Fluorine Chemistry V2

1st Edition - January 1, 1954
Editor: J.H. Simons
Language: English
eBook ISBN:
9 7 8 - 0 - 3 2 3 - 1 4 5 4 3 - 5

Fluorine Chemistry, Volume II focuses on studies on fluorocarbons and fluorocarbon derivatives. Composed of various literature, the book first discusses fluorine-containing complex… Read more

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Fluorine Chemistry, Volume II focuses on studies on fluorocarbons and fluorocarbon derivatives. Composed of various literature, the book first discusses fluorine-containing complex salts and acids. The complex fluorides of alkali metals, beryllium, boron, carbon, silicon, germanium, tin, and lead are described. The text also looks at research on halogen fluorides. The physical properties of chlorine, bromine, and iodine fluorides; halogen fluorides as ionizing solvents; and acids and bases in iodine pentafluoride and chlorine trifluoride are discussed. The book discusses analytical chemistry of fluorine and fluorine-containing compounds. Analysis of gaseous samples; separation and isolation of fluorine; qualitative detection and identification of fluorine; and determination of fluorine in specific materials are described. The text also focuses on organic compounds containing fluorine. Alcohols, acids and their derivatives, polymer containing fluorines, amines, amino acids, drugs, dyes, and pesticides are discussed as well. The book further looks at metallic compounds containing fluorocarbon radicals and organometallic compounds containing fluorine, fluorocarbon chemistry, and the infrared spectra of fluorocarbons and related compounds. The text is a vital source of information for readers wanting to study fluorocarbons and fluorocarbon derivatives.

List of Contributors

Preface

List of Tables

Fluorine Containing Complex Salts and Acids

Complex Fluorides

Complex Fluorides of Group I

Complex Fluorides of Group II

Complex Fluorides of Group III

Complex Fluorides of Group IV

Complex Fluorides of Group V

Complex Fluorides of Group VI

Complex Fluorides of Group VII

Complex Fluorides of Group VIII

Bibliography

Halogen Fluorides—Recent Advances

Introduction

Physical Properties of the Halogen Fluorides

The Chlorine Fluorides

The Bromine Fluorides

The Iodine Fluorides

The Halogen Fluorides as Ionizing Solvents

Acids and Bases in Iodine Pentafluoride and Chlorine Trifluoride

Bibliography

Analytical Chemistry of Fluorine and Fluorine-Containing Compounds

Introduction

Sampling of Fluorine-Containing Materials

Analysis of Gaseous Samples

Separation and Isolation of Fluorine

Qualitative Detection and Identification of Fluorine

Determination of Fluoride Ion

Fluorine Compounds

Determination of Fluorine in Specific Materials

Bibliography

Organic Compounds Containing Fluorine

Introduction

Hydrofluorocarbons

Cyclobutane Derivatives

Alcohols

Ethers

Aldehydes and Ketones

Acids and Their Derivatives

Amines

Heterocyclic Compounds

Amino Acids

Dyes

Drugs

Pesticides

Polymers Containing Fluorine

Bibliography

Metallic Compounds Containing Fluorocarbon Radicals and Organometallic Compounds Containing Fluorine

Metallic Compounds Containing Fluorocarbon Radicals

Fluorocarbon Mercurials

Fluorocarbon Derivatives of Phosphorous

Fluorocarbon Derivatives of Arsenic

Fluorocarbon Derivatives of Antimony

Fluorocarbon Derivatives of Sulfur

Fluorocarbon Derivatives of Selenium

Fluorocarbon Derivatives of Magnesium, Zinc, Cadmium, and Silicon

Organometallic Compounds Containing Fluorine

Alkyl and Aryl Fluorides of Metals and Nonmetals

Bibliography

Fluorocarbon Chemistry

Introduction

Developments in Methods of Producing Fluorochemicals

The Chemical and Physical Properties of Fluorocarbons

Fluorocarbon Derivatives

Bibliography

The Infrared Spectra of Fluorocarbons and Related Compounds

Introduction

Hydrogen Stretching Frequencies

C≡C, C≡N, and N=C=O Stretching Frequencies

C=C Stretching Frequencies

C=O Stretching Frequencies

Spectral Correlations in the 1350- to 650-Cm.-1

Region

Infrared Absorption Spectra

Bibliography

Author Index

Subject Index