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Fourth International Conference on Non-Aqueous Solutions - 1st Edition - ISBN: 9780408706926, 9781483278827

Fourth International Conference on Non-Aqueous Solutions

1st Edition

Vienna 1974

Editor: V. Gutmann
eBook ISBN: 9781483278827
Imprint: Butterworth-Heinemann
Published Date: 1st January 1975
Page Count: 125
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Non-Aqueous Solutions is a collection of papers presented at the Fourth International Conference on the same subject. One paper presents the application of far- and mid-infra-red, Raman, alkali metal n.m.r. and 35C1 n.m.r. techniques to the study of electrolyte solutions in non-aqueous solvents. The paper notes that spectroscopic techniques can be very useful in the elucidation of the structure of electrolyte solutions. Both the vibrational spectroscopy and particularly the alkali metal n.m.r. are very sensitive probes of the immediate chemical environment of ions in solutions. Another paper points out that the energy change associated with the solvation of ions can be represented as the sum of two energy terms; firstly, from the dielectric polarization of the solvent molecules in the continuous dielectric medium; and secondly, due to specific ion-solvent interactions in the inner solvation shells of the ions. The energy contribution of the latter is minimal but can show comparatively large differences in various types of solvents. Another paper describes the chemistry of solutions in highly associated strong protonic acid solvents, including sulphuric acid, oleums, fluorosulfuric acid, and hydrogen fluoride. Organic chemists, analytical chemists, investigators, and scientists whose works involve physical or inorganic chemistry will find the collection truly beneficial.

Table of Contents

Alkali Metal n.m.r. and Vibrational Spectroscopic Studies on Solvates in Non-Aqueous Solvents

Ionic Equilibria in Donor Solvents

Mechanism of Complex Formation in Non-Aqueous Solvents

Recent Advances in Molten Salts as Reaction Media

Some Aspects of Chemistry in Strongly Acidic Solvent Media


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© Butterworth-Heinemann 1975
1st January 1975
eBook ISBN:

About the Editor

V. Gutmann

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