Chemistry in Anhydrous, Prototropic Solvents
Inorganic Chemistry in Liquid Hydrogen Cyanide and Liquid Hydrogen Fluoride
- 1st Edition - January 1, 1971
- Authors: Barbara Grüttner, Michael F. A. Dove, Alan F. Clifford
- Editors: Gerhart Jander, Hans Spandau
- Language: English
- eBook ISBN:9 7 8 - 1 - 4 8 3 1 - 6 1 0 0 - 6
Chemistry in Nonaqueous Ionizing Solvents: Volume II — Part 1 investigates the chemical and physico-chemical properties of substances dissolved or suspended in non-aqueous ionizing… Read more
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Request a sales quoteChemistry in Nonaqueous Ionizing Solvents: Volume II — Part 1 investigates the chemical and physico-chemical properties of substances dissolved or suspended in non-aqueous ionizing solvents (also known as water-like solvents). This volume is concerned with chemistry in anhydrous hydrogen cyanide and with inorganic chemistry in liquid hydrogen fluoride. This book is comprised of 35 chapters that cover topics ranging from commercial preparation of hydrogen fluoride to laboratory preparation of pure hydrogen fluoride as well as deuterium and tritium fluorides. Experimental techniques and the apparatus used in investigations of liquid hydrogen fluoride are also described. Subsequent chapters explore health risks and first aid with respect to handling hydrogen fluoride; physical properties of the pure solvent; inorganic solvates; solubilities and reactions of inorganic compounds; and acids and bases and their reactions with each other. The last two chapters are devoted to fluorides of the lanthanides and actinides in hydrogen fluoride. This monograph will be of interest to chemists.
Part 1 Anorganische Chemie in flüssigem Cyanwasserstoff
1. Das Lösungsmittel flüssiger Cyanwasserstoff
1.1. Physikalische Daten des reinen Solvens
1.2. Struktur des Solvens HCN
2. Das Verhalten anorganischer Verbindungen im Lösungsmittel Cyanwasserstoff
2.1. Additionsverbindungen mit Cyanwasserstoff (Solvate)
2.2. Die Löslichkeit von anorganischen Substanzen und Salzen organischer Ionen in flüssigem Cyanwasserstoff
2.3. Lösungszustand
2.4. Das Solvosystem des flüssigen Cyanwasserstoffs
2.5. Das Verhalten von "Säure-Basen" - Indikatoren in flüssigem wasserfreiem Cyanwasserstoff
2.6. Neutralisationenanaloge Reaktionen in flüssigem Cyanwasserstoff
2.7. Solvolyse-Reaktionen in wasserfreiem Cyanwasserstoff
2.8. Die Erscheinung der Amphoteric in flüssigem Cyanwasserstoff
2.9. Weitere Reaktionen in flüssigem Cyanwasserstoff
3. Das Verhalten organischer Verbindungen im Lösungsmittel Cyanwasserstoff
3.1. Additionsverbindungen mit Cyanwasserstoff (Solvate)
3.2. Die Löslichkeit von organischen Verbindungen in wasserfreiem Cyanwasserstoff
3.3. Lösungszustand
3.4. Solvolysereaktionen organischer Verbindungen in wasserfreiem Cyanwasserstoff
3.5. Bemerkung über weitere Reaktionen organischer Verbindungen in und mit Cyanwasserstoff
4. Literaturverzeichnis
Sachwortverzeichnis
Part 2 Inorganic Chemistry in Liquid Hydrogen Fluoride
1. Commercial Preparation of Hydrogen Fluoride
2. Laboratory Preparation of Pure Hydrogen Fluoride
3. Laboratory Preparation of Deuterium and Tritium Fluorides
4. Preparation of 18 F-Labeled Hydrogen Fluoride
5. Experimental Techniques
5.1. Constructional Materials
5.2. Apparatus
6. Health Risks and First Aid
7. Physical Properties of the Pure Solvent
8. Structure of the Solvent
8.1. Solid Hydrogen Fluoride
8.2. Gaseous Hydrogen Fluoride
8.3. Liquid Hydrogen Fluoride
9. Inorganic Solvates
10. Solubilities and Reactions of Inorganic Compounds
