COVID-19 Update: We are currently shipping orders daily. However, due to transit disruptions in some geographies, deliveries may be delayed. To provide all customers with timely access to content, we are offering 50% off Science and Technology Print & eBook bundle options. Terms & conditions.
Geological Sequestration of Carbon Dioxide - 1st Edition - ISBN: 9780444529503, 9780080466880

Geological Sequestration of Carbon Dioxide, Volume 11

1st Edition

Thermodynamics, Kinetics, and Reaction Path Modeling

Author: Luigi Marini
Hardcover ISBN: 9780444529503
eBook ISBN: 9780080466880
Imprint: Elsevier Science
Published Date: 12th October 2006
Page Count: 470
Sales tax will be calculated at check-out Price includes VAT/GST
Price includes VAT/GST

Institutional Subscription

Secure Checkout

Personal information is secured with SSL technology.

Free Shipping

Free global shipping
No minimum order.

Table of Contents

1. Why we should care: the impact of anthropogenic carbon dioxide on the carbon cycle.
2. The thermodynamic background.
3. Carbon dioxide and CO2-H2O mixtures.
4. The aqueous electrolytic solution.
5. The product solid phases.
6. The kinetics of mineral carbonation.
7. Reaction path modeling of geological CO2 sequestration.


The contents of this monograph are two-scope. First, it intends to provide a synthetic but complete account of the thermodynamic and kinetic foundations on which the reaction path modeling of geological CO2 sequestration is based. In particular, a great effort is devoted to review the thermodynamic properties of CO2 and of the CO2-H2O system and the interactions in the aqueous solution, the thermodynamic stability of solid product phases (by means of several stability plots and activity plots), the volumes of carbonation reactions, and especially the kinetics of dissolution/precipitation reactions of silicates, oxides, hydroxides, and carbonates.

Second, it intends to show the reader how reaction path modeling of geological CO2 sequestration is carried out. To this purpose the well-known high-quality EQ3/6 software package is used. Setting up of computer simulations and obtained results are described in detail and used EQ3/6 input files are given to guide the reader step-by-step from the beginning to the end of these exercises.

Finally, some examples of reaction-path- and reaction-transport-modeling taken from the available literature are presented. The results of these simulations are of fundamental importance to evaluate the amounts of potentially sequestered CO2, and their evolution with time, as well as the time changes of all the other relevant geochemical parameters (e.g., amounts of solid reactants and products, composition of the aqueous phase, pH, redox potential, effects on aquifer porosity). In other words, in this way we are able to predict what occurs when CO2 is injected into a deep aquifer.

Key Features

  • Provides applications for investigating and predicting geological carbon dioxide sequestration
    * Reviews the geochemical literature in the field
    * Discusses the importance of geochemists in the multidisciplinary study of geological carbon dioxide sequestration


Geological, geochemical and environmental branches of oil and electrical companies; Professionals and students in geology, environemental studies and environmental engineering


No. of pages:
© Elsevier Science 2006
12th October 2006
Elsevier Science
Hardcover ISBN:
eBook ISBN:

Ratings and Reviews

About the Author

Luigi Marini

Affiliations and Expertise

University of Genova, Genova, Italy