Structure of Molecules and Internal Rotation
1st Edition
Secure Checkout
Personal information is secured with SSL technology.Free Shipping
Free global shippingNo minimum order.
Description
Structure of Molecules and Internal Rotation focuses on the processes, methodologies, and reactions involved in internal rotation.
The manuscript first offers information on studies on dihalogenoethanes, as well as the spectroscopic and thermal measurements of ethane and its derivatives. Discussions focus on the dielectric constant of halogenoethanes, electron diffraction, Raman effect in ethane derivatives, and entropy difference between rotational isomers. The text also ponders on internal rotation in simple molecules and paraffinic hydrocarbons.
The publication examines polypeptides and related compounds and the principles and experimental methods of structure determination. Topics include Raman effect, infrared absorption, molecules with two peptide bonds, and the configuration of a polypeptide chain.
The manuscript is a valuable source of data for chemists and readers interested in the structure of molecules and internal rotation.
Table of Contents
Contents
Part I
Preface
Chapter I. Introduction and Earlier Investigations
1. Introduction
2. Earlier Studies on Dihalogenoethanes
3. Some Other Earlier Dipole Investigations
Chapter II. Ethane and its Derivatives I (Spectroscopic and Electric Measurements)
4. The Raman Effect in Ethane Derivatives
5. Infrared Absorption of Ethane Derivatives
6. Dielectric Constant of Halogenoethanes
7. Energy Difference between the Rotational Isomers
8. Electron Diffraction
Chapter III. Ethane and its Derivatives II (Thermal Measurements and General Discussion)
9. Entropy of 1.2-Dihalogenoethanes
10. The Potential Barrier to Internal Rotation
11. Internal Hydrogen Bond. Entropy Difference Between the Rotational Isomers
12. The Nature of the Hindering Potential
Chapter IV. Internal Rotation in Other Simple Molecules
13. Other Simple Molecules with C-C Axes
14. Cyclic Compounds
15. Internal Rotation about the C-O Axis
16. Internal Rotation about O-O, S-S and Si-Si Bonds as Axes
Chapter V. Paraffinic Hydrocarbons
17. Internal Rotation in Butane, Pentane and Hexane
18. Internal Rotation in Long Chain n-Paraffins
19. Skeletal Vibrations of n-Paraffins
Chapter VI. Polypeptides and related compounds
20. Molecules with One Peptide Bond
21. Molecules with Two Peptide Bonds
22. Diketopiperazine and Amino Acids
23. The Configuration of a Polypeptide Chain
Part II
Chapter I. Principles and Experimental Methods of Structure Determination
1. Infrared Absorption
2. The Raman Effect
3. Dielectric Constant
4. Electron Diffraction
Chapter II. Normal Vibrations
5. Normal Vibrations
6. Normal Vibrations of the 1,2-Dihalogenoethanes
7. Normal Vibrations of n-Paraffins
8. The Sum Rule and the Product Rule for Rotational Isomers
9. Assignment of the Raman and Infrared Frequencies of 1,2-Dichloroethane
Author Index
Subject Index
Details
- No. of pages:
- 256
- Language:
- English
- Copyright:
- © Academic Press 1954
- Published:
- 1st January 1954
- Imprint:
- Academic Press
- eBook ISBN:
- 9781483261645
About the Author
San-Ichiro Mizushima
About the Editor
Eric Hutchinson
Ratings and Reviews
Request Quote
Tax Exemption
Elsevier.com visitor survey
We are always looking for ways to improve customer experience on Elsevier.com.
We would like to ask you for a moment of your time to fill in a short questionnaire, at the end of your visit.
If you decide to participate, a new browser tab will open so you can complete the survey after you have completed your visit to this website.
Thanks in advance for your time.