Annual Reports in Inorganic and General Syntheses-1972

Annual Reports in Inorganic and General Syntheses-1972

1st Edition - January 1, 1973

Write a review

  • Editors: Kurt Niedenzu, Hans Zimmer
  • eBook ISBN: 9781483213873

Purchase options

Purchase options
DRM-free (PDF)
Sales tax will be calculated at check-out

Institutional Subscription

Free Global Shipping
No minimum order

Description

Annual Reports in Inorganic and General Syntheses-1972 presents an organized annual summary of synthetic developments in inorganic chemistry and its related areas. The book discusses alkali and alkaline earth elements, alloys, silver, gold, zinc, cadmium, mercury, boron, aluminum, gallium, indium, thallium, yttrium, scandium, lanthanides, actinides, titanium, zirconium, hafnium, Group V and VI transition elements, manganese, technetium, rhenium, iron, cobalt, nickel, ruthenium, osmium, rhodium, and iridium. The text also describes the chemistry of palladium, platinum, silicon, germanium, tin, lead, nitrogen, phosphorus, arsenic, antimony, bismuth, chalcogenides, fluorine, halogens, pseudohalogens, noble gases, and simple and complex metal hydrides of main groups I, I, and III. New techniques and reagents in synthetic coordination chemistry, as well as the stabilizing effects of large counter-ions are also encompassed. Chemists, chemistry students, and people working in chemical laboratories will find the book invaluable.

Table of Contents


  • Preface

    Alkali and Alkaline Earth Elements

    The Elements

    Complexes with Halogens

    Compounds with Group VI Elements

    Ozonide

    Alkoxides

    Oxygen-Bonded Chelates

    Other Salts and Complexes of Oxy Compounds

    Sulfur-Containing Compounds

    Nitrogen-Containing Compounds

    Organometallic Compounds

    Compounds with Transition Metals

    References

    Copper

    Alloys and Intermetallic Compounds

    Inorganic Copper Compounds

    Binary and Tertiary Copper Compounds

    Copper(II) Metallates

    Complexes of Copper(I)

    Phosphine Ligands

    Nitrogen Containing Ligands

    Complexes of Copper(II)

