Chelating Extractants

Equilibrium Constant of Liquid–Liquid Distribution Reactions

1st Edition - January 1, 1978
Authors: J. Stary, H. Freiser
Language: English
eBook ISBN:
9 7 8 - 1 - 4 8 3 1 - 5 8 0 1 - 3

Equilibrium Constants of Liquid-Liquid Distribution Reactions, Part IV: Chelating Extractants is a compilation of liquid-liquid distribution equilibrium constants, with emphasis on… Read more

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Equilibrium Constants of Liquid-Liquid Distribution Reactions, Part IV: Chelating Extractants is a compilation of liquid-liquid distribution equilibrium constants, with emphasis on extractants that form chelates. This tabulation includes all data published up to the end of 1972 for the major chelating extractants, and the given equilibrium parameters are supplemented by calculations (or recalculations) from experimental results. This monograph consists of 12 chapters and characterizes the homogeneous equilibria involving the acid dissociation of the extractant in the aqueous phase and adduct or mixed ligand complex formation in the organic phase. The information given for each system includes the chemical reactions, the equilibrium constant, the temperature, and the composition of the aqueous and organic phases. Compounds covered include dialkyldithiocarbamic acids (such as diethyldithiocarbamic acid and dibutyldithioarbamic acid), tropolones (beta-isopropyltropolone and gamma-isopropyltropolone), N-acylhydroxylamines, N-nitroso-N-arylhydroxylamines (cupferrons), alpha-dioximes, diarylthiocarbazones (dithizones), 8-hydroxyquinolines, 8-mercaptoquinolines, o-dimercaptobenzenes (toluene-3,4-dithiol), beta-diketones (such as acetylacetone and hexafluoroacetylacetone), 4-acylpyrazol-5-ones, and o-nitrosophenols (1-nitroso-2-naphthol and 2-nitroso-1-naphthol). This book will be of interest to chemists.