10.1. Introductory Remarks
10.2. Elements
10.3. Halides
10.4. Oxides, Hydroxides, and Salts of Oxyacids
10.5. Azides, Cyanides and Sulphides
10.6. Miscellaneous
11. Acids and Bases
11.1. Formal Definitions
11.2. Quantitative Measurements
11.3. Basic Solutes
11.4. Acidic Solutes
11.5. Neutral Solutes
12. Acid-Base Reactions
12.1. Conductimetric and Tensimetric Titrations
12.2. Preparative Reactions
12.3. Solvolysis of Fluoro Anions
12.4. Amphoteric Behavior
13. Redox Reactions
13.1. Electrode Potentials
13.2. Polarography
13.3. Electrolytic Reactions
13.4. Chemical Agents
14. Complexions
14.1. Fluoro Anions
14.2. Complex Cations
15. H2O-HF System
15.1. Hydrofluoric Acid
15.2. Wet Hydrogen Fluoride
15.3. Hammett Acidity Function
15.4. Phase Diagram
15.5. Vapor Pressures and Boiling Points
15.6. Density Measurements
15.7. Conductivity Measurements
15.8. Infrared Spectroscopy
15.9. Nuclear Magnetic Resonance Spectroscopy
15.10. Solvent Extraction
16. SO2-HF System
17. Alkali Metal Fluorides in HF
17.1. Lithium Fluoride
17.2. Sodium Fluoride
17.3. Potassium Fluoride
17.4. Rubidium Fluoride
17.5. Cesium Fluoride
18. Ammonium and Substituted Ammonium Fluorides in HF
18.1. Ammonium Fluoride
18.2. Substituted Ammonium Fluorides
19. Group II Metal Fluorides in HF
19.1. Beryllium Fluoride
19.2. Magnesium Fluoride
19.3. Calcium Fluoride
19.4. Strontium Fluoride
19.5. Barium Fluoride
20. Group III Fluorides in HF
20.1. Boron Trifluoride
20.2. Aluminum Trifluoride
20.3. Gallium Fluorides
20.4. Indium Trifluoride
20.5. Thallium Fluorides
21. Group IV Fluorides in HF
21.1. Carbon Fluorides
21.2. Silicon Tetrafluoride
21.3. Germanium Tetrafluoride
21.4. Tin Fluorides
21.5. Lead Fluorides
22. Group V Fluorides in HF
22.1. Nitrogen Fluorides and Oxyfluorides
22.2. Phosphorus Fluorides
22.3. Arsenic Fluorides
22.4. Antimony Fluorides
22.5. Bismuth(IH) Fluoride
23. Group VI Fluorides in HF
23.1. Oxygen Difluoride
23.2. Sulphur Fluorides and Oxyfluorides
23.3. Selenium(IV) Fluoride
23.4. Tellurium (IV) Fluoride
24. Halogen Fluorides in HF
24.1. Chlorine Fluoride
24.2. Bromine Fluorides
24.3. Iodine Fluorides and Oxyfluorides
25. Noble Gas Fluorides in HF
25.1. Krypton(II) Fluoride
25.2. Xenon Fluorides
26. Titanium, Zirconium and Hafnium Fluorides in HF
26.1. Titanium(IV)
26.2. Zirconium(IV)
26.3. Hafnium(IV)
27. Vanadium, Niobium and Tantalum Fluorides in HF
27.1. Vanadium(IV)
27.2. Vanadium(V)
27.3. Niobium(V)
27.4. Tantalum(V)
28. Chromium, Molybdenum and Tungsten Fluorides in HF
28.1. Chromium(III)
28.2. Chromium(VI)
28.3. Molybdenum(V)
28.4. Molybdenum(VI)
28.5. Tungsten(VI)
29. Manganese and Rhenium Fluorides in HF
29.1. Manganese(III)
29.2. Manganese(VII)
29.3. Rhenium(VI)
29.4. Rhenium(VII)
30. Iron, Cobalt and Nickel Fluorides in HF
30.1. Iron
30.2. Cobalt
30.3. Nickel(II)
30.4. Nickel(III)
30.5. Nickel(IV)
31. Palladium, Osmium, and Platinum Fluorides in HF
31.1. Palladium(IV)
31.2. Osmium(VI)
31.3. Platinum(II)
31.4. Platinum(IV)
32. Copper and Silver Fluorides in HF
32.1. Copper(II)
32.2. Silver(I)
32.3. Silver (II)
33. Zinc, Cadmium and Mercury Fluorides in HF
33.1. Zinc(II), Cadmium(II) and Mercury(I)
33.2. Mercury(II)
34. Fluorides of the Lanthanides in HF
35. Fluorides of the Actinides in HF
35.1. Thorium(IV)
35.2. Uranium(IV)
35.3. Uranium(V)
35.4. Uranium(VI)
35.5. Neptunium(IV) and Neptunium(V)
35.6. Plutonium(VI)
References
Index
- No. of pages: 340
- Language: English
- Edition: 1
- Published: January 1, 1971
- Imprint: Pergamon
- eBook ISBN: 9781483161006
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