    Multidentate and Polymeric Ligands

    Complexes of Copper(II) with Nitrogen Linkage

    Complexes of Copper(II) with Schiff Bases

    Complexes of Copper(II) with Pyridine

    Complexes with Other Heterocyclic Ligands

    Complexes with Amino Acid Ligands

    Complexes with Phosphorus and Arsenic Ligands

    Complexes with Oxygen Linkage

    Derivatives with Thio- and Seleno-Ligands

    Complexes with Fluorinated Ligands

    Organocopper Compounds

    Copper(III) Compounds

    References

    Silver and Gold

    General

    Phosphine Complexes and Related Derivatives

    Simple Salts and Other Complexes

    Nitrogen Donors

    Chalcogen Donors

    Miscellaneous Organometallic Compounds

    References

    Zinc, Cadmium and Mercury

    General and Coordination Compounds

    Compounds with Metal-Metal Bonds

    Group IV Metals

    Boron Derivatives

    Transition Metals

    Organometallic Compounds

    Organomercury

    Organozinc

    References

    Boron

    General

    New Procedures

    Organoboranes

    Hydroboration

    Carboranes

    Boron Hydrides

    Metal-Boron Compounds

    Three Coordinate Boron

    Boron-Nitrogen Compounds

    Ring Systems

    Four Coordinate Boron

    BX3 Complexes

    BX4 Complexes

    References

    Aluminum, Gallium, Indium, Thallium

    Introduction

    Procedures of Synthesis

    Aluminum

    Ga and In Derivatives by Oxidative Addition

    Thallium

    Deuterium and Tritium Labeling

    Reactions of Al Derivatives with Epoxides and Carbonyls

    Epoxides

    Carbonyl Compounds

    Reactions of R2AlX

    Reactions with Olefins

    Addition Reactions

    Cyclization

    Reactions of Thallium Compounds

    Cyanation

    Halogenation

    Oxidation

    Compounds with Metal-Metal Bonds

    Aluminum

    Gallium and Indium

    Thallium

    Miscellaneous Reactions

    Ate Complexes

    Reactions of Optically Active Compounds

    Oxygen-Bridged Compounds

    Hydrogen-Bridged Compounds

    References

    Yttrium, Scandium, Lanthanides and Actinides

    Hydrides

    Oxides

    Fluorides

    Borides

    Chalcogenides

    Organo Lanthanides and Actinides

    Beta-Diketonato Compounds

    References

    Titanium, Zirconium and Hafnium

    Borides

    Alkoxides

    Phosphonato Complexes

    Organo Titanium, Zirconium and Hafnium

    Aniline and O-allylaniline

    Methyltitanium Rrichloride

    Cyclopentadienyl Derivatives

    Reaction with Alkylaluminurn

    Cyclopentadienyl Halo Complexes

    Heteronuclear Complexes

    Pentamethylcyclopentadienyl Titanium

    Metallocycles

    Binuclear Compounds

    References

    Group V Transition Elements

    Vanadium

    Halides, Oxohalides and Adducts

    Other Simple Compounds

    Coordination Compounds

    Vanadates and Other Oxide Phases

    Niobium and Tantalum

    Halides, Oxohalides and Adducts

    Other Simple Compounds

    Coordination Compounds

    Niobates and Tantalates

    References

    Group VI Transition Elements

    Chromium

    Oxides

    Chromates and Chromites

    Halogen-Containing Compounds of Chromium

    Refractory Compounds

    Miscellaneous

    Molybdenum

    Oxides

    Simple Molybdates

    Isopoly Compounds

    Heteropoly Compounds

    Thiomolybdates and Chalcogenides

    Halogen-Containing Molybdenum Compounds

    Miscellaneous compounds

    Tungsten

    Tungsten Bronzes and Simple Tungstates

    Heteropoly Tungstates

    Chalcogenides and Chalcotungstates

    Halogen-Containing Tungsten Compounds

    References

    Manganese, Technetium and Rhenium

    General

    Manganese

    Lower Oxidation States

    Manganese(II)

    Manganese (III)

    Higher Oxidation States

    Technetium

    Rhenium

    Rhenium(I)

    Rhenium(II)

    Rhenium(III)

    Rhenium(IV)

    Rhenium(V)

    Rhenium(VI)

    Rhenium(VII)

    References

    Iron

    General

    Hydrides and Phosphine Complexes

    Compounds with Iron-Carbon Bonds

    Compounds with Nitrogen Donors

    Compounds with Oxygen Donors

    Complexes with Sulfur Ligands

    Halide Complexes

    Miscellaneous

    References

    Cobalt and Nickel

    Low Oxidation States - Co(-I), Co(0), Co(I)

    Carbonyls

    Phosphine Complexes

    Nitrosyls

    Low-Valent Nickel Complexes

    Carbonyls

    Phosphine Complexes

    Other Zerovalent Nickel Complexes

    Nickel(I) Complexes

    Nitrosyls

    Cobalt(II) and Nickel(II) Complexes

    Complexes with Heavy Donor Atoms

    Nickel(II) Complexes of Macrocyclic Ligands

    Oxidative and Reductive Syntheses of Cobalt(II) and Nickel(II) Complexes

    Unusual Cobalt(II) and Nickel(II) Complexes

    Cobalt (III) Complexes

    Some Unusual Cobalt(III) Complexes

    Syntheses in Non-Aqueous Solvents

    Cobalt(III) Intermediates with Weakly Coordinated Solvent Molecules

    Syntheses from Nitro, Sulfito and Carbonate Intermediates

    Complexes of Macrocyclic Ligands

    Binuclear and Polynuclear Complexes

    Cobalt(III) Complexes with Less Common Combinations of Donor Atoms

    Separation of Cobalt(III) Complexes

    Nickel in Higher Oxidation States - Ni(III) and Ni(IV)

