Coulometry in Analytical Chemistry

Coulometry in Analytical Chemistry

The Commonwealth and International Library: Selected Readings in Analytical Chemistry

1st Edition - January 1, 1967

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  • Authors: G. W. C. Milner, G. Phillips
  • eBook ISBN: 9781483182490

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Coulometry in Analytical Chemistry aims to fill the apparent gap in analytical textbook literature on analytical chemistry by presenting relevant studies from the time the ideas are first developed to the more topical ones, wherein more modernized concepts are encompassed. This text has seven chapters; first of which gives an introduction to the study. This book goes on examining the constant-current coulometry and constant-potential coulometry. The next two chapters encompass the equipment needed for these groups of techniques, followed by a chapter on the applications of these methods. The next chapter then discusses the constant-current coulometric titrations. The last part presents the fundamental papers in the development of coulometry. This book will be invaluable to chemistry students and practitioners, especially those interested in analytical chemistry.

Table of Contents

  • Basic References Reproduced in Chapter VII


    1 Introduction

    2 Theoretical Treatment

    2.1. Constant-Current Coulometry

    2.1.1. Methods of End-Point Determination

    2.2. Constant-Potential Coulometry

    2.2.1. Measurement of Total Current

    2.2.2. Working Electrode Potentials

    3 Equipment and Technique for Constant-Current Coulometry

    3.1. Current Sources

    3.2. Measurement of the Quantity of Electricity

    3.3. Electrolysis Cells

    3.3.1. Cells for the External Generation of Titrants

    3.4. Differential Coulometric Titrations

    4 Equipment for Controlled-Potential Coulometry

    4.1. Coulometers for Controlled-Potential Coulometry

    4.1.1. Chemical Integration

    4.1.2. Electrical and Electromechanical Integration

    4.1.3. Electronic Integration

    4.2. Controlled-Potential Coulometric Titrators

    4.3. High Sensitivity Controlled-Potential Coulometric Titrators

    4.4. Differential Controlled-Potential Coulometry

    4.5. Cells for Controlled-Potential Coulometry

    4.5.1. Cells for Use with Solid-Working Electrodes

    4.5.2. Cells for Use with a Stirred-Mercury Electrode

    5. Applications of Controlled-Potential Coulometry

    5.1. Inorganic

    5.2. Organic

    6. Constant-Current Coulometric Titrations

    6.1. Redox, Complexometric and Precipitation Titrations for Inorganic Substances

    6.2. Redox, Complexometric and Precipitation Titrations for Organic Substances

    6.3. Neutralization Titrations in Inorganic and Organic Analysis

    7. Fundamental Papers in the Development of Coulometry

    7.1. Constant-Current Coulometry

    7.2. Controlled-Potential Coulometry

    7.2.1. Control of Potential

    7.2.2. Developments in Integration

    7.2.3. Fundamental Principles

    7.2.4. Background Corrections in Controlled-Potential Coulometric Analysis


Product details

  • No. of pages: 220
  • Language: English
  • Copyright: © Pergamon 2013
  • Published: January 1, 1967
  • Imprint: Pergamon
  • eBook ISBN: 9781483182490

About the Authors

G. W. C. Milner

G. Phillips

George M. Phillips is Reader in Mathematics at the University of St. Andrews, UK. His longstanding collaboration in mathematics has encompassed both teaching and research. Both authors have published many papers in numerical analysis and approximation theory.

Affiliations and Expertise

University of St. Andrews

About the Editor

R. J. Magee

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