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Preface. 211. Filled Skutterudites (B.C. Sales). 212. Rare Earth-Antimony Systems (O.L. Sologub, P.S. Salamakha). 213. Thermodynamic Properties of the Lanthanide (III) Halides (R.I.M. Konings, A. Kovacs). 214. Rare Earth-Manganese Perovskites (J.B. Goodenough). 215. Paramagnetic NMR Lanthanide Induced Shift for Extracting Solution Structure (C. Piguet, C. Geraldès). 216. Lanthanide and Actinide Solution Chemistry Studied by Time-resolved Laser-induced Spectrocopy (TRLS) (I. Billard). 217. Optical Studies of Non-metallic Rare Earth Compounds Under Pressure (Th. Tröster).
This volume of the Handbook illustrates the rich variety of topics covered by rare earth science. Three chapters are devoted to the description of solid state compounds: skutterudites (Chapter 211), rare earth -antimony systems (Chapter 212), and rare earth-manganese perovskites (Chapter 214). Two other reviews deal with solid state properties: one contribution includes information on existing thermodynamic data of lanthanide trihalides (Chapter 213) while the other one describes optical properties of rare earth compounds under pressure (Chapter 217). Finally, two chapters focus on solution chemistry. The state of the art in unraveling solution structure of lanthanide-containing coordination compounds by paramagnetic nuclear magnetic resonance is outlined in Chapter 215. The potential of time-resolved, laser-induced emission spectroscopy for the analysis of lanthanide and actinide solutions is presented and critically discussed in Chapter 216.
- No. of pages:
- © North Holland 2003
- 19th June 2003
- North Holland
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Iowa State University, Ames, IA, USA
J.-C. Bünzli was educated as a physico-chemical inorganic chemist (BSc and PhD at EPFL; postdocs at UBC, Canada and ETH Zürich). He started to work on lanthanide coordination chemistry in 1975 at the University of Lausanne and was promoted full professor in 1980. In 2001 he transferred to EPFL where he founded the Laboratory of Lanthanide Supramolecular Chemistry. After studying the solvation of lanthanide ions by innovative experimental techniques, he turned to macrocyclic and supramolecular chemistry, focusing on self-assembly processes. In parallel he kept interest in the relationship between luminescence and structure, developing several luminescent materials, including ionic liquids, liquid crystals, and nanoparticles. All this led to the design of rugged and sensitive luminescent bioprobes for the detection of markers expressed by cancerous cells and tissues. Lately he has expanded this aspect of his research by collaborating with several groups in Australia and China. Selected as World Class University professor at Korea University during 2009-2013, he has since been working at the Chinese Academy of Sciences, UTS (Sydney), HKBU (Hong Kong), and SUSTech (Shenzhen). He has also been invited professor at ten different universities in China, Japan, France, Belgium, and the U.K. He has been elected dean of the Faculty of Science (1990-1991) and Vice-president of the University of Lausanne (1991-1995) and as such implemented the Erasmus program in Switzerland. He also acted as expert on several review committees in China, France, Norway, Switzerland, Ireland, Italy, Finland, UK, and USA. He is the founder (1989) and president of the European Rare Earth and Actinide Society and co-editor of the Handbook on the Physics and Chemistry of Rare Earths. He has published 330 WOS papers (>27 300 cites, h factor =78).
Swiss Federal Institute of Technology Lausanne (EPFL), Switzerland
V.K. Pecharsky received a combined BSc/MSc degree in Chemistry (1976) and a PhD degree in Inorganic Chemistry (1979) from Lviv State University (now Ivan Franko National University of Lviv) in Ukraine. He held a faculty appointment at the Department of Inorganic Chemistry at Lviv State University between 1979 and 1993, after which he moved to Ames, Iowa, where he became a staff member at the U.S. Department of Energy Ames Laboratory. In 1998 he accepted a faculty position at the Department of Materials Science and Engineering at Iowa State University, while remaining associated with Ames Laboratory. He was named an Anson Marston Distinguished Professor of Engineering in 2006. He also serves as a Faculty Scientists, Field Work Project Leader, and Group Leader at Ames Laboratory. While in Lviv, V. Pecharsky was studying phase relationships and crystallography of ternary intermetallic compounds containing rare earths. After moving to Ames his research interests shifted to examining composition-structure-physical property relationship of rare-earth intermetallic compounds. Together with Karl Gschneidner, Jr., he discovered a new class of materials that exhibit the giant magnetocaloric effect in 1997, triggering worldwide interest in caloric materials and caloric cooling, which promises to become an energy-efficient, environmentally-friendly alternative to conventional vapor-compression approach. Today his research interest include synthesis, structure, experimental thermodynamics, physical and chemical properties of intermetallic compounds containing rare-earth metals; anomalous behavior of 4f-electron systems; magnetostructural phase transformations; physical properties of ultra-pure rare earth metals; caloric materials and systems; hydrogen storage materials; mechanochemistry, mechanically induced solid-state reactions and mechanochemical transformations. He organized the 28th Rare Earth Research Conference in Ames, Iowa in 2017. He serves as co-editor of the Handbook on the Physics and Chemistry of Rare Earths and senior editor of the Journal of Alloys and Compounds. He has published over 500 WOS papers (>22 600 cites, h factor = 60).
Ames Laboratory, Iowa State University, Ames, IA, USA
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