Description

This volume of the Handbook on the Physics and Chemistry of Rare Earth begins with a Dedication to late Professor LeRoy Eyring who had been a committed co-editor of the first 32 volumes of this series. This is followed by four chapters, the first two pertaining to solid state physics and materials science, while the last two chapters describe organic (and inorganic) reactions mediated by tetravalent cerium-based oxidants and by divalent samarium-based reductants. Chapter 227 is devoted to the description of the crystal chemistry and physical properties of rare-earth bismuthides, a class of compounds showing large similarities with the rare-earth antimonides previously reviewed in volume 33 of this series. The fascinating optical and electric properties of rare-earth hydride films displaying a switchable mirror effect as a function of hydrogen pressure, i.e. from a shiny metallic state to a transparent insulating film with increasing pressure, are described in Chapter 228, along with their fabrication methods. Many chemical reactions take advantage of the tetravalent/trivalent Ce(IV)/Ce(III) redox couple and many of its potential applications are presented in Chapter 229, from analytical procedures, to electrosynthesis, and organic and industrial (polymerization) reactions. The last review (Chapter 230) focuses on the synthesis and use of divalent samarium-based reductants in organic and inorganic reactions, mainly on those containing iodide and pentamethylcyclopentadienyl ligands.

Key Features

· Authoritative · Comprehensive · Up-to-date · Critical · Reliable

Readership

Researchers working on rare earth materials, Rare earth industry and University libraries

Table of Contents

Preface
Contents
Contents of Volumes 1-35
Index of Contents of Volumes 1-36
Dedication to Professor LeRoy Eyring
227. Bismuthides (A. Mar)
228. Switchable Metal Hydride Films (I. Aruna, L.K. Malhotra, and B.R. Mehta)
229. Applications of tetravalent cerium compounds (K. Binnemans)
230. Samarium(II) Based Reductants (Robert A. Flowers II, and Edamana Prasad)
Author Index
Subject Index

Details

No. of pages:
580
Language:
English
Copyright:
© 2006
Published:
Imprint:
North Holland
eBook ISBN:
9780080466729
Print ISBN:
9780444521422
Print ISBN:
9780444561244

About the series-volume-editors

Karl A. Gschneidner

Gschneidner has published over 485 journal articles and chapters in books and edited or written 40 books on the chemistry, materials science, and physics or rare earth materials. He was the founder of the Rare-earth Information Center and served as its Director for 30 years.

Affiliations and Expertise

Iowa State University, Ames, USA

Jean-Claude Bünzli

Professor J-C.G. Bünzli is a physical-inorganic and analytical chemist by training and an active researcher in the field of co-ordination and supramolecular chemistry of rare-earth ions. His research focuses mainly on designing self-assembled functional edifices containing rare-earth ions and with predetermined photophysical and/or magnetic properties.

Affiliations and Expertise

Swiss Federal Institute of Technology Lausanne (EPFL), Switzerland

Vitalij Pecharsky

Professor V.K. Pecharsky is an active researcher in the field of structure-physical property relationships of rare earth-based intermetallic compounds. He co-authored over 250 papers published in peer reviewed journals and as chapters in books, holds 10 patents, mostly related to preparation and processing rare earth-based alloys.

Affiliations and Expertise

Ames Laboratory, Iowa State University, Ames, IA, USA