Description

This comprehensive handbook will be an indispensable research tool for chemists. Handbook of Palladium Catalysed Organic Reactions provides a synoptic description of the main types of reactions which are catalyzed by Palladium and the mechanism which causes these reactions. Each reaction is presented in graphical form and classified according to the type of transformation involved. Other books covering the use of Palladium complexes as catalysts have been written, but the Handbook is the only to offer a synoptic view, showing the catalytic cycle of each reaction. This complete coverage provides the reader with a good understanding of the parameters involved. The tables included can be viewed from the point of view of the reagents, the product of the reaction, or the mechanism involved. The Handbook is a companion to the Database of Palladium Chemistry: Reactions andCatalytic Cycles, published on CD-ROM.

Key Features

@introbul:Key Features @bul:* Begins with explicit instructions from the authors, facilitating use of the Handbook * Details the associated catalytic cycle for each class of reactions * Offers a choice of references, allowing the reader to find the closest example for solving a given problem * 84 types of mechanism covered, plus over 2500 references * Presents graphical abstracts for all reactions described, making it easy to search a type of reaction * Comb-bound for easy reference * Free demo disk included for the Database of Palladium Chemistry * A versatile tool for chemists in the academic community, this handbook will be an invaluable tool in the laboratory * 84 types of mechanism covered, plus over 2500 references * Presents graphical abstracts for all reactions described, making it easy to search a type of reaction * Comb-bound for easy reference * Free demo disk included for the Database of Palladium Chemistry * A versatile tool for chemists in the academic community, this handbook will be an invaluable tool in the laboratory.

Readership

The book is a tool for the chemist, to be used in the lab. It is aimed at the academic scientist who does not have access to the software necessary to run the CD-ROM.

Table of Contents

Abbreviations. Introduction. Graphical Abstracts of Reaction Numbers (RXN). Reactions Catalyzed by Palladium Complexes: Cross-Coupling of Organometallics with RX Derivatives. Cross-Coupling of Organometallicswith RCOX Derivatives. Cross-Coupling of Siloxycyclopropanes with RX and RCOX Derivatives. Cross-Coupling of Terminal Alkynes with RX Derivatives. Intermolecular HECK Reaction. Intramolecular HECK Reaction. Intramolecular Coupling of Di(Vinyl Halides). Tandem HECK-Anion Capture Process of Alkenes, Alkyenes, Alkynes, Allenes and Dienes. Tandem HECK-Anion Capture Process of Norbonene and Related Compounds. Tandem Arylsulfonation-Cyclization Process. Tandem Cyclization-Anion Capture (-Carbonylation) Processof Alkenes and Alkynes. Tandem Cyclization-Anion Capture (-Carbonylation) Process of Ene-Vinyl, Ene-Aryl, and Ene-Alkyl Halides. Tandem Cyclization-Anion Capture Process of Yne-Vinyl and Yne-Aryl Halides. Hydroarylation and Hydrovinylation of Alkenes andAlkynes. Reduction of Alkenes. Semihydrogenation of Alkynes and 1,3-Dienes. Hydroboration, Hydrogennyladon, Hydrosilylation and Hydrostannation of Alkynes, Allenes, Dienes, and Enynes. Hydroselenation of Alkynes. 1,4-Disilyation of Conjugated Enones. Hydrocarboxylation, Hydrocarboalkoxylation and Hydrocarboamination of Alkenes and Alkynes. Tandem Carbonylation-Arylation with Alkynes. 1,2-Dimetallation of Alkynes and Alkenes and Related Reactions. 1,2-Dimetallation of Isonitriles. 1,2-Dimetallation of Allenes. Coupling of Aryl Derivatives with Alkenes Involving a Pd(II) Catalyst. Homocoupling of Aryl and Vinyl Derivatives. Codimerization of Alkynes. Codimerization of Terminal Alkynes with Allenes. Codimerization of Alkynes and Allyl Halides. Cyclopropanation of Alkenes and 1,3-Dienes by Diazomethane. Rearrangement of (-Hydroxy Diazo Compounds. Substitution, Addition, and Elimination on Pro-(-Allyl Substrates. [3,3]-Sigmatropic Rearrangement and [1,3]-Shift on Allyl

Details

No. of pages:
304
Language:
English
Copyright:
© 1997
Published:
Imprint:
Academic Press
Print ISBN:
9780124666153
Electronic ISBN:
9780080533148

About the authors

Jean-Luc Malleron

Jean-Luc Malleron received his graduate degree from the school of chemistry at Montpellier and then went on to obtain his Ph.D. at the Université Paris Sud. Malleron has been Senior Research Fellow in medicinal chemistry at Rhône-Poulec Rorer Company since 1981.