The Chemistry of Nonaqueous Solvents III

The Chemistry of Nonaqueous Solvents III

1st Edition - January 28, 1970

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  • Editor: J.J. Lagowski
  • eBook ISBN: 9780323151030

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The Chemistry of Nonaqueous Solvents, Volume III: Inert, Aprotic, and Acidic Solvents is a compilation of critical surveys of specific solvent systems. The compendium contains discussions on the solution chemistry of sulfur dioxide and acyl halides; the solvent properties of hydrogen sulfide and carboxylic acids; and the Bronsted acid-base behavior in inert organic solvents. Chemists, researchers, and students of chemistry and chemical engineering will find the book a good reference material.

Table of Contents

  • List of Contributors


    Contents of Previous Volumes

    1. Brønsted Acid-Base Behavior in "Inert" Organic Solvents

    I. Introduction

    II. Acid-Base Concepts

    III. Properties and Classification of Solvents

    IV. Self-Association of Nitrogen-Containing Bases through Hydrogen Bonding

    V. Self-Association of Acids through Hydrogen Bonding

    VI. Evidence for Hydrogen Bonding in Ion Pairs

    VII. Hydrogen Bonding of Neutral Proton Acceptors to Cations

    VIII. Hydrogen Bonding of Neutral Proton Donors to Anions

    IX. Acidity and Basicity Scales in "Inert" Solvents

    X. Acid-Base Titrations in "Inert" Organic Solvents


    2. Liquid Sulfur Dioxide

    I. Physicochemical Properties of Sulfur Dioxide

    II. Solvent Purification and Manipulation

    III. Solvent Properties

    IV. Solvent Character and Solution Species

    V. Electrochemical Studies

    VI. Reactions in Liquid Sulfur Dioxide


    3. Acyl Halides as Nonaqueous Solvents

    I. Introduction

    II. Physical Constants

    III. Molecular Structures

    IV. Thermodynamic Properties

    V. Purification of Solvents

    VI. Solubility of Substances

    VII. Solvate Formation

    VIII. Isotopic Exchange Studies

    IX. Solvolytic Reactions

    X. Acid-Base Neutralization Reactions

    XI. Conductometric Titrations

    XII. Visual Titrations

    XIII. Potentiometric Titrations

    XIV. Thermochemical Studies

    XV. Miscellaneous


    4. Liquid Hydrogen Sulfide

    I. Introduction

    II. Preparation and Analysis of H2S

    III. Physical and Chemical Properties

    IV. Solvent Properties

    V. Reactions


    5. Anhydrous Acetic Acid as Nonaqueous Solvent

    I. Introduction

    II. Purification of Acetic Acid

    III. Physical Properties and Structures of Acetic Acid

    IV. Solubility of Salts and Ionic Equilibria in Acetic Acid

    V. Cryoscopic and Ebullioscopic Studies

    VI. Reactions in Acetic Acid

    VII. Electrochemical Studies in Acetic Acid

    VIII. Acid-Base Equilibria in Acetic Acid

    IX. Analytical Chemistry in Acetic Acid


    6. Other Carboxylic Acids

    I. Formic Acid

    II. Propionic Acid

    III. Butyric Acid

    IV. Trifluoroacetic Acid


    Author Index

    Subject Index

Product details

  • No. of pages: 422
  • Language: English
  • Copyright: © Academic Press 1970
  • Published: January 28, 1970
  • Imprint: Academic Press
  • eBook ISBN: 9780323151030

About the Editor

J.J. Lagowski

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