The Organic Chemistry of Nickel

Organonickel Complexes

1st Edition - January 28, 1974
Author: P.W. Jolly
Language: English
eBook ISBN:
9 7 8 - 0 - 3 2 3 - 1 4 6 9 0 - 6

The Organic Chemistry of Nickel, Volume I: Organonickel Complexes is devoted to a description of the organonickel complexes. The major goal is to provide a reference work, and for… Read more

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The Organic Chemistry of Nickel, Volume I: Organonickel Complexes is devoted to a description of the organonickel complexes. The major goal is to provide a reference work, and for this reason a conventional layout has been adopted with separate chapters devoted to each type of organic ligand. In the interest of readability, known compounds have been assembled in tables at the end of each chapter, thereby allowing the text to be used for discussions of the general chemistry involved and to highlight the special reactions associated with nickel. Conscious of the needs of organometallic chemists, the authors included systems in which no nickel-carbon bond is involved. Among these is a chapter on the tetrakisligand nickel complexes and sections on dioxygen and azobenzene complexes. The nitrosyl complexes and complexes containing a metal-metal bond—topics frequently considered to be part of the domain of the organometallic chemist—have not received individual attention. Tables of the observed bond distances in organonickel complexes are provided as an Appendix; a short list of the more important review articles relevant to each organic ligand can be found at the end of each chapter.

PrefaceIntroductionChapter I. Nickel Tetracarbonyl I. Introduction II. Preparation III. Physical and Thermodynamic Data IV. Structure and Bonding V. Spectral Properties VI. Reactions VII. Mixed-Metal Carbonyl Clusters VIII. Toxicity ReferencesChapter II. Lewis-Base Nickel Carbonyl Complexes I. Introduction II. The Mechanism of Substitution III. Substitution by Group IV-Donor Ligands IV. Substitution by Group V-Donor Ligands V. Substitution by Group VI-Donor Ligands VI. Substitution by Group VII-Donor Ligands ReferencesChapter III. Tetrakisligand Nickel Complexes I. Introduction II. Preparation III. Structure IV. Reactions V. Spectroscopic Properties VI. Tetrakistrifluorophosphine Nickel VII. Coordinatively Unsaturated Ligand-Nickel Complexes References ReviewsChapter IV. Nickel Hydride, Nickel Alkyl, andNickel Aryl Complexes I. Nickel Hydride Complexes: Introduction II. Monoligand Nickel Hydride Complexes III. Bisligand Nickel Hydride Complexes IV. π-Allyl-and π-Cyclopentadienylnickel Hydride Complexes V. Nickel Carbonyl Hydrides and Cationic Nickel Hydrides VI. Nickel Alkyl and -Aryl Complexes : Introduction VII. Ligand-Free Nickel Alkyl and -Aryl Complexes VIII. Monoligand Nickel Alkyl and -Aryl Complexes IX. Bisligand Nickel Alkyl and -Aryl Complexes X. Tris- and Tetrakisligand Nickel Alkyl and -Aryl Complexes XI. π-Allylnickel Alkyl and -Aryl Complexes XII. π-Cyclopentadienylnickel Alkyl and -Aryl Complexes References ReviewsChapter V. Nickel-Olefin and -Alkyne Complexes I. Introduction II. Bonding and Structure III. Nickel-Olefin Complexes Formed by Ethylene and Alkyl- or Aryl-Substituted Olefins IV. Nickel Complexes Formed by Olefins Having Electron-Withdrawing Substituents V. Nickel-Alkyne Complexes VI. Nickel-π-Azo Complexes VII. Nickel-Dioxygen Complexes References ReviewsChapter VI. π-Allyl Nickel Complexes I. Bonding Considerations II. Spectroscopic Properties III. Bis(π-Allyl)Nickel Complexes IV. π-Allyl Nickel X Complexes V. π-Allyl NiX(Ligand) Complexes VI. [π-AllylNi(Lig)3]+ Complexes VII. π-Allylnickel π-Cyclopentadienyl Complexes VIII. Hetero-π-Allylnickel Complexes IX. π-Cyclopropenylnickel Complexes References ReviewsChapter VII. Cyclobutadienenickel Complexes I. Introduction II. Preparation of Cyclobutadienenickel Complexes III. Structural Considerations IV. Reactions of Cyclobutadienenickel Complexes References ReviewsChapter VIII. π-Cyclopentadienyl Nickel Complexes I. Bis-π-Cyclopentadienylnickel (Nickelocene) II. π-Cyclopentadienylnickel Carbonyl and Isonitrile Complexes III. π-Cyclopentadienylnickel Cluster Compounds IV. π-C5H5NiX(Lig) and Related Complexes V. Reaction of Nickelocene with Phosphorus and Sulfur Compounds VI. π-Cyclopentadienylnickel Nitrosyl VII. Nickel-Carborane Complexes References ReviewsChapter IX. Nickel Arene Complexes Text References ReviewsAppendix. Structural Data for Organonickel ComplexesSubject Index