
The Application of Green Solvents in Separation Processes
Description
Key Features
- Provides insights into recent advances in greener extraction and separation processes
- Gives an understanding of alternatives to harmful solvents commonly used in extraction and separation processes, as well as advanced techniques for such processes
- Written by a multidisciplinary group of internationally recognized scientists
Readership
Environmental scientists, analytical chemists, green chemistry researchers, biochemists, engineers, bioanalytical chemists, environmental engineers
Table of Contents
List of Contributors
Section I: Introduction
Chapter 1. Initial Considerations
- Abstract
- 1.1 The Need to Use Solvents
- 1.2 Traditional Solvents
- 1.3 Green Solvents
- 1.4 Greener Extraction Techniques
- 1.5 Green Sampling and Sample Preparation
- 1.6 Solvents for Analytical Separations
- 1.7 Concluding Remarks
- Acknowledgments
- References
Section II: Green Solvents
Chapter 2. Water as the First Choice Green Solvent
- Abstract
- 2.1 Introduction
- 2.2 Solvent Properties of Water
- 2.3 Separation Techniques Utilizing Water
- 2.4 Recent Applications in Extraction
- 2.5 Recent Applications Carried out by High-Temperature Chromatography
- 2.6 Conclusions and Future Trends
- References
Chapter 3. A Systematic Approach to Green Solvent Selection, Design, and Verification
- Abstract
- 3.1 Introduction
- 3.2 Solvent Selection and Design
- 3.3 Application
- 3.4 Conclusions
- References
Chapter 4. Bio-Based Molecular Solvents
- Abstract
- 4.1 Introduction to Bio-Based Solvents and Solvent Extraction
- 4.2 Bio-Based Solvent Drivers
- 4.3 Selecting Solvents for Solvent Extraction Applications
- 4.4 Bio-Based Solvents
- 4.5 Conclusions
- References
Chapter 5. Supramolecular Solvents for Green Chemistry
- Abstract
- 5.1 Introduction
- 5.2 Synthesis of Supramolecular Solvents
- 5.3 Tailoring Composition and Nanostructure of Supramolecular Solvents
- 5.4 Solubilization of Solutes in Supramolecular Solvents
- 5.5 Applications
- 5.6 Conclusions
- Acknowledgments
- References
Chapter 6. Ionic Liquids, Switchable Solvents, and Eutectic Mixtures
- Abstract
- 6.1 Motivation for Research in Neoteric Solvents: Ionic Liquids, Switchable Solvents, and Deep Eutectic Solvents
- 6.2 Recent Trends in Using ILs for Separation Processes
- 6.3 Recent Trends in Using DESs for Separation Processes
- 6.4 Recent Trends in Using Switchable Solvents for Separation Processes
- 6.5 Concluding Remarks
- References
Chapter 7. Supercritical Fluids and Gas-Expanded Liquids
- Abstract
- 7.1 Introduction
- 7.2 Physicochemical Properties of SCFs
- 7.3 Physicochemical Properties of GXLs
- 7.4 Phase Equilibria and Phase Diagrams
- 7.5 Solubility of Compounds in SCFs and GXLs
- 7.6 Experimental Procedures
- 7.7 Examples of Applications
- 7.8 Greenness of SCFs and GXLs
- 7.9 Conclusions
- List of abbreviations
- Acknowledgments
- References
Section III: Green Extraction Techniques
Chapter 8. Green-Membrane Extraction
- Abstract
- 8.1 Lead-in
- 8.2 Green-Membrane Classification
- 8.3 Porous Membrane Extractions
- 8.4 Nonporous Membrane Extractions
- 8.5 Conclusions
- Acknowledgments
- References
Chapter 9. Microwaves for Greener Extraction
- Abstract
- 9.1 Introduction
- 9.2 Types of Microwave Systems
- 9.3 Experimental Variables Affecting Microwave-Assisted Extraction
- 9.4 Green Aspects of Microwave-Assisted Extraction
- 9.5 Standardized Procedures Using Microwave-Accelerated Extraction Techniques
- 9.6 Selected Applications Using Microwaves
- 9.7 Conclusions
- Acknowledgments
- References
Chapter 10. Ultrasound-Assisted Extraction
- Abstract
- 10.1 Introduction
- 10.2 Ultrasound Principles
- 10.3 Kinetics of Ultrasound-Assisted Extraction
- 10.4 Typical Ultrasound Devices Used in Analytical Laboratories
- 10.5 Application of UAE
- 10.6 Conclusion
- References
Chapter 11. Environmentally Benign Supercritical Fluid Extraction
- Abstract
- 11.1 Introduction
- 11.2 Supercritical Fluid Extraction Technology
- 11.3 Process and Natural Products Improvements Based on SFE Technology
- 11.4 Prospective Applications of Supercritical Fluids at Industrial Scale
- 11.5 Final Remarks
- Acknowledgments
- References
Chapter 12. Surfactant-Mediated Extraction Techniques
- Abstract
- 12.1 Introduction
- 12.2 Cloud point and Coacervate Extraction
- 12.3 Combination of Surfactants With Other Techniques and Substances
- 12.4 Nonanalytical Application of Surfactants
- 12.5 Conclusions
- References
Section IV: Green Sampling and Sample Preparation Techniques
Chapter 13. Green Sample Collection
- Abstract
- 13.1 Introduction
- 13.2 Green Sample Collection Techniques in Air Quality Monitoring
- 13.3 Application of Green Sampling Techniques in the Field of Aquatic Medium Quality Monitoring
- Acknowledgment
- References
Chapter 14. Microextraction and Solventless Techniques
- Abstract
- 14.1 Introduction
- 14.2 Sorption-Based Microextraction Techniques
- 14.3 LPME Techniques
- 14.4 Conclusion
- References
Section V: Green Analytical Separations
Chapter 15. Green Gas and Liquid Capillary Chromatography
- Abstract
- 15.1 Introduction
- 15.2 Green Aspects of Liquid Chromatography
- 15.3 Green Aspects of Gas Chromatography
- 15.4 Conclusions
- References
Chapter 16. Supercritical Fluid Chromatography
- Abstract
- 16.1 Introduction
- 16.2 Supercritical Fluid Carbon Dioxide as Potent Green Solvent
- 16.3 Supercritical Fluid Chromatography as a New Approach in “Omics” Technology
- 16.4 The Evolution of SFC Technology
- 16.5 Detector and Ionization Mode in SFC
- 16.6 Supercritical Fluid Chromatography/Mass Spectrometry
- 16.7 Application of Supercritical Fluid Chromatography
- 16.8 Conclusions and Future Perspective
- References
Chapter 17. Capillary Electrophoresis as a Green Alternative Separation Technique
- Abstract
- 17.1 Chromatographic and Electrokinetic Separations
- 17.2 The Greenness of CE
- 17.3 Conclusion
- Acknowledgment
- References
Product details
- No. of pages: 560
- Language: English
- Copyright: © Elsevier 2017
- Published: February 28, 2017
- Imprint: Elsevier
- Paperback ISBN: 9780128052976
- eBook ISBN: 9780128054437
About the Editors
Francisco Pena-Pereira
Affiliations and Expertise
Marek Tobiszewski
Affiliations and Expertise
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