Transition metal Organometallics In Organic Synthesis

Transition metal Organometallics In Organic Synthesis

2nd Edition - January 28, 1976

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  • Editor: Howard Alper
  • eBook ISBN: 9780323161930

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Description

Transition Metal Organometallics in Organic Synthesis: Volume I reviews the literature in the field of organic synthesis with a focus on the most effective synthetic transformations. The text covers topics such as the general considerations in organic synthesis, C-C and C-X bond formations, and the isomerization and reorganization reactions of olefins. Also covered are topics such as displacement reactions with transition metal complexes, electrophilic reactions of organopalladium complexes, carbonylation reactions, and metal-carbene complexes — its structure, spectra, bonding, and direct synthesis. The book is recommended as a reference for chemists and inorganic chemists who would like to learn the applications of organometallic complexes as reagents and catalysts.

Table of Contents


  • List of Contributors

    Preface

    1 Transition Metal Complexes of Olefinic Compounds

    I. Introduction

    II. General Considerations in Organic Synthesis Preparation of Starting Materials

    III. C-C Bond Formation

    IV. C-X Bond Formation (X = Element Other than Carbon)

    V. Isomerization and Reorganization Reactions of Olefins

    VI. Stabilization of Unstable Intermediates

    VII. Transition Metals as Protecting, Activating, and Directing Groups

    VIII. Rearrangements and the Synthesis of Some Unusual Compounds

    IX. Stereochemical Implications

    References

    2 Coupling Reactions via Transition Metal Complexes

    I. Coupling Reactions of σ- and π-Bonded Organic Ligands

    II. Displacement Reactions with Transition Metal Complexes

    III. Nucleophilic Reactions of Organotransition Metal Complexes with Carbonyl and Epoxy Compounds

    IV. Electrophilic Reactions of Organopalladium Complexes

    V. Addition Reactions of Organometallic Complexes across Unsaturated Carbon-Carbon Bonds

    VI. Carbonylation Reactions

    VII. Miscellanous

    References

    3 Metal-Carbene Complexes in Organic Sythesis

    I. Introduction

    II. Structure, Bonding, and Spectra of Metal-Carbene Complexes

    III. Direct Synthesis of Metal-Carbene Complexes

    IV. Modification and Elaboration of the Structure of Metal-Carbene Complexes

    V. Release of the Carbene Ligand from Metal Complexes

    VI. Application of Metal-Carbene Complexes in Organic Synthesis

    References

    Author Index

    Subject Index


Product details

  • No. of pages: 270
  • Language: English
  • Copyright: © Academic Press 1976
  • Published: January 28, 1976
  • Imprint: Academic Press
  • eBook ISBN: 9780323161930

About the Editor

Howard Alper

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