Ring-Forming Polymerizations Pt B 2

Ring-forming Polymerizations is a part of a volume that features a complete review and compilation of ring-forming polymerization reactions that result to heterocyclic ring formation. This book shows relevant growth in terms of research and commercial development in the area of polymer chemistry. This volume is comprised of four major chapters and is organized according to the specific heterocyclic ring structure resulting from ring-forming polymerizations. Each of the chapters is arranged further according to the polymer type and the different methods used in the preparation of that type, where emphasis is given to synthetic methods. This book specifically discusses the linear polymers that were intentionally made. Also, the structures presented are limited in scope considering that they are the result of the research cited in this book. However, claims that dispute a certain structure found in the research are also included to provide balance, fairness, and objectivity. Specifically, this book is a valuable resource for polymer and organic chemists. However, it can also be of great use to those scientists and researchers interested in the study of polymer chemistry of living systems.

PrefaceContents of Part AContents of Part B, 1IntroductionChapter I. Rings Containing Four Carbon Atoms A. Polyimides Polyimide Homopolymers Method 1. Thermal Dehydration of Polyamic Acids Method 2. Chemical Dehydration of Polyamic Acids Method 3. Polyimides via Intermediate Polyiminolactones Method 4. Polyimides from Diamines and Tetranitriles Method 5. Polyimides from Diisocyanates and Dianhydrides Method 6. Miscellaneous Polyimide Syntheses Properties Applications Poly(Amide-Imides) Method 7. Thermal Dehydration of Polyamic Acids Method 8. Chemical Dehydration of Polyamic Acids Method 9. Polymerization of Trimellitic Anhydride with Diisocyanates Properties and Applications Poly(Ester-Imides) Method 10. Thermal Dehydration of Polyamic Acids Method 11. Poly(Ester-Imides) from Dianhydrides and Diisocyanates Method 12. Poly(Ester-Imides) from Trimellitic Anhydride and Diamines and Diols Properties of Poly(Ester-Imides) Poly(Imide-Imidazopyrrolones) Method 13. Thermal Dehydration of Polyamic Acids Method 14. Polymerization in Polyphosphoric Acid Polytriazololactams Method 15. Thermal Dehydration of Appropriate Polyamic Acids Oxadiazole Copolymers Method 16. Thermal Dehydration of Polyamic Acids to Give Copolymers Containing the 1,3,4-Oxadiazole Ring Method 17. Thermal Dehydration of Polyamic Acids to Give Copolymers Containing the 1,2,4-Oxadiazole Ring Polyiminolactones Method 18. Chemical Dehydration of Polyamic Acids Chemical Reactions of Polyiminolactones B. Polymers Containing Pyrrole and Related Rings Method 1. Polyteracyanoethylene Method 2. Polyphthalocyanines Method 3. Polymerization of Multifunctional Nitriles and Amines Method 4. Polypyrrolines from Diamines Method 5. Polypyrollinones C. Poly(1,3-Oxazinones) and Poly(1,3-Oxazindiones) Method 1. Poly(1,3-Oxazinones) from o-Amino Aromatic Carboxylic Acids Method 2. Poly(1,3-Oxazindiones) from Diisocyanates and Bis(Hydroxy Acids) Method 3. Poly(1,3-oxazindiones) from Carbonate-Blocked Bis(Hydroxy Acids) and Diamines D. Polydioxins, Polyoxazines, and Polythiazines Method 1. Polydioxins from Tetraphenols and Tetrachloroquinoxalines Method 2. Polyoxazines and Polythiazines from Diaminodiphenols and Tetrachloro or TetrahydroxyCompounds Method 3. Polyoxazines and Polythiazines from Diaminodiphenols and Quinones Method 4. Condensation of Diaminodithiophenols with Bis-(α-Haloalkyl Aryl Ketones) E. Polyquinoxalines and Related Types Method 1. Pyrazine Ring-Containing Polymers Method 2. Polyquinoxalines from Bis(o-Diamines) and Tetracarbonyl Compounds Method 3. Polyquinoxalines by Polycondensation in Polyphosphoric Acid Properties of Polyquinoxalines F. Polypiperazines and Polydiketopiperazines Method 1. Polypiperazines from Bis(β-Hydroxyethyl)Diamines Method 2. Polymerization of Bis(α-Amino Acids) to Polydiketopiperazines Method 3. Polydiketopiperazines from Bis(α-Chloroacetamides) G. Polypyrimidines and Polytetraazapyrenes Method 1. Polypyrimidine Syntheses Method 2. Polytetraazapyrene Synthesis H. Polypyrimidones, Polyquinazolones, and Polyquinazolinediones Method 1. Polypyrimidones from Unsaturated Isocyanates Method 2. Polyquinazolones from Diamines and Bis(benzoxazinones) Method 3. Polyquinazolones from Aromatic Bis(o-Amino Acids) and Derivatives Method 4. Polyquinazolinediones by Condensation of Diisocyanates with Aromatic Bis(o-Amino Acids) Method 5. Poly(isoindoloquinazolinediones) from Condensation of Aromatic Bis(o-Aminoamides) withDianhydrides Properties of Polyquinazolones and Polyquinazolinediones I. Polyacetals and Polyketals Method 1. Condensation of Polyols with Dialdehydes and Diketones Method 2. Polyacetals by Transacetalization Miscellaneous Related Syntheses Properties of Polyacetals and Polyketals J. Polyquinones Method 