
V. Layered Oxide Bronzes
VI. Conclusions
References
11 Intercalation of Halides
I. Normal-Valent Halides
II. Oxyhalides
III. Reduced Halides with Metal-Metal Interactions
IV. Hydrogen in Reduced Halides
References
12 Intercalation Chemistry of Metal Chalcogenohalides
I. Introduction
II. Structure, Synthesis, and Physical Properties of Layered Metal Oxyhalides
III. Intercalation Compounds with Cationic Guests
IV. Intercalation Compounds with "Neutral" Amine Guests
V. Topochemical Substitution Reactions
VI. Addendum
References
13 Hydrogen-Containing Materials
I. Introduction
II. Intermetallic Compounds
III. Hydrogen Sorption in Intermetallic Compounds
IV. Thermodynamic Considerations
V. Technical Applications
References
14 Intercalation in Biological Systems
I. Early Investigations of the Interaction of Planar Aromatic Cations with DNA
II. The Classical Intercalation Model
III. Development of the Intercalation Model
IV. Thermodynamics of Intercalation
V. Nonclassical Intercalation
VI. Applications of Intercalation
References
15 Reactions in Crystallographic Shear Structures
I. Introduction
II. Crystallographic Shear and the Structure of Crystallographic Shear Compounds
III. Reactions in Crystallographic Shear Structures
References
16 Oxide Insertion Compounds
I. Introduction
II. Preparative Methods
III. MoO3-Derived Insertion Compounds
IV. V2O5-Derived Insertion Compounds
V. WO3-Derived Insertion Compounds
VI. Miscellaneous
VII. Summary of Thermodynamic Data
VIII. Conclusions
References
17 Lithium Intercalation Compounds of Vanadium Chalcogenides
I. Introduction
II. Oxides
III. Sulfides and Selenides
IV. Summary
References
18 Physical Properties of Intercalation Compounds of Transition Metal Dichalcogenides
I. Introduction
II. Metal Intercalates in Chalcogenide Hosts
III. Organic Intercalates and Superconductivity
References
Index
Product details
- No. of pages: 611
- Language: English
- Copyright: © Academic Press 1982
- Published: January 28, 1982
- Imprint: Academic Press
- eBook ISBN: 9780323140409