Transition Metal Organometallics in Organic Synthesis

Transition Metal Organometallics in Organic Synthesis

Organic Chemistry: A Series of Monographs, Vol. 33.2

1st Edition - January 28, 1978

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  • Editor: Howard Alper
  • eBook ISBN: 9781483215921

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Description

Transition Metal Organometallics in Organic Synthesis, Volume II covers chapters on the applications of arene and alkyne complexes, as well as cluster compounds, in organic synthesis. The book discusses the potential utility of transition metal-alkyne complexes and derived cluster compounds as reagents in organic synthesis, as well as the complexation reactions of arenes. The text also describes the oxidation, reduction, rearrangement, and other synthetically useful processes. Chemists will find the book invaluable.

Table of Contents


  • List of Contributors

    Preface to Volume I

    Preface to Volume II

    1 The Potential Utility of Transition Metal-Alkyne Complexes and Derived Cluster Compounds as Reagents in Organic Synthesis

    I. Introduction

    II. Bonding and Structure of Metal-Alkyne Complexes

    III. Preparation of Metal-Alkyne Complexes

    IV. Reactions of Alkyne Complexes

    V. Synthesis and Reactions of Alkylidynetricobalt Nonacarbonyl Complexes

    References

    2 Arene Complexes in Organic Synthesis

    I. Introduction

    II. Arene Ligands as Displacing Agents in Organometallic Complexes

    III. Electronic Influence of the Cr(CO)3 Group

    IV. Side-Chain Reactions of a Ring Complexed by Cr(CO)3

    V. Use of Chromium Carbonyl Groups for the Selective Activation of Aromatic Side Chains

    VI. Reactivity of an Aromatic Moiety Complexed by Cr(CO)3

    VII. Phenylation of Nucleophiles via Neutral Organometallic Intermediates

    VIII. Electrophilic Reactivity of Cationic Arene Complexes

    IX. Stereochemical Consequences of the Transition Metal Complexation of an Arene

    X. Aromatization of Diene Structures via Complexation

    XI. Ortho-Metallated Arènes. New Syntheses of Specific Arene Positional Isomers. Carbonylation

    XII. Arene Complexes as Catalysts

    References

    3 Oxidation, Reduction, Rearrangement, and Other Synthetically Useful Processes

    I. Oxidation

    II. Reduction

    III. Addition and Condensation Reactions

    IV. Elimination Processes

    V. Cleavage Reactions

    VI. Rearrangements

    VII. Other

    References

    Author Index

    Subject Index






Product details

  • No. of pages: 200
  • Language: English
  • Copyright: © Academic Press 1978
  • Published: January 28, 1978
  • Imprint: Academic Press
  • eBook ISBN: 9781483215921

About the Editor

Howard Alper

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