    Cobalt (IV)

    References

    Platinum Metals, Part I: Ru, Os, Rh, Ir

    Introduction

    The Chemistry of Ruthenium and Osmium

    Group VII Donors

    Group VI Donors

    Group V Donors

    Group IV Donors

    The Chemistry of Rhodium and Iridium

    Group VII Donors

    Group VI Donors

    Group V Donors

    Group IV Donors

    References

    Platinum Metals, Part II: Pd and Pt

    Introduction

    Group VII Donors

    Group VI Donors

    Oxygen Donors

    Sulfur Donors

    Group V Donors

    Nitrogen Donors

    Phosphorus or Arsenic Donors

    Palladium(II) and Platinum(II) Complexes

    Hydrido-Phosphine or -Arsine Complexes

    Group IV Donors

    Heteronuclear Carbonyl Complexes

    Monoolefin and Acetylene Complexes

    Chelating Diolefin Complexes

    π-Allyl Complexes

    Isonitrile and Carbenoid Complexes

    Metallation Reactions and Complexes Containing Metal-Carbon Sigma Bonds

    Complexes Containing Pt-Si or Pt-Ge Bonds

    References

    Silicon

    General

    Silicon-Halogen

    Silicon-Nonmetal

    Silicon-Oxygen

    Silicon-Carbon

    Silicon-Nitrogen

    Other Silicon-Nonmetals

    Silicon-Metal

    Silicon-Silicon

    Inorganic

    Organic

    References

    Germanium, Tin and Lead

    General

    MR4 Compounds

    Metal-Carbon Bonded Compounds

    Metal-Nitrogen Bonded Compounds

    Metal-Oxygen Bonded Compounds

    Metal-Halogen Bonded Compounds

    Compounds Containing More Than One Group IV Metal in the Structure

    Miscellaneous MR4 Compounds

    Reactions of MR4 Compounds

    Metal-Metal Bonded Compounds

    Organometallic Compounds

    Coordination Compounds

    Coordination Compounds of Ge, Sn, Pb

    References

    Nitrogen

    General

    Compounds with no N-N Bonds

    Compounds with One N-N Bond

    Compounds with Three Linked Nitrogens

    Compounds with Chains of Four Nitrogens

    References

    Phosphorus

    Introduction

    New Syntheses

    Elemental Phosphorus

    Phosphoranes

    Phosphines, Phosphine Oxides and Sulfides

    Phosphorus-Boron Compounds

    Compounds Containing Phosphorus-Halogen Bonds

    Derivatives with Halogen and Other Groups

    Compounds with Hydrogen or Carbon Bonded to Phosphorus

    Phosphorus-Halogen Compounds

    Phosphorus-Metal Derivatives

    Phosphorus-Phosphorus Bonds

    Phosphorus-Oxygen Compounds

    Hypophosphites and Phosphites

    Halophosphates

    Metaphosphates and Phosphates

    Hypophosphates and Diphosphates

    Peroxiphosphoric Acids

    Phosphorus-Sulfur Compounds

    Phosphorus-Nitrogen Compounds

    Cyclic Phosphazines

    Cyclic Phosphazines Containing Heteroatoms

    Cyclic and Linear Phosphazenes

    Linear Phosphazenes

    Phosphorus Amides

    Phosphorus Amines

    Hydrazine Derivatives of Halodiphosphines

    P(III) and P(V) Nitroxide Fluorides

    Imides of Phosphorus

    Phosphorus Azides

    Phosphorus-Hydrogen Compounds

    Radicals in Phosphorus Chemistry

    Phosphorus Containing Cage Compounds

    Complexes with Phosphorus Containing Ligands

    References

    Arsenic, Antimony and Bismuth

    General

    Organometallic Compounds of Arsenic, Antimony and Bismuth

    Chelating Agents

    Tertiary Arsines

    Heteroatom-Arsenic Species

    Cyclic Compounds

    Tertiary Antimony

    Antimony(V) Compounds

    Bismuth

    Inorganic Arsenic, Antimony and Bismuth Compounds

