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Survey of Progress in Chemistry
Volume 1
1st Edition, Volume 1 - January 1, 1963
Editor: Arthur F. Scott
Language: English
eBook ISBN:9781483225067
9 7 8 - 1 - 4 8 3 2 - 2 5 0 6 - 7
Survey of Progress in Chemistry, Volume 1 explores the principles common to all chemistry that undergo major developments and modifications, including high-temperature reactions,…Read more
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Survey of Progress in Chemistry, Volume 1 explores the principles common to all chemistry that undergo major developments and modifications, including high-temperature reactions, chemical valence, metallocenes, and redox reactions. This volume is divided into seven chapters, and begins with the presentation of some analytical methods as research tools in chemistry. The next chapters deal with the thermodynamic generalization of high-temperature reactions; molecular structural studies that are incompatible with the Lewis theory; and the general chemical aspects of metallocenes. These topics are followed by discussions on the significance of oxidation-reaction mechanisms in organic chemistry and some remarkable chemical processes occurring in the living systems. The last chapter describes the structure and reaction mechanisms of Grignard reagent. This book is of value to chemistry teachers and students.
List of Contributors
Preface
New Research Tools of Chemists
I. Introduction
II. Magnetic Resonance Methods
III. Mass Spectrometry
IV. Diffraction Methods
V. Spectroscopic Methods
VI. Optical Rotatory Dispersion
References
High-Temperature Reactions
I. Introduction
II. Factors That Determine Equilibrium Reaction Products
III. The Displacement of a Metal From Compounds by a Second Metal
IV. Displacement of One Nonmetal by a Second Nonmetal
V. Conclusion
References
The Implications of Some Recent Structures for Chemical Valence Theory
I. Introduction
II. The Rare Gas Rule and Valence Orbitals
III. Outer D-Orbital Compounds
IV. Summary
References
Metallocenes
I. Introduction
II. Ferrocene
III. Other Metallocenes
References
Oxidation-Reduction Mechanisms in Organic Chemistry
I. Introduction
II. General Methods of Investigating Oxidation-Reduction Reactions
III. Ester Mechanisms
IV. Hydride Transfer Mechanisms
V. Hydrogen Atom Abstraction Mechanisms
VI. Electron Abstraction Mechanisms
VII. Displacement Mechanisms
VIII. Addition-Elimination Mechanisms
IX. Conclusion
References
The Chemistry of Biological Energy Transfer
I. Introduction
II. Terminology and Some Examples
III. The Source of Useful Energy in Biological Systems
IV. Group Transfer Reactions
V. Utilizations of Chemical Energy
VI. Future Developments
References
The Structure of the Grignard Reagent and the Mechanisms of Its Reactions
I. Structure of the Grignard Reagent
II. Mechanisms of Grignard Reactions
References
Author Index
Subject Index
No. of pages: 352
Language: English
Edition: 1
Volume: 1
Published: January 1, 1963
Imprint: Academic Press
eBook ISBN: 9781483225067
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