SEPARATION OF ISOTOPES OF BIOGENIC ELEMENTS IN TWO-PHASE SYSTEMS
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By Boris Andreev, University of Chemical Technology of Russia, Russia
Description Separation of Isotopes of Biogenic Elements provides a detailed overview of this area of research covering all aspects from the value
of isotope effects to their practical use (equilibrium single-stage isotope effect - kinetics and mass transfer – multiplication of the
single-stage isotope separation factor - technological peculiarity of processes) with the purpose of extraction from the natural mixture
of the enriched and highly concentrated isotopes. In contrast to traditional books on the theory of isotope separation, the theoretical
part of the book describes separation in two-phase processes in counter-flow columns. The experimental part of the book presents systematic
analysis of specialists in the field of isotope separation in counter-flow columns. This book will be of interest to scientists, engineers
and technical workers engaged in isotope separation processes and isotope application in nuclear physics, medicine, agro-chemistry, biology
and other areas. This book may also be used in teaching theory and practical aspects in courses on physical chemistry and Isotope separation
of light elements by physicochemical methods.
Audience
For scientists, engineers and technical workers engaged in isotope separation processes and isotope applications. Also useful for teaching
theory and practical aspects in courses on physical chemistry and Isotope separation of light elements by physicochemical methods.
Contents
Chapter 1. Theory of Isotope Separation in Counter-Current Columns: General Review
1.1 Separation Factor
1.2
Kinetics of CHEX Reactions and Mass Exchange in Counter-Current Phase Movement
1.3 Stationary State of the Column with Flow Reflux
1.4 Unsteady State of the Column and Cascades of Columns
1.5 Separation Column Contactors
Chapter 2.
Hydrogen Isotope Separation by Rectification
2.1 D2O Production by Water Rectification
2.2 Heavy Water Production
by Ammonia Rectification
2.3 Heavy Water Production by Cryogenic Rectification of Hydrogen
2.4 Isotope Extraction and Concentration
of Tritium
Chapter 3. Hydrogen Isotope Separation by Chemical Isotope Exchange Method in Gas-Liquid Systems
3.1 Two-Temperature Method and Its Main Features
3.2 Two-Temperature Hydrogen-Sulphidous Method
3.3 Hydrogen-Ammonia and Hydrogen-Amine
Systems
3.4 Water-Hydrogen System
Chapter 4. Isotope Separation in Systems with Gas and Solid Phases
4.1 Isotope Equilibrium
4.2 Kinetics of Isotope Exchange and Mass Transfer in Separation Columns
4.3 Counter-current
Isotope Separation Processes
4.4 Application of the Solid-phase Systems for the Separation of Tritium-Containing Hydrogen Isotope
Systems
Chapter 5. Carbon Isotope Separation
5.1 Carbon Isotope Separation by Rectification
5.2 Cabon
Isotope Separation by Chemical Exchange Method
Chapter 6. Nitrogen Isotope Separation
6.1 Nitrogen Isotope
Separation by Rectification
6.2 Nitrogen Isotope Separation by Chemical Isotope Exchange
6.3 Comparison of Nitrogen Isotope
Separation Techniques
6.4 Large-scale Production Characteristics
Chapter 7. Oxygen Isotope Separation
7.1 Oxygen Isotope Separation by Rectification
7.2 Oxygen Isotope Separation by Chemical Exchange Method
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