The Organic Chemistry of Nickel
Organonickel Complexes
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The Organic Chemistry of Nickel, Volume I: Organonickel Complexes is devoted to a description of the organonickel complexes. The major goal is to provide a reference work, and for this reason a conventional layout has been adopted with separate chapters devoted to each type of organic ligand. In the interest of readability, known compounds have been assembled in tables at the end of each chapter, thereby allowing the text to be used for discussions of the general chemistry involved and to highlight the special reactions associated with nickel. Conscious of the needs of organometallic chemists, the authors included systems in which no nickel-carbon bond is involved. Among these is a chapter on the tetrakisligand nickel complexes and sections on dioxygen and azobenzene complexes. The nitrosyl complexes and complexes containing a metal-metal bond—topics frequently considered to be part of the domain of the organometallic chemist—have not received individual attention. Tables of the observed bond distances in organonickel complexes are provided as an Appendix; a short list of the more important review articles relevant to each organic ligand can be found at the end of each chapter.
Table of Contents
Preface
Introduction
Chapter I. Nickel Tetracarbonyl
I. Introduction
II. Preparation
III. Physical and Thermodynamic Data
IV. Structure and Bonding
V. Spectral Properties
VI. Reactions
VII. Mixed-Metal Carbonyl Clusters
VIII. Toxicity
References
Chapter II. Lewis-Base Nickel Carbonyl Complexes
I. Introduction
II. The Mechanism of Substitution
III. Substitution by Group IV-Donor Ligands
IV. Substitution by Group V-Donor Ligands
V. Substitution by Group VI-Donor Ligands
VI. Substitution by Group VII-Donor Ligands
References
Chapter III. Tetrakisligand Nickel Complexes
I. Introduction
II. Preparation
III. Structure
IV. Reactions
V. Spectroscopic Properties
VI. Tetrakistrifluorophosphine Nickel
VII. Coordinatively Unsaturated Ligand-Nickel Complexes
References
Reviews
Chapter IV. Nickel Hydride, Nickel Alkyl, and
Nickel Aryl Complexes
I. Nickel Hydride Complexes: Introduction
II. Monoligand Nickel Hydride Complexes
III. Bisligand Nickel Hydride Complexes
IV. π-Allyl-and π-Cyclopentadienylnickel Hydride Complexes
V. Nickel Carbonyl Hydrides and Cationic Nickel Hydrides
VI. Nickel Alkyl and -Aryl Complexes : Introduction
VII. Ligand-Free Nickel Alkyl and -Aryl Complexes
VIII. Monoligand Nickel Alkyl and -Aryl Complexes
IX. Bisligand Nickel Alkyl and -Aryl Complexes
X. Tris- and Tetrakisligand Nickel Alkyl and -Aryl Complexes
XI. π-Allylnickel Alkyl and -Aryl Complexes
XII. π-Cyclopentadienylnickel Alkyl and -Aryl Complexes
References
Reviews
Chapter V. Nickel-Olefin and -Alkyne Complexes
I. Introduction
II. Bonding and Structure
III. Nickel-Olefin Complexes Formed by Ethylene and Alkyl- or Aryl-Substituted Olefins
IV. Nickel Complexes Formed by Olefins Having Electron-Withdrawing Substituents
V. Nickel-Alkyne Complexes
VI. Nickel-π-Azo Complexes
VII. Nickel-Dioxygen Complexes
References
Reviews
Chapter VI. π-Allyl Nickel Complexes
I. Bonding Considerations
II. Spectroscopic Properties
III. Bis(π-Allyl)Nickel Complexes
IV. π-Allyl Nickel X Complexes
V. π-Allyl NiX(Ligand) Complexes
VI. [π-AllylNi(Lig)3]+ Complexes
VII. π-Allylnickel π-Cyclopentadienyl Complexes
VIII. Hetero-π-Allylnickel Complexes
IX. π-Cyclopropenylnickel Complexes
References
Reviews
Chapter VII. Cyclobutadienenickel Complexes
I. Introduction
II. Preparation of Cyclobutadienenickel Complexes
III. Structural Considerations
IV. Reactions of Cyclobutadienenickel Complexes
References
Reviews
Chapter VIII. π-Cyclopentadienyl Nickel Complexes
I. Bis-π-Cyclopentadienylnickel (Nickelocene)
II. π-Cyclopentadienylnickel Carbonyl and Isonitrile Complexes
III. π-Cyclopentadienylnickel Cluster Compounds
IV. π-C5H5NiX(Lig) and Related Complexes
V. Reaction of Nickelocene with Phosphorus and Sulfur Compounds
VI. π-Cyclopentadienylnickel Nitrosyl
VII. Nickel-Carborane Complexes
References
Reviews
Chapter IX. Nickel Arene Complexes
Text
References
Reviews
Appendix. Structural Data for Organonickel Complexes
Subject Index
Product details
- No. of pages: 532
- Language: English
- Copyright: © Academic Press 1974
- Published: January 28, 1974
- Imprint: Academic Press
- eBook ISBN: 9780323146906
About the Author
P.W. Jolly
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