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| THE LANGUAGE OF SHAPE
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The Role of Curvature in Condensed Matter: Physics, Chemistry and Biology
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By
S. Hyde, Australian National University, Canberra, Australia
Z. Blum
T. Landh
S. Lidin, University of Lund, Sweden
B.W. Ninham, Australian National University, Canberra, Australia
S. Andersson, Sandviks Forskningsinstitut, S-380 74 Löttorp, Sweden
K. Larsson, KL Chem AB, S-237 34 Bjärred and Camurus Lipid Research, S-223 70 Lund, Sweden
Description
This book develops the thesis that structure and function in a variety of condensed systems - from the atomic assemblies in inorganic
frameworks and organic molecules, through molecular self-assemblies to proteins - can be unified when curvature and surface geometry
are taken together with molecular shape and forces. An astonishing variety of synthetic and biological assemblies can be accurately modelled
and understood in terms of hyperbolic surfaces, whose richness and beauty are only now being revealed by applied mathematicians, physicists,
chemists and crystallographers. These surfaces, often close to periodic minimal surfaces, weave and twist through space, carving out
interconnected labyrinths whose range of topologies and symmetries challenge the imaginative powers.
The book offers an overview of
these structures and structural transformations, convincingly demonstrating their ubiquity in covalent frameworks from zeolites used
for cracking oil and pollution control to enzymes and structural proteins, thermotropic and lyotropic bicontinuous mesophases formed
by surfactants, detergents and lipids, synthetic block copolymer and protein networks, as well as biological cell assemblies, from muscles
to membranes in prokaryotic and eukaryotic cells. The relation between structure and function is analysed in terms of the previously
neglected “hidden variables” of curvature and topology. Thus, the catalytic activity of zeolites and enzymes, the superior material
properties of interpenetrating networks in microstructured polymer composites, the transport requirements in cells, the transmission
of nerve signals and the folding of DNA can be more easily understood in the light of this.
The text is liberally sprinkled with figures
and colour plates, making it accessible to both the beginning graduate student and researchers in condensed matter physics and chemistry,
mineralogists, crystallographers and biologists.
Contents
Preface. 1. The Mathematics of Curvature. 2. The Lessons of Chemistry. Inorganic Chemistry: From the discrete lattice of crystal symmetry
to the continuous manifolds of differential geometry. Organic Chemistry: The shape of molecules. 3. Molecular Forces and Self–Assembly.
4. Beyond Flatland. The Geometric Forms due to Self–Assembly. 5. Lipid Self–Assembly and Function in Biological Systems.
Self-association of lipids in an aqueous environment. Cell membranes. 6. Folding and Function in Proteins and DNA. 7. Cytomembranes and
Cubic Membrane Systems Revisited. 8. Some Miscellaneous Speculations. Templating. Supra self-assembly. Index.
| Bibliographic details |
Hardbound, 0 pages, publication date: NOV-1996
ISBN-13: 978-0-444-81538-5
ISBN-10: 0-444-81538-4
Imprint: ELSEVIER
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| Price and Ordering |
Price:
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USD 330
EUR 237.95
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Last update: 4 Sep 2009
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