Current Developments in Biotechnology and Bioengineering

Deep Eutectic Solvents: Fundamentals and Emerging Applications

1st Edition - September 10, 2022
Editors: Ashish Pandey, Bhagyashree Tiwari, Ashok Pandey, Suzana Yusup
Language: English
Paperback ISBN:
9 7 8 - 0 - 3 2 3 - 9 9 9 0 5 - 2
eBook ISBN:
9 7 8 - 0 - 3 2 3 - 9 9 9 5 6 - 4

Deep eutectic solvents represent the newest addition among all other non-conventional and alternate solvent systems. Deep Eutectic Solvent Fund Emerging Applications pr… Read more

Current Developments in Biotechnology and Bioengineering

Purchase options

LIMITED OFFER

Save 50% on book bundles

Immediately download your ebook while waiting for your print delivery. No promo code is needed.

Institutional subscription on ScienceDirect

Request a sales quote

Deep eutectic solvents represent the newest addition among all other non-conventional and alternate solvent systems. Deep Eutectic Solvent Fund Emerging Applications provides detailed insights on these neoteric solvents, their synthesis methods, types, physicochemical properties, and sustainable applications in emerging scientific areas. The book follows a mechanistic approach on understanding the role of DESs as sustainable media for CO2 capture, biomass pretreatment, as catalysts, as reaction media for material synthesis, cross coupling reactions, templates for drug delivery, etc. The book offers a springboard for encouraging vital discussions and inspiring further innovations in the field of environmentally benign eutectic solvent systems.

Cover Image
Series Editor
Title Page
Copyright
Table of Contents
Contributors
Preface
Chapter 1 Deep eutectic solvents—An Introduction
1.1 Introduction
1.2 Deep eutectic solvents
1.3 Physicochemical properties of DESs
1.4 Applications of DESs
1.5 Challenges in development and applications of DESs
1.6 Conclusions and perspectives
References
Chapter 2 Design strategies for the synthesis of deep eutectic solvents
2.1 Introduction
2.2 Deep eutectic solvents solubility in water
2.3 Technologies for the synthesis of deep eutectic solvents
2.4 Conclusions and perspectives
Acknowledgment
References
Chapter 3 Applications of deep eutectic solvents in gas capture
3.1 Introduction
3.2 Computational studies on gas capture by deep eutectic solvents
3.3 Conclusions and perspectives
Acknowledgments
References
Chapter 4 Critical analysis of green solvent credentials of eutectic solvents
4.1 Introduction
4.2 Defining green credentials
4.3 Deep eutectic solvents in terms of inherent greenness
4.4 Physical properties of deep eutectic solvents
4.5 Potential and reality of deep eutectic solvents applications
4.6 Three components eutectic mixtures containing water
4.7 Conclusions and perspectives
Acknowledgments
References
Chapter 5 Deep eutectic solvents vs. ionic liquids: Similarities and differences
5.1 Introduction
5.2 Ionic liquids vs. deep eutectic solvents
5.3 Physicochemical properties: ILs vs. DES
5.4 A case study: Lignocellulosic biomass valorization
5.5 Solvent recycling
5.6 Conclusions and perspectives
Acknowledgments
References
Chapter 6 Role of deep eutectic solvents as pretreatment medium for biomass transformation
6.1 Introduction
6.2 Current status of biomass pretreatment
6.3 Deep eutectic solvents and their biopolymers solubility
6.4 Biomass pretreatment and transformation using DESs
6.5 Current constraints
6.6 Conclusions and perspectives
Acknowledgments
References
Chapter 7 Deep eutectic solvents as green and efficient media for biocatalytic processes
7.1 Introduction
7.2 Evolution of deep eutectic solvents as biocatalytic solvents
7.3 Types of deep eutectic solvents
7.4 Deep eutectic solvents compatible biocatalysts
7.5 Process optimization using computational modeling
7.6 Commercially relevant biocatalytic processes involving DES
7.7 Conclusions and perspectives
References
Chapter 8 Applications of deep eutectic solvents in membrane-based separation processes
8.1 Introduction
8.2 Deep eutectic solvents assisted or containing membranes
8.3 Applications of deep eutectic solvents-based membranes
8.4 Conclusions and perspectives
References
Chapter 9 Liquid-liquid equilibria and alcohol valorization in aqueous alcoholic systems using hydrophobic eutectic solvents
9.1 Introduction
9.2 Liquid-liquid equilibria with lower alcohols
9.3 Process design and techno-economic assessment for the recovery of 1-butanol from aqueous solution using a hybrid extraction-distillation system
9.4 Conclusions and perspectives
Nomenclature
References
Chapter 10 Applications of deep eutectic solvents in remediation of emerging contaminants
10.1 Introduction
10.2 Applications of deep eutectic solvents (DESs) in the remediation of pollutants
10.3 Challenges and opportunities
10.4 Conclusions and perspectives
Acknowledgments
References
Chapter 11 Cross-coupling reactions in deep eutectic solvents
11.1 Introduction
11.2 Carbon-carbon cross-coupling reactions
11.3 Carbon-nitrogen cross-coupling reactions
11.4 Carbon-oxygen cross-coupling reactions
11.5 Carbon-sulfur cross-coupling reactions
11.6 Conclusions and perspectives
Acknowledgments
References
Chapter 12 Deep eutectic solvents (DESs) as efficient systems for drug discovery, drug delivery, and pharmaceutical applications
12.1 Introduction
12.2 Preparation of DESs
12.3 DESs for drug applications
12.4 Toxicological profile of DESs
12.5 Conclusions and perspectives
References
Chapter 13 Applications of deep eutectic solvents (DESs) in CO2 mitigation technologies
13.1 Introduction
13.2 Deep eutectic solvents-based techniques for CO2 capture
13.3 Conclusions and perspectives
References
Chapter 14 Deep eutectic solvents in desulfurization of fuel oil
14.1 Introduction
14.2 Deep eutectic solvents (DESs) in desulfurization
14.3 DESs in extractive desulfurization
14.4 DESs in oxidative desulfurization
14.5 Response surface methodology of DESs—Desulfurization system
14.6 Regeneration of DESs in desulfurization
14.7 Mechanisms of DESs desulfurization process
14.8 Molecular modeling
14.9 Conclusions and perspectives
References
Chapter 15 Regulatory aspects of deep eutectic solvents technology and applications
15.1 Introduction
15.2 Regulations of deep eutectic solvents applications
15.3 Problems of deep eutectic solvents as sustainable solvents
15.4 Recommendation: Regulatory aspects of deep eutectic solvents application
15.5 Conclusions and perspectives
References
Chapter 16 Impact of deep eutectic solvents to health, safety, and environment
16.1 Introduction
16.2 Toxicity of deep eutectic solvents (DESs)
16.3 Safety impact of deep eutectic solvents
16.4 Biodegradability of deep eutectic solvents
16.5 Inherent safety assessment of DESs
16.6 Way forward of evaluating safety, health, and environmental impacts of deep eutectic solvents
16.7 Conclusions and perspectives
References
Index

