Chemical Reactions in Solvents and Melts - 1st Edition - ISBN: 9780080126784, 9781483146140

Chemical Reactions in Solvents and Melts

1st Edition

Authors: G. Charlot B. Trémillon
eBook ISBN: 9781483146140
Imprint: Pergamon
Published Date: 1st January 1969
Page Count: 536
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Description

Chemical Reactions in Solvents and Melts discusses the use of organic and inorganic compounds as well as of melts as solvents. This book examines the applications in organic and inorganic chemistry as well as in electrochemistry. Organized into two parts encompassing 15 chapters, this book begins with an overview of the general properties and the different types of reactions, including acid–base reactions, complex formation reactions, and oxidation–reduction reactions. This text then describes the properties of inert and active solvents. Other chapters consider the proton transfer reactions in polar solvents as well as the transfer of other ions. This book discusses as well the solubility in a number of solvents by the formation of different bonds between the solute and the solvent molecule. The final chapter deals with the general characteristics of the oxidation–reduction reactions of melts. This book is a valuable resource for chemists, students, and researchers.

Table of Contents


Preface

Introduction

Part I. General Properties

Polar and Non-Polar Solvents

The Fundamental Types of Reactions

Chapter 1. Acid-Base Reactions in Non-Polar Solvents

Inert Solvents

Active Solvents

Comparison of the Strengths of Acids and Bases in Various Solvents

Supplementary Notes:

Hydrogen Bonding

Experimental Methods of Study

Chapter 2. Acid-Base Reactions in Polar Solvents

Effect of the Chemical Properties of the Solvent

Comparison of the Strengths of Acid-Base Couples in Various Solvents

Chapter 3. Complexes

Complexes in Polar Media

Complexes in Non-Polar Media

Exchange Reactions Involving Two Ions

Ionized Melts

Chapter 4. Oxidation-Reduction Reactions

Electron Transfer Reactions in Non-Polar Media

Electron Exchange Reactions in polar media

Comparison of Scales of Potential in Various Solvents

Oxidation-Reduction and Acidity. Oxidation-Reduction and Complexes

Chapter 5. Solubility. Sparingly Soluble Compounds

Solubilities in Non-Polar Media

Solubilities in Polar Media

Part II. Chemical Properties in Various Solvents

Chapter 6. Hydrocarbons and Halogen Derivatives

Chapter 7. Acids

Chapter 8. Bases

Chapter 9. Alcohols and Phenols

Chapter 10. Amides

Chapter 11. Nitro-Derivatives, NitrilesI and Ketones

Chapter 12. Anhydrides, Ethers and Esters

Chapter 13. Various Solvents

Chapter 14. Halides

Chapter 15. Ionized Melts

General Bibliography

Solvent Index

Subject Index


Details

No. of pages:
536
Language:
English
Copyright:
© Pergamon 1969
Published:
Imprint:
Pergamon
eBook ISBN:
9781483146140

About the Author

G. Charlot

B. Trémillon