Description

A vast range of different functional groups is potentially available from the attachment of three or four heteroatoms to carbon. Some of these are abundantly represented in the literature, others are rare, and many have yet to be described. The aim of this volume is to describe the synthesis of examples of known functional groups and to highlight those that are little known or unknown. All possible combinations of heteroatoms have been surveyed, with the exception of complexes in which carbon atoms are bonded only to transition elements. The material is organised in four parts: tetracoordinated carbon atoms bearing three attached heteroatoms are covered in Part 1, and those bearing four heteroatoms in Part II; the synthesis of tricoordinated carbon atoms with three attached heteroatoms is described in Part III; stabilized radicals and carbocations with three attached heteroatoms are covered briefly in Part IV.

Table of Contents

Trihalides (R.D. Chambers, J. Hutchinson). Functions containing halogens and any other elements (G.B. Jones). Functions containing three chalcogens (and no halogens) (G. Mitchell). Functions containing a chalcogen and any other heteroatoms other than a halogen (M.J. Rice). Functions containing at least one group V element (and no halogen or chalcogen) (D.P.J. Pearson). Functions containing at least one metalloid (Si, Ge, or B) and no halogen, chalogen or group V element; also functions containing three metals (V. Ramanenko). Functions containing four halogens, or three halogens and one other heteroatom substituent (A. Senning, A.H. Gouliaev). Functions containing two halogens and two other heteroatom substituents (A. Varvoglis). Functions containing one halogen and three other heteroatom substituents (P. Savignac, A. Marinetti). Functions containing four or three chalcogens and no halogens (A. Senning, A.H. Gouliaev). Functions containing two or one chalcogen (and no halogens) (W. Petz, F. Weller). Functions containing at least one group V element (and no halogen or chalcogen) (Ph. Savignac, D. Carmichal, A. Marinetti). Functions containing at least one metalloid (Si,Ge or B) and no halogen, chalcogen or group V element; also functions containing four metals (P.D. Lickiss). Functions containing a carbonyl group and at least one halogen (G.E. Gymer, S. Narayanaswami). Functions containing a carbonyl group and at least One chalcogen (but no halogen) (H. Eckert). Functions containing a carbonyl group and two heteroatoms other than a halogen or chalcogen (A.F. Hegarty). Functions containing a thiocarbonyl group and at least Oone halogen; also at least one chalcogen and no halogen (K. Pihlaja, E. Kleinpeter). Functions containing a thiocarbonyl group bear

Details

Language:
English
Copyright:
© 1995
Published:
Imprint:
Pergamon
Print ISBN:
9780080427041
Electronic ISBN:
9780080912813