Ashish Pandey

Dr. Ashish Pandey received his Ph.D. from Department of Chemistry, Indian Institute of Technology (IIT) Delhi, India and subsequently completed the two-year prestigious institute postdoctoral position from Chemical Engineering department at IIT Delhi. His research interests are in the development of non-conventional media, viz., deep eutectic solvents, ionic liquids, supercritical fluids, etc., and their sustainable applications in CO2 capture, bitumen cracking, biomass, and e-waste valorisation among others. Dr. Pandey has 25 scientific publications, 2 patents and over 650 citations. Dr. Pandey was awarded by Springer India Limited and Indian National Academy of Engineering (INAE) in the INAE Youth Conclave 2019 for his innovative research endeavours. Presently, Dr. Pandey works as senior R&D chemist at CalAgua Innovations Corp. on the design and synthesis of ionic liquids to develop cost-effective and sustainable solutions for the energy sector. Dr. Pandey has previously worked as Head (R&D) at Clensta International Private Limited and is also a visiting scientist at the Centre for Energy and Environmental Sustainability, Lucknow, India.

Affiliations and expertise

Scientist, Centre for Energy and Environmental Sustainability, Lucknow, India

Bhagyashree Tiwari

Dr. Bhagyashree Tiwari received her Ph.D. in water sciences from Institut national de la recherche Scientifique (INRS), Université du Québec, Canada in 2020. Her research work focuses on the development as well as optimization of various water and wastewater treatment techniques, production of value-added products, such as, biopolymers from waste, identification, and characterization of microscopic organisms and on molecular biology approach for emerging contaminant removal. Previously, Dr. Tiwari was a MITACS-ELEVATE Postdoctoral Fellow at INRS, Université du Québec, Canada. She has published several peer-reviewed journal papers, over 15 book chapters, edited 1 book and has presented in many national and international conferences. She is also the recipient of several awards, prominent among them are the Philip Jones award from Canadian Association on Water Quality in 33rd Eastern Canadian Symposium on Water Quality Research, best oral research presentation award in 7th International forum on Industrial Bioprocess in Wuxi, China. She received the prestigious mobility grant from Venice International University, Italy.

