Time-Resolved Vibrational Spectroscopy - 5th Edition - ISBN: 9780120662807, 9780323162210

Time-Resolved Vibrational Spectroscopy

5th Edition

Editors: George Atkinson
eBook ISBN: 9780323162210
Imprint: Academic Press
Published Date: 28th January 1983
Page Count: 418
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Time-Resolved Vibrational Spectroscopy covers the proceedings of the International Conference on Time-Resolved Vibrational Spectroscopy, convened in Lake Placid, New York on August 16-20, 1982. This book is organized into six sections encompassing 51 chapters. The first section deals with the theoretical and computational developments concerning Raman scattering and two-photon and optical spectroscopies. Section II focuses on the instrumentation and techniques of various time-resolved vibrational spectroscopies (TRVS), such as Raman techniques, stroboscopic interferometry, and infrared multiphoton. Sections III and IV deal with the chemical (ground and excited states) and biochemical systems of TRVS. The concluding sections discuss the theoretical principles and methods of observation of nonlinear Raman spectroscopy and surface-enhanced and colloidal Raman scattering. This book is of value to chemists, spectroscopists, and photobiologists.

Table of Contents




Section I Theoretical and Computational Developments

Some Theoretical Considerations Concerning Raman Scattering

Intermediate Gauge Formulation of Two-Photon Spectroscopies

The Local Mode Picture of Molecular Vibrations

Advantages of the Time Correlator Theory of Resonance Raman Scattering

On the Interaction Operator in the Optical Spectroscopies: Position vs. Momentum

Semiclassical Simulation of Vibronic Processes

Normal Coordinate Analysis of Polyene Chains for Interpreting the Vibrational Spectra of Transient and Less Stable Species

Spectra from Molecular Dynamics

Section II Instrumentation and Techniques

Stimulated Raman Techniques for Time-Resolved Spectroscopy of Gas-Phase Molecules

Time-Resolved Study of Subpicosecond Orientational Relaxation in Molecular Liquids

Dynamic Measurements of Gas Properties by Vibrational Raman Scattering: Applications to Flames

Time-Resolved Photoacoustic Detection of Collisional Relaxation of Vibrationally Excited HD Molecules

Stroboscopic Interferometry: A Means to Follow Broadband Infrared Phenomena Using an FT-IR Spectrometer

Infrared Multiphoton Excited Visible Luminescence from Hexafluorobenzene

Difference Raman Spectroscopy with a Stopped-Flow Device

High Overtone Vibrational Spectrum of SF6: Evidence for Localized Vibrations

Vibrational Energy Transfer Rate Constants from the Thermal Lens

Slowing of the Vibrational Dephasing Time by Hydrogen Bonding in Glycerol

Time-Resolved V-T Energy Transfer Measurements in Iodine Monofluoride

Section III Chemical Systems: Ground and Excited States

Raman Scattering from Excited States with Lifetimes into the Femtosecond Range

Resonance Raman Spectroscopy of the Electronically Excited States of Transition Metal Bipyridine Complexes

Spatial and Time-Resolved Resonance Raman Spectra of Excited Electronic States of the Uranyl Ion

Time-Resolved Resonance Raman Spectra of Excited 3B2 Phenanthrene

Time-Resolved Resonance Raman Spectra of the Lowest Triplet State of N,N,N',N'-Tetramethyl-P-Phenylenediamine in Solution

Oxidation Reaction of Excited Triplet p-Benzoquinone

Resonance Raman Spectra and Vibrational Analyses of Reaction Intermediates

Photochemically Induced Electron Transfer Reactions of trans-Stilbene

Electron Transfer Reactions in Stilbene Isomers

Time-Resolved Raman Studies of Radiation-Produced Radicals

Raman Spectra of Phenoxy Radicals

The Electronic and Resonance Raman Spectroscopy of the Inorganic Transients S2-,S3-, and Se2- Stabilized in Ultramarine

Section IV Biochemical Systems

Time-Resolved Resonance Raman Spectroscopy of the K610 and O640 Photointermediates of Bacteriorhodopsin

Time-Resolved Resonance Raman Studies of the Photochemical Cycle of Bacteriorhodopsin

Resonance Coherent Anti-Stokes Raman Spectroscopy of the Κ Intermediate in the Bacteriorhodopsin Photocycle

Resonance Raman Spectra of Photochemical Picosecond Transients: Method and Application to Study Bacteriorhodopsin Primary Processes

Picosecond Events in Biological Processes

Applications of Time-Resolved Resonance and Raman Spectroscopy in Radiation Chemistry and Photobiology: Structure and Chemistry of Carotenoids in the Excited Triplet State

Influence of Excitation Wavelength on the Time-Resolved Resonance Raman Spectroscopy of Deoxy Heme Proteins

Structure and Dynamics in the Photolysis of CO- and O2-Hemoglobin, Monitored by Time-Resolved Resonance Raman Spectroscopy

Structure-Function Relationships in Hemoglobin: Transient Raman Studies

Resonance Raman Spectra of Photodissociated Carbonmonoxy Hemoglobin (Hb*): Room Temperature Transients and Cryogenically Trapped Intermediates

Time-Resolution by Transient Chromophore Creation: Defining the Scissile Bonds in an Enzyme-Substrate Complex to 0.03 Å

Time-Resolved Fluorescence Spectra of Chlorophyll-A Dimers and Aggregates Using Selective Fluorescence Quenchiiig

Section V Nonlinear Raman Spectroscopy

Excited State Population Effects on Coherent Raman Spectroscopy

New Results on Vibrational Dephasing and Population Relaxation from Picosecond Techniques

Raman Spectra of Short-Living Molecular States by CARS

Resonance CARS of Excited Molecules

Section VI Surfaced - Enhanced and Colloidal Raman Scattering

Surface Enhancement Mechanisms

Time-Resolved Studies of Electrochemical SERS: The Pyridine / Cl- / Ag Model System

Combined Surface-Enhanced and Resonance Raman Scattering by Dabsyl Aspartate on Colloidal Silver

Transient Raman Scattering Studies of Chemical Kinetics in Aqueous Micellar and Semiconductor Colloidal Solutions


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© Academic Press 1983
Academic Press
eBook ISBN:

About the Editor

George Atkinson