
Chelating Agents and Metal Chelates
Description
Table of Contents
List of Contributors
Preface
1. Historical Background and Fundamental Concepts
I. Introduction
II. Historical Background
III. Fundamental Concepts
IV. Investigation of the Structure of Metal Chelates
V. The Stability of Metal Chelates
References
2. The Nature of the Metal-Ligand Bond
I. Bond Types and Characteristic Properties
II. The Classes of Acceptor Metal Atoms
III. Consideration of Orbitals and Orbital Properties
IV. Metal-Metal Bonds in Complex Compounds
References
3. Bidentate Chelates
I. Introduction
II. Oxygen Chelates
III. Nitrogen Chelates
IV. Sulfur Chelates
V. Phosphorus and Arsenic Chelates
References
4. Design and Stereochemistry of Multidentate Chelating Agents
I. Introduction
II. Tridentate Chelating Agents
III. Quadridentate Chelating Agents
IV. Quinquedentate Chelating Agents
V. Sexadentate Chelating Agents
VI. Higher Multidentate Chelating Agents
References
5. Optical Phenomena in Metal Chelates
I. General Introduction
II. Optical Isomerism and Stereochemistry
III. Methods of Resolution
IV. Stereospecificity
V. Rotary Dispersion and Configuration
References
6. Oxidation-Reduction Potentials as Functions of Donor Atom and Ligand
I. Theoretical Aspects
II. Liquid Junction Potentials
III. Reversibility
IV. Measurement of Redox Potentials
V. Factors Governing Redox Potential Values
VI. Evaluation of the Terms in the Born-Haber Cycle
VII. Aquo Couples
VIII. The Potentials of Fe(II)/(III) Complex Couples
IX. Hexacyano Metal Complex Couples
X. Ethylenediaminetetraacetato Chelate Couples
XI. Metal Phenanthroline-Type Chelate Couples
XII. Ruthenium Chelate Couples
XIII. Osmium Chelate Couples
XIV. The Effect of Substitution in the Ligand
References
7. Metal Chelates of Ethylenediaminetetraacetic Acid and Related Substances
I. Ethylenediaminetetraacetic Acid
II. The Metal Chelates of Ethylenediaminetetraacetic Acid
III. 1,2-Propylenediaminetetraacetic Acid and its Metal Chelates
IV. Cis- and Trans-1,2-Cyclohexanediaminetetraacetic Acids
References
8. Enzyme-Metal Ion Activation and
Catalytic Phenomena with Metal Complexes
I. Metal Enzyme Catalysis
II. The Reactivity of Coordinated Molecules
III. Metal Ion Catalysis
References
9. Metal Chelates in Biological Systems
I. Metal Ion Toxicity
II. Biological Effects of Synthetic Chelates
III. Metal Chelates in Microbiological Systems
IV. Clinical Uses of Metal Chelates
V. Conclusions
References
10. Physical and Coordination Chemistry of the Tetrapyrrole Pigments
I. Porphyrins as Chelating Agents
II. Perpendicular Coordination by Metal Porphyrin Chelates
III. The Nature of the Metal-Ligand Bond
IV. Physicochemical Properties
V. Hemoproteins: Some Aspects of Their Coordination Chemistry and Some Model Compounds
References
Author Index
Subject Index
Product details
- No. of pages: 546
- Language: English
- Copyright: © Academic Press 1964
- Published: January 1, 1964
- Imprint: Academic Press
- eBook ISBN: 9780323146418
About the Editor
F Dwyer
Ratings and Reviews
Latest reviews
(Total rating for all reviews)
Peter A. Thu Feb 08 2018
Chelating Agents and Metal Chelates
The book gives a good background on the topic of chelation. My particular interest was for mineral processing but the book is focussed on biological chelation aspects. Nevertheless it gives a good grounding and understanding of the process/es which is what I needed.