Description During the past fifteen years there has been a dramatic increase in the number of different surfaces whose structures have been determined
experimentally. For example, whereas in 1979 there were only 25 recorded adsorption structures, to date there are more than 250. This
volume is therefore a timely review of the state-of-the-art in this dynamic field.
Chapter one contains a compilation of the structural
data base on surfaces within a series of tables that allows direct comparison of structural parameters for related systems. Experimental
structural trends amongst both clean surfaces and adsorbate systems are highlighted and discussed.
The next chapter outlines the successes
of local density functional theory in predicting the relaxations and reconstructions of clean metal and semiconductor surfaces, and the
behaviour of adsorbates such as hydrogen, oxygen and alkali elements on metal surfaces, thereby explaining some of the experimental trends
observed within the database. These ab initio density functional calculations are of ground state properties at the absolute
zero of temperature.
Chapter three provides an introduction to finite temperature effects in a pedagogical review of current statistical
mechanical treatments of phase transitions at surfaces, many of which display the prominent role of fluctuations or non-mean field behaviour.
The final chapter discusses the relationship of the reactivity of a surface to its morphology and composition, which is particularly
relevant to a fundamental understanding of catalysis.
Contents Preface.
Surface Crystallography: The Experimental Data Base (P.J. Rous). Abstract. Introduction. Metals. Semiconductors.
Graphite and diamond surfaces. Compounds. Selected bibliography. Acknowledgements. References.
Theory of Surface Structure and
Bonding (J.E. Inglesfield). Abstract. Introduction. Solving the Schrödinger equation at the surface. Forces and optimization.
Clean metal surfaces. Adsorbates on metals. Semiconductor surfaces. Conclusions. Acknowledgements. References.
Phase Transitions
at Surfaces (K. Binder). Abstract. Introduction: surface phase transitions versus transitions in the bulk. Phenomenological
theory of phase transitions: a brief review. Surface effects on bulk phase transitions. Discussion. Acknowledgements. References.
Surface
Structure and Reactivity (M. Bowker). Abstract. Introduction. Thermodynamic considerations. Adsorption. Desorption. Surface
diffusion. Surface reactions. Structure dependence of reactivity. Modification of surface reactivity: poisoning and promotion. Conclusions.
References.
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