A Critical Review of Equilibrium Data for Proton- and Metal Complexes of 1,10-Phenanthroline, 2,2'-Bipyridyl and Related Compounds

A Critical Review of Equilibrium Data for Proton- and Metal Complexes of 1,10-Phenanthroline, 2,2'-Bipyridyl and Related Compounds

Critical Evaluation of Equilibrium Constants in Solution: Stability Constants of Metal Complexes

1st Edition - January 1, 1978

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  • Author: W.A.E. McBryde
  • eBook ISBN: 9781483139845

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Description

A Critical Review of Equilibrium Data for Proton- and Metal Complexes of 1,10-Phenanthroline, 2,2'-Bipyridyl and Related Compounds is a compilation of acidity constants for the 1,10-phenanthrolinium and 2,2'-bipyridinium ions and their derivatives, as well as stability constants for metal complexes formed by the conjugate bases of these. These equilibrium data are critically examined. This monograph includes values determined in non-aqueous or mixed solvents, as well as those for a large number of ""mixed"" metal complexes incorporating these bases and a second ligand. The survey also contains known values for the enthalpies and entropies of formation for the proton- and metal-ion complexes. The compilation indicates the conditions under which the equilibrium constants apply and the methods by which they were determined. The acid-base properties of the compounds are represented by the acidity constant of the phenanthrolinium or bipyridinium ion expressed as a pK value. Nearly all the values listed were obtained either potentiometrically or spectrophotometrically, both of which depend fundamentally on measurements of pH or hydrogen-ion concentration. This book will be of value to chemists.

Table of Contents


  • Introduction

    Acidity Constants

    Stability Constants of Metal Complexes

    Mixed Complexes

    Other Ternary or Higher Complexes

    Enthalpies and Entropies of Formation

    Table I.1 Acidity Constants for the Phenanthrolinium Ion

    Table I.2 Acidity Constants for the Bipyridinium Ion

    Table I.3 Acidity Constants for Substituted Phenanthrolinium Ion

    Table I.4 Acidity Constants for Substituted Bipyridinium Ion

    Table I.5 Second Stage Protonation of Phenanthroline and Bipyridyl

    Table II.1 Stability Constants of Metal Complexes (Single Ligand), 1,10-Phenanthroline

    Table II.2 Stability Constants of Metal Complexes (Single Ligand), 2,2'-Bipyridyl

    Table II.3 Stability Constants of Metal Complexes (Single Ligand), Substituted Phenanthrolines

    Table II.4 Stability Constants of Metal Complexes (Single Ligand), Substituted Bipyridyls

    Table III.1 Acidity Constants of Phenanthrolines, Mixed or Non-Aqueous Solvents

    Table III.2 Acidity Constants of Bipyridyls, Mixed or Non-Aqueous Solvents

    Table III.3 Stability Constants of Phenanthroline Metal Complexes (Mixed or Non-Aqueous Solvents)

    Table III.4 Stability Constants of Bipyridyl Metal Complexes (Mixed or Non-Aqueous Solvents)

    Table IV.1 Equilibrium Constants of Mixed Complexes with 1,10-Phenanthroline

    Table IV.2 Equilibrium Constants of Mixed Complexes with 2,2'-Bipyridyl

    Table V.1 Equilibrium Constants for Complex Adducts, etc. with 1,10-Phenanthroline

    Table V.2 Equilibrium Constants of Complex Adducts, etc. with 2,2'-Bipyridyl

    Table VI.1 Enthalpies and Entropies of Complex Formation, 1,10-Phenanthroline

    Table VI.2 Enthalpies and Entropies of Complex Formation, 2,2'-Bipyridyl

    Table VI.3 Enthalpies and Entropies of Complex Formation, Substituted Phenanthrolines

    Table VI.4 Enthalpies and Entropies of Complex Formation, Substituted Bipyridyls

Product details

  • No. of pages: 84
  • Language: English
  • Copyright: © Pergamon 1978
  • Published: January 1, 1978
  • Imprint: Pergamon
  • eBook ISBN: 9781483139845

About the Author

W.A.E. McBryde

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