Affiliations and expertise

Industrial and Environmental Biotechnology, Institut national de la recherche scientifique – Eau, terre, et environnement (INRS-ETE), Universite of Quebec, Canada

Ashok Pandey

Professor Ashok Pandey is currently Distinguished Scientist at the Centre for Innovation and Translational Research, CSIR-Indian Institute of Toxicology Research, Lucknow, India and Executive Director (Honorary) at the Centre for Energy and Environmental Sustainability – India. Formerly, he was Eminent Scientist at the Center of Innovative and Applied Bioprocessing, Mohali and Chief Scientist & Head of Biotechnology Division and Centre for Biofuels at CSIR’s National Institute for Interdisciplinary Science and Technology, Trivandrum. His major research and technological development interests are industrial & environmental biotechnology and energy biosciences, focusing on biomass to biofuels & chemicals, waste to wealth & energy, industrial enzymes, etc. Professor Pandey is Adjunct/Visiting Professor/Scientist in universities in France, Brazil, Canada, China, Korea, South Africa, and Switzerland and also in several universities several in India. He has ~1425 publications/communications, which include 16 patents, 90 books, >700 papers and book chapters, etc with h index of 105 and ~48,800 citations (Goggle scholar). He has transferred several technologies to industries and has done industrial consultancy for about a dozen projects for Indian/international industries. Professor Pandey is the recipient of many national and international awards and honours, which include Highest Cited Researcher (Top 1% in the world), Clarivate Analytics, Web of Science (2020, 2019 & 2018); Top scientist in Biotechnology (#1 in India and #8 in the world), Stanford University world ranking (2020); Fellow, World Society of Sustainable Energy Technologies (2020); Fellow, Indian Chemical Society (2020); Distinguished Scientist, VDGOOD Professional Association, India (2020); Distinguished Professor of Eminence with global impact in the area of Biotechnology, Precious Cornerstone University, Nigeria (2020); IconSWM Life-time Achievement Award 2019, International Society for Solid Waste Management, KIIT, Bhubaneshwar, India (2019); Yonsei Outstanding Scholar, Yonsei University, Seoul, Korea (2019); Life-Time Achievement Award from the Biotech Research Society, India (2018); Life-Time Achievement Award from Venus International Research Awards (2018), Most Outstanding Researcher Award from Career360 (2018), Life-Time Achievement Award from the International Society for Energy, Environment and Sustainability (2017); Fellow, Royal Society of Biology, UK (2016); Felow, International Society for Energy, Environment and Sustainability (2016); Academician of European Academy of Sciences and Arts, Austria (2015); Fellow, National Academy of Sciences, India (2012); Fellow, Association of Microbiologists of India (2008); Honorary Doctorate degree from Univesite Blaise Pascal, France (2007); Fellow, International Organization of Biotechnology and Bioengineering (2007); Thomson Scientific India Citation Laureate Award, USA (2006); Fellow, the Biotech Research Society, India (2005); UNESCO Professor (2000); Raman Research Fellowship Award, CSIR (1995); GBF, Germany and CNRS, France Fellowships (1992) and Young Scientist Award (1989), etc. Professor Pandey is Founder President of the Biotech Research Society, India (www.brsi.in); Founder & International Coordinator of International Forum on Industrial Bioprocesses, France (www.ifibiop.org), Chairman of the International Society for Energy, Environment & Sustainability (www.isees.in), Editor-in-chief of Bioresource Technology (http://ees.elsevier.com/bite/), Honorary Executive Advisor of Journal of Energy and Environmental Sustainability (www.jees.in), Journal of Systems Microbiology and Biomanufacturing (https://www.springer.com/journal/43393), Journal of Environmental Sciences and Engineering (http://neerijese.org/editorial-board/), Subject Editor, Proceedings of National Academy of Sciences, India (https://www.springer.com/life+sciences/journal/40011) and Associate Editor, Biologia – Section Cellular and Molecular Biology (https://www.springer.com/journal/11756/editors) and editorial board member of several international and Indian journals.

Affiliations and expertise

Distinguished Scientist, Centre for Innovation and Translational Research, CSIR-Indian Institute of Toxicology Research, Lucknow, Uttar Pradesh, India; Sustainability Cluster, School of Engineering, University of Petroleum and Energy Studies, Dehradun, Uttarakhand, India; Centre for Energy and Environmental Sustainability, Lucknow, Uttar Pradesh, India

Suzana Yusup

Professor Ir. Dr Suzana Yusup, is the Head of HICoE Center for Biofuel & Biochemical Research (CBBR) and is a full Professor at the Chemical Engineering Department, Universiti Teknologi PETRONAS (UTP), Malaysia. Her research interest is in the area of biomass conversion to biofuels and bio-chemicals, material development, and greener processes. To date, Professor Dr Suzana Yusup has authored one book, 26 book chapters, more than 300 scientific articles in high impact journals and as conference papers, 19 patents (including 7 granted patents).

Affiliations and expertise

Head, HICoE Center for Biofuel and Biochemical Research (CBBR) and Professor, Chemical Engineering Department, Universiti Teknologi PETRONAS (UTP), Malaysia