Advances in Physical Organic Chemistry
- Thomas Tidwell, University of Toronto, Ontario, Canada
- John Richard, Department of Chemistry, University of Buffalo, NY, U.S.A.
For organic and physical chemists and biochemists.
- Published: December 2002
- Imprint: ACADEMIC PRESS
- ISBN: 978-0-12-033537-4
Table of Contents
Quantitative thermodynamic criteria of stability in the gas phase. Definitions and experimental techniques. The specific case of carbocations.
Uncertainties.Thermodynamics and structure of selected species. Carbocations C1 to C4. Aliphatic carbocations with more than five carbon atoms. Cyclic species without formal systems. Cyclopropyl-substituted carbonations. Secondary and tertiary carbocations derived from cage hydrocarbons. Carbenium ions with formal systems. Two-electron aromatic and homoaromatic ions. Six-electron aromatic ions. Phenyl-substituted carbocations. Solution reactivity. Thermodynamic properties. Reaction kinetics.