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## Description

Theories of Chemistry reviews the theories that underpin chemistry, but yet are not traditionally recognized as such, being normally considered as part of physics. Based on the argument that the needs of chemistry are distinctive, a mathematical structure of topics such as quantum mechanics, relativity theory, thermodynamics and statistical mechanics, suiting the needs of chemistry, is outlined. The subject matter is arranged in a sequence that reveals the foundations of chemistry. Starting from the mathematical basis, the sequence runs through the general concepts (mechanics and wave formalism) and the elementary building blocks, to molecules and macrosystems.
The book is the product of the author's reading of original literature rather than of standard texts. It differs from what is conventionally emphasized because of the different approach that it argues for the recognition of chemistry as an emergent discipline, ultimately based on the properties and structure of space and time. Hence the emphasis on otherwise unexpected topics such as quaternions, lie groups, polarized light, compressed atoms, rydberg atoms, solitons, molecular hydrogen, and phase transitions, amongst others. The topic is the understanding of chemistry from first principles.
The book is self-contained and can be used without reference to other sources.

### Key Features

- All chemisty theories are covered in this one volume.
- The book is self-contained and can be used without reference to other sources.
- Many topics, routinely referred to in advanced chemistry texts, without making them accessible to the non-specialist, are brought together.

### Readership

Theoretical and physical chemists. Physisists. Students and researchers at university and institutional libraries. Private scientists.

## Table of Contents

**Basic Mathematics**Elementary Vector Algebra * Vectors * Sum of Vectors * Scalar Product * Three-dimensional Vectors * Vector Product * Three-vector products * Complex Numbers * N-dimensional Vectors * Quaternions Determinants and Matrices * Matrix Operations * Inverse of a Matrix * Linear Homogeneous Equations * Linear Transformations * Direct Sums and Products Vector Fields * The Gradient * The Laplacian * The Divergence * The Curl * Orthogonal Curvilinear Coordinates * Tensor Analysis Differential Equations * Series Solution of Differential Equations * Separation of Variables * Special Functions

**Group Theory**The Multiplication Table Conjugate Elements and Classes Homomorphis Some examples of symmetry groups * Cayley's theorem Field and Space * Unitary Space * Hilbert Space * The Eigenvalue Problem Representation of Groups * Equivalent representations * Reducible Representations * Orthogonality * Orthogonal Relationships * Direct Product Representations Continuous Groups (Lie Groups) * Representations of a Lie group * Important Lie Groups * Homomorphi

## Details

- No. of pages:
- 570

- Language:
- English

- Copyright:
- © 2003

- Published:
- 24th November 2003

- Imprint:
- Elsevier Science

- Electronic ISBN:
- 9780080519043

- Print ISBN:
- 9780444514912