Table of ContentsAbbreviations. Introduction. Graphical Abstracts of Reaction Numbers (RXN). Reactions Catalyzed by Palladium Complexes: Cross-Coupling of Organometallics with RX Derivatives. Cross-Coupling of Organometallicswith RCOX Derivatives. Cross-Coupling of Siloxycyclopropanes with RX and RCOX Derivatives. Cross-Coupling of Terminal Alkynes with RX Derivatives. Intermolecular HECK Reaction. Intramolecular HECK Reaction. Intramolecular Coupling of Di(Vinyl Halides). Tandem HECK-Anion Capture Process of Alkenes, Alkyenes, Alkynes, Allenes and Dienes. Tandem HECK-Anion Capture Process of Norbonene and Related Compounds. Tandem Arylsulfonation-Cyclization Process. Tandem Cyclization-Anion Capture (-Carbonylation) Processof Alkenes and Alkynes. Tandem Cyclization-Anion Capture (-Carbonylation) Process of Ene-Vinyl, Ene-Aryl, and Ene-Alkyl Halides. Tandem Cyclization-Anion Capture Process of Yne-Vinyl and Yne-Aryl Halides. Hydroarylation and Hydrovinylation of Alkenes andAlkynes. Reduction of Alkenes. Semihydrogenation of Alkynes and 1,3-Dienes. Hydroboration, Hydrogennyladon, Hydrosilylation and Hydrostannation of Alkynes, Allenes, Dienes, and Enynes. Hydroselenation of Alkynes. 1,4-Disilyation of Conjugated Enones. Hydrocarboxylation, Hydrocarboalkoxylation and Hydrocarboamination of Alkenes and Alkynes. Tandem Carbonylation-Arylation with Alkynes. 1,2-Dimetallation of Alkynes and Alkenes and Related Reactions. 1,2-Dimetallation of Isonitriles. 1,2-Dimetallation of Allenes. Coupling of Aryl Derivatives with Alkenes Involving a Pd(II) Catalyst. Homocoupling of Aryl and Vinyl Derivatives. Codimerization of Alkynes. Codimerization of Terminal Alkynes with Allenes. Codimerization of Alkynes and Allyl Halides. Cyclopropanation of Alkenes and 1,3-Dienes by Diazomethane. Rearrangement of (-Hydroxy Diazo Compounds. Substitution, Addition, and Elimination on Pro-(-Allyl Substrates. [3,3]-Sigmatropic Rearrangement and [1,3]-Shift on Allylic Derivatives. 1,3-Diene Monoepoxide Rearrangement. Ring Extension of Cyclobutane Derivatives. [3+2], [3+4], [3+6], [1+2] Cycloadditions. Intramolecular Ene-Like Reactions. Cyclization of Hexatrienolate Derivatives. Amination or Amidation of Alkenes. Alkoxylation of Alkenes and Alkynes. Acetalization of Alkenes. Allylic Acyloxylation of Cycloalkenes. Tandem Acyloxylation-Cyclization of 1,5-Dienes. Tandem Acycloxychlorination-Cyclization of 1,6-Dienes. 1,4-Acycloxychlorination of 1,3-Dienes. 1,4-Diacyloxylation of 1,3-Dienes and Related Reactions. Intramolecular Amination, Alkoxylation of Acyloxylation of Alkynes. Tandem Intramolecular Amination, Alkoxylation, or Acyloxylation-Allylation of Alkynes and Allenes. Tandem Intramolecular Amination, Alkoxylation, or Acyloxylation-Carbonylation of Alkynes. Intramolecular Amination or Alkoxylation of Alkenes. Tandem Intramolecular Amination or Alkoxylation-Carbonylation of Alkenes and Allenes. Reductive Cyclization with Diynes and Enynes. Cycloisomerization of Diynes and Enynes. Cycloaddition of Aziridines with Carbodiimides. Telomerization of 1,3-Dienes with Nucleophiles. WACKER Process. Preparation of Ketones from Alcohols or Derivatives via a (-Hydride Elimination. Preparation of ((-Unsaturated Carbonyl Derivatives via a (-Hydride Elimination. Preparation of (-Diketones Derivatives via an Oxidative Rearrangement of a Propargyl Acetate. Carbonylation. Isomerization of Alkynes. Addition of Thiols to Alkynes. Preparation of Allylic Acetates from Alkynes by Tandem Redox-Addition. Tandem Cyclization-Capture Process of Enynes. Aldol-Like Condensation of Enol Esters with Aldehydes. Addition of Fluoroalkyl Iodides to Alkenes or Alkynes via a Pd(I) Species. Intermolecular Tandem Carbonylation-Coupling-Cyclization Process of Aryl Halides with Terminal Alkynes.Intramolecular Coupling of Aryl Halides with Arenes. Tandem Intramolecular Alkoxylation-Vinylation of Alkenes. Carbonylative [2+2] Cycloaddition. Dicarboalkoxylation of Alkenes. Addition of Pronucleophiles on 1,3-Dienes or Allenes. Tandem Cycloisomerization-Cycloaddition of Dienynes with 1,3-Dienes via Metallodienes. Acylcyanation of Terminal Alkynes. 1,4-Carbochlorination of 1,3-Dienes. Tandem Chlorination-Cyclization and Tandem Chlorination-Carbonylation-Cyclization of 1,6-Enynes. Intramolecular Cyclocarbonylation of Alkenes. Abbreviations and Symbols. Notes. Subject Index.