    Arsenic

    Antimony

    Bismuth

    Acceptor Compounds Involving the Group V Elements

    References

    The Chalcogens

    Oxygen

    Singlett Oxygen

    Oxygen Compounds

    Sulfur

    Polysulfur Compounds

    Sulfur(II) Compounds

    Sulfur-Nitrogen Ring Compounds

    Sulfur(IV) Compounds

    Sulfur(VI) Compounds

    Selenium

    Selenium(II) Compounds

    Selenium(IV) Compounds

    Selenium(VI) Compounds

    Tellurium

    Polonium

    References

    Fluorine

    General

    New Fluorinating Agents and Techniques

    Xenon-Fluorine Compounds

    Chlorine-Fluorine Compounds

    Sulfur-Fluorine Compounds

    Nitrogen-Fluorine Chemistry

    Carbon-Fluorine Compounds

    Fluoro Polymers

    Silicon-Fluorine Chemistry

    References

    Halogens and Pseudohalogens

    General

    Halogens

    Fluorine

    Chlorine

    Bromine

    Iodine

    Miscellaneous

    Pseudohalogen Compounds of Main Group Elements

    Group II

    Group III

    Group IV

    Group V

    Group VI

    Compounds with Transition Metals

    Compounds with Inner Transition Metals

    References

    Noble Gases

    General Remarks

    Argon, Krypton

    Xenon

    References

    Simple and Complex Metal Hydrides of Main Groups I-III

    Introduction

    Simple Hydrides of Groups I and II

    Sodium (and Other Alkali Metal) Hydrides

    Beryllium Hydride Tertiary Amine Complexes

    Magnesium Hydride

    Complex Hydrides of Groups I and II

    Tetra Hydrido-Beryllates

    Complex Magnesium Hydrides

    Lithium Strontium Hydride

    Aluminum Hydride

    Amine Adducts of Aluminum Hydride

    Group I Metal Hydridoaluminates

    Lithium Hydridoaluminates

    Sodium Hydridoaluminates

    Group II Metal Hydridoaluminates

    Hydridogallates

    References

    New Techniques and Reagents in Coordination Chemistry

    Synthesis of Low-Valent Metal Complexes

    Zerovalent Metal Complexes at Intermediates

    Carbonyls

    Phosphine Complexes

    Nitrosyl Complexes

    Electrochemical Syntheses

    Metal Complexes in Normal Oxidation States

    Intermediates with Weakly Coordinated Solvents

    Redox Catalysis

    Carboxylate Complexes

    Complexes of Neutral Acetylacetone

    Dinitrogen Complexes

    Metal Complexes in Higher Oxidation States

    References

    Stabilizing Effects of Large Counter-Ions

    Introduction

    Lattice Dominating

    Lattice Energy Limiting

    Insulating Effects

    Polarization Effects

    Shape and Charge Effects

    Large Cations

    Hydrogen Bonded Complex Ions

    Anionic Boron Complexes

    Nitrato Complexes

    The Polyhalide Ions

    Tellurocyanate Salts

    Counter-Ion Effects in Linkage Isomerism

    Silver Complexes

    Indium Complexes

    Tricoordinated Group IV Metals and Their Complexes

    Pentacoordinated Group IV Metals

    Group V

    Group VI

    Lanthanate Complexes

    Actinides

    Carbonyl and Cyano Complexes

    Transition Metal Complexes

    Cationic Complexes

    Stability

    References




Product details

  • No. of pages: 336
  • Language: English
  • Copyright: © Academic Press 1973
  • Published: January 1, 1973
  • Imprint: Academic Press
  • eBook ISBN: 9781483213873

About the Editors

Kurt Niedenzu

Hans Zimmer

Ratings and Reviews

Write a review

There are currently no reviews for "Annual Reports in Inorganic and General Syntheses-1972"