Preface

How to Use the Tables

I. Dialkyldithiocarbamic Acids

1-Pyrrolidinedithiocarbamic Acid

Diethyldithiocarbamic Acid

Dibutyldithioarbamic Acid

3-Phenyl-Pyrazolinedithiocarbamic Acid

5-Phenyl-Pyrazolinedithiocarbamic Acid

3-Phenyl-5-(2-Furyl)-Pyrazolinedithiocarbamicacid

3,5-Diphenyl-Pyrazolinedithiocarbamic Acid

II. Tropolones

Tropolone

ß-Isopropyltropolone

γ-Isopropyltropolone

III. N-Acylhydroxylamines

Benzohydroxamic Acid

N-Phenylacetylhydroxamic Acid

Caprinohydroxamic Acid

N-Furoyl-N-Phenylhydroxylamine

N-Benzoyl-N-Phenylhydroxylamine

N-Phenylacetyl-N-Phenylhydroxylamine

N-Cinnamoyl-N-Phenylhydroxylamine

N-(o-Trifluoromethyl-Benzoyl-N-Phenylhydroxylamine

N-(m-Trifluoromethyl)Benzoyl-N-Phenylhydroxylamine

N-(p-Trifluoromethyl)Benzoyl-N-Phenylhydroxylamine

N-(3-Trifluoromethyl-5-Nitro)Benzoyl-N-Phenylhydroxylamine

IV. N-Nitroso-N-Arylhydroxylamines (Cupferrons)

N-Nitroso-N-Naphthylhydroxylamine

N-Nitroso-N-Phenylhydroxylamine

V. α-Dioximes

Dimethylglyoxime

Ethylmethylglyoxime

1,2-Cyclohexanedionedioxime

1,2-Cycloheptanedionedioxime

α-Furildioxime

α-Benzildioxime

VI. Diarylthiocarbazones (Dithizones)

Diphenylthiocarbazone

Di-(p-Fluorophenyl)-Thiocarbazone

Di-(p-Chlorophenyl)-Thiocarbazone

Di-(o-Chlorophenyl)-Thiocarbazone

Di-(o-Bromophenyl)-Thiocarbazone

Di-(p-Bromophenyl)-Thiocarbazone

Di-(p-Iodophenyl)-Thiocarbazone

Di-(p-Methoxyphenyl)-Thiocarbazone

Di-(o-Tolyl)-Thiocarbazone

Di-(p-Tolyl)-Thiocarbazone

Di-(m-Trifluoromethylphenyl)-Thiocarbazone

Di-(2,4-Xylyl)-Thiocarbazone

Di-(α-Naphthyl)-Thiocarbazone

Di-(ß-Naphthyl)-Thiocarbazone

Di-(o-Diphenyl)-Thiocarbazone

VII. 8-Hydroxyquinolines

8-Hydroxyquinoline

5,7-Dichloro-8-Hydroxyquinoline

5,7-Dibromo-8-Hydroxyquinoline

5,7-Diiodo-8-Hydroxyquinoline

5-Chloro-7-Iodo-8-Hydroxyquinoline

2-Methyl-8-Hydroxyquinoline

4-Methyl-8-Hydroxyquinoline

5-Methyl-8-Hydroxyquinoline

5-Acetyl-8-Hydroxyquinoline

VIM. 8-Mercaptoquinolines

8-Mercaptoquinoline

5-Fluoro-8-Mercaptoquinoline

5-Chloro-8-Mercaptoquinoline

5-Bromo-8-Mercaptoquinoline

5-Iodo-8-Mercaptoquinoline

2-Methyl-8-Mercaptoquinoline

4-Methyl-8-Mercaptoquinoline

6-Methyl-8-Mercaptoquinoline

7-Methyl-8-Mercaptoquinoline

2,4-Dimethyl-8-Mercaptoquinoline

4,6-Dimethyl-8-Mercaptoquinoline

2-Phenyl-8-Mercaptoquinoline

IX. o-Dimercaptobenzenes

Toluene-3,4-Dithiol

X. ß-Diketones

Acetylacetone

Hexafluoroacetylacetone

Trifluoroacetylacetone

Dipropionylmethane

Heptafluorobutyryltrifluoroacetylmethane

Pivaloylacetylmethane

Isovaleroyltrifluoroacetone

2-Thenoylacetone

2-Furoyltrifluoroacetone

2-Thenoyltrifluoroacetone

Diisobutyrylmethane

Benzoylacetone

Benzoyltrifluoroacetone

Heptafluorobutyrylpivaloylmethane

Dipivaloylmethane

2-Naphthoyltrifluoroacetone

Dibenzoylmethane

2-Selenoyltrifluoroacetone

2-Selenoylacetone

2-Thenoyl-2-Selenoylmethane

2-Furoyl-2-Selenoylmethane

Di-2-Selenoylmethane

2-Selenoyl-2-Picolinylmethane

2-Selenoyl-Nicotinylmethane

2-Selenoyl-Isonicotinylmethane

Pyrroyltrifluoroacetone

2-Selenoyl-3-Nitrobenzoylmethane

Benzoyl-2-Selenoylmethane

XI. 4-Acylpyrazol-5-Ones

1-Phenyl-3-Methyl-4-Acetyl-Pyrazol-5-One

1-Phenyl-3-Methyl-4-Trifluoroacetyl-Pyrazol-5-One

1-Phenyl-3-Methyl-4-Trichloroacetyl-Pyrazol-5-One

1-Phenyl-3-Methyl-4-Chloroacetyl-Pyrazol-5-One

1-Phenyl-3-Methyl-4-Propionyl-Pyrazol-5-One

1-Phenyl-3-Methyl-4-Ethoxycarbonyl-Pyrazol-5-One

1-Phenyl-3-Methyl-4-Butyryl-Pyrazol-5-One

1-Phenyl-3-Methyl-4-Valeryl-Pyrazol-5-One

1-Phenyl-3-Methyl-4-Thenoyl-Pyrazol-5-One

1-Phenyl-3-Methyl-4-Capronyl-Pyrazol-5-One

1-Phenyl-3-Methyl-4-Benzoyl-Pyrazol-5-One

1-Phenyl-3-Methyl-4-p-Bromobenzoyl-Pyrazol-5-One

1-Phenyl-3-Methyl-4-Capryl-Pyrazol-5-One

XII. o-Nitrosophenols

1-Nitroso-2-Naphthol

2-Nitroso-1-Naphthol