Selected Papers. Fundamental Concepts of Complexes with Encapsulated Metal Ions. Classification of macropolycyclic ligands. Nomenclature, abbreviations and classification of clathrochelates.
Synthesis of Clathrochelates. Synthesis of macrobicyclic tris-dioximates. Synthesis of macrobicyclic phosphorus-containing d-metal tris-diiminates. Synthesis of sepulchrates and sarcophaginates. Synthesis of polyene and other types of clathrochelate complexes.
Spatial and Electronic Structure of Clathrochelates. Sarcophaginates and sepulchrates. Macrobicyclic phosphorus-containing d-metal tris-diiminates. Macrobicyclic d-metal tris-dioximates. Polyene and other types of clathrochelate complexes.
Kinetics and Mechanism of Synthesis and Decomposition of Clathrochelates. Experimental approaches. Reactions of boron-capped iron(II) dioximates. Reactions of sarcophaginates and sepulchrates. Properties of Clathrochelates
. Ion association of clathrochelates in solution. Electron-transfer processes in macrobicyclic complexes. Photochemical properties of macrobicyclic complexes.
Application Possibilities of Clathrochelate Chemistry. New Types of Clathrochelates: Perspectives of Synthesis
. Ribbed-functionalized d
-metal tris-dioximates. Mononuclear and polynuclear &agr;-dioximates and -&agr;oximehydrazonates obtained by capping with several p
-block elements (arsenic, bismuth, and some others), d
- and f
-elements. Macrobicyclic Schiff bases formed by capping with Lewis acids. Clathrochelate complexes formed by the analogs of &agr;-dioximes and &agr;-oximehydrazones. Superclathrochelate structures.