1. Polyquinones from Halo-Substituted p-Quinones Table I.1. Polyimides from Aliphatic and Cycloaliphatic Dianhydrides Table I.2. Polyimides from Multicyclic Dianhydrides Table I.3. Polypyromellitimides Table I.4. Polyimides Based on 3,3',4,4'-Benzophenonetetracarboxylic Acid Dianhydride Table I.5. Miscellaneous Polyimides Table I.6. Poly(amide-imides) from Diamino Amides Table I.7. Poly(amide-imides) from Tricarboxylic Acid Derivatives Table I.8. Poly(amide-imides) from Amide Anhydrides Table I.9. Poly(ester-imides) from Ester Anhydrides Table I.10. Poly(ester-imides) from Diamino Esters Table I.11. Poly(ester-imides) from Dimethyl Bis(trimellitimidates) Table I.12. Polyiminolactones Table I.13. Poly(imide-imidazopyrrolones) Table I.14. Polymers Containing Pyrrole and Related Rings Table I.15. Poly(1,3-oxazinones) and Poly(1,3-oxazindiones) Table I.16. Polydioxins Table I.17. Polyoxazines Table I.18. Polythiazines Table I.19. Polyquinoxalines and Related Polymers Table I.20. Polypiperazines and Polydiketopiperazines Table I.21. Polypyrimidines and Polytetraazopyrenes Table I.22. Polyquinazolones Table I.23. Polyquinazolinediones Table I.24. Polyacetals and Polyketals Table I.25. Polyquinones ReferencesChapter II. Intra-Intermolecular Polymerizations Leading to Heterocyclic Rings A. Polymerization of Dialdehydes Method 1. Free-Radical Initiation Method 2. Ziegler Initiation Method 3. Cationic Initiation Method 4. Anionic Initiation B. Polymerization of Diepoxides Method 1. Free-Radical Initiation Method 3. Cationic Initiation Method 4. Anionic Initiation C. Polymerization of Divinyl Acetals and Ketals Method 1. Free-Radical Initiation Method 2. Ziegler Initiation Method 3. Cationic Initiation D. Polymerization of Unsaturated Esters Polymerizations of Unsaturated Glycidyl Esters Method 3. Cationic Initiation Method 4. Anionic Initiation Polymerization of Diunsaturated Esters Method 1. Free-Radical Initiation E. Polymerization of Diunsaturated Anhydrides Method 1. Free-Radical Initiation Method 4. Anionic Initiation F. Polymerization of Diunsaturated Germanium Derivatives Method 2. Ziegler Initiation G. Polymerization of Diunsaturated Ammonium Salts, Amine Oxides, and Amines Method 1. Free-Radical Initiation H. Polymerization of Diunsaturated Amides Method 1. Free-Radical Initiation Method 4. Anionic Initiation I. Polymerization of Diisocyanates Method 1. Free-Radical Initiation Method 4. Anionic Initiation J. Polymerization of Dinitriles Method 1. Free-Radical Initiation Method 2. Ziegler Initiation, Miscellany K. Polymerization of Diunsaturated Phosphorus-Containing Compounds Method 1. Free-Radical Initiation Method 4. Anionic Initiation L. Polymerization of Diunsaturated Sulfur-Containing Compounds Method 1. Free-Radical Initiation Method 2. Ziegler Initiation Method 3. Cationic Initiation M. Polymerization of Diunsaturated Silicon Derivatives Method 1. Free-Radical Initiation Method 2. Ziegler Initiation Method 3. Cationic Initiation Method 4. Anionic Initiation N. Miscellaneous Polymerizations Method 1. Free-Radical Initiation Method 2. Ziegler Initiation Table II.1. Polydialdehydes Table II.2. Polydiepoxides Table II.3. Poly(divinyl acetals) and Poly(divinyl ketals) Table II.4. Polymers from Unsaturated Glycidyl Esters Table II.5. Polymers from Diunsaturated Esters Table II.6. Polymers from Diunsaturated Anhydrides Table II.7. Polymers from Polyunsaturated Ammonium Salts and Amine Oxides Table II.8. Copolymers from Diunsaturated Ammonium Salts and Sulfur Dioxide Table II.9. Polymers from Diunsaturated Amines Table II.10. Polymers from Diunsaturated Amides Table II.11. Cyclopolymers from Diisocyanates and Diisothiocyanates Table II.12. Cyclopolymers from Dinitriles Table II.13. Phosphorous-Containing Cyclopolymers Table II.14. Sulfur-Containing Cyclopolymers Table II.15. Silicon-Containing Cyclopolymers Table II.16. Miscellaneous Cyclopolymers ReferencesChapter III. α,β-Unsaturated Aldehyde Polymerizations A. Acrolein Polymers Polymerizations Properties Structure Copolymers B. Polymers from α-Substituted Acroleins C. Polymerization of β-Substituted Acroleins D. Miscellaneous Polymers Table III.1. Initiator Systems for Acrolein Polymerization Table III.2. Properties of Various Polyacroleins Table III.3. Polymerization of α-Alkyl Acroleins ReferencesChapter IV. Miscellaneous Ring-Forming Polymerizations A. Polydiazadiphosphetidines B. Polytetrazadiborines C. Polytetrazoles D. Polybenzboroxazinones E. Polysulfimides and Related Polymers F. Poly(4-Phosphoniapyran Salts) G. Poly(amide-indoles) H. Polyxanthones I. Copolymerization of 1,4-Butynediol with Acrolein J. Polymerizations to Fused Pyridine Ring-Containing Polymers K. Polydiazepines L. Polydisalicylides M. Polyferrocenes and Polytitanocenes N. Miscellaneous Polymerizations ReferencesSupplementary Reference ListSupplementary Reference List for Part AAuthor IndexSubject Index

Heterocyclic Rings

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