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Theory of Experiments in Paramagnetic Resonance - 1st Edition - ISBN: 9780080161570, 9781483186689

Theory of Experiments in Paramagnetic Resonance

1st Edition

International Series of Monographs in Natural Philosophy

Author: Jan Talpe
Editor: D. ter Haar
eBook ISBN: 9781483186689
Imprint: Pergamon
Published Date: 1st January 1971
Page Count: 272
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International Series of Monographs in Natural Philosophy, Volume 33: Theory of Experiments in Paramagnetic Resonance discusses the technique for studying materials with unpaired electrons. This book is divided into four chapters. Chapter 1 provides a general introduction to examining matter through applying a magnetic field. The paramagnetic resonance line, such as the HF susceptibility as a function of certain parameters, is analyzed in the next chapter. Chapter 3 deals with the electronic signal that produces the HF susceptibility. The last chapter is devoted to the enhancement of the electronic signal above noise. This volume is beneficial to chemists and students interested in paramagnetic resonance.

Table of Contents

Chapter 1. General Introduction


Chapter 2. The Paramagnetic Resonance Line

1. Introduction

2. The Paramagnetic Resonance Line of an Idealized System

2.1. A Linear Stationary System

2.2. A Causal Passive System

2.3. The Dispersion Relation

2.4. Resonance and Drag

2.5. The Relaxation in a Single Paramagnetic Resonance Line

2.6. The Structure of a Resolved Paramagnetic Resonance Line

3. Information about the Structure and Relaxation in the Paramagnetic Resonance Dispersion and Absorption Line

3.1. Introduction

3.2. Some Mathematics

3.3. Structure: Eigenfrequency (g-Factor)

3.4. Structure: "Spin" Density (Static Susceptibility)

3.5. Relaxation: Characteristic Time (Line Width)

3.6. Relaxation: Correlation (Moments and Asymptotic Expansion)

4. A Single Paramagnetic Resonance Line in Experimental Conditions

4.1. Introduction

4.2. The Components of the Susceptibility Tensor

4.3. Resonance Line as a Function of the Static Field

4.4. Non-Linear System

4.5. Non-Stationary System

5. Composite Lines

5.1. Introduction

5.2. Line Shape Models

5.3. Superposition of Lines

5.4. Inhomogeneous Applied Fields

5.5. Anisotropy Broadening


Chapter 3. The Paramagnetic Resonance Signal

1. Introduction

2. Electromagnetic Fields in a Microwave Structure

2.1. Introduction

2.2. Equations of the Electromagnetic Field

2.3. Standing Waves

2.4. Traveling Waves

2.5. Reflection Coefficient and Admittance

2.6. Field in The Cavity as a Function of the Orthonormal Modes

3. High-Frequency Susceptibility and Cavity Parameters

3.1. Introduction

3.2. Paramagnetic Filling Function for Monochromatic Fields

3.3. The Admittance as a Function of

3.4. Non-Monochromatic Fields

4. Measurement of Cavity Parameters

4.1. Introduction

4.2. Paramagnetic Resonance in the Smith Diagram

4.3. Microwave Circuit Elements

4.4. Spectrometer for a Noiseless Microwave Generator

4.5. Oscillator Noise-Suppression Schemes

4.6. Frequency Conversion

4.7. Compensation Schemes

4.8. Sensitivity


Chapter 4. Signal Enhancement

1. Introduction

2. Noise

2.1. Filter

2.2. Correlation

2.3. Noise through a Filter

3. Signal Modulation Technique

3.1. Frequency Conversion

3.2. Signal-to-Noise Ratio Improvement

3.3. Lock-in Detection. Monochromatic Signals

3.4. Lock-in Detection. Noise

4. Signal Accumulation Technique

4.1. Time of Measurement

4.2. Noise Suppression by Accumulation



Other Titles in the Series


No. of pages:
© Pergamon 1971
1st January 1971
eBook ISBN:

About the Author

Jan Talpe

About the Editor

D. ter Haar

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