Redistribution Reactions - 1st Edition - ISBN: 9780124544505, 9780323160483

Redistribution Reactions

1st Edition

Authors: J.C. Lockhart
eBook ISBN: 9780323160483
Imprint: Academic Press
Published Date: 1st January 1970
Page Count: 188
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Description

Redistribution Reactions is a comprehensive coverage of redistribution phenomena for the entire Periodic Table. This book is organized into two sections encompassing 10 chapters that tackle the concepts of structural reorganization.
Part I provides first an overview of redistribution reactions, followed by a discussion on a series of techniques capable of detecting all compounds in a redistribution reaction, including electronic, vibrational, and nuclear magnetic spectroscopy, X-ray crystallography, mass spectroscopy, polarography, chromatography, and the use of phase diagram. Part II is devoted to the redistribution reactions of the elements under Periodic Group headings with available kinetics or thermodynamics information. This part also presents valuable structural information of the group elements, such as their vibrational frequencies and chemical shifts.
This work will be of convenient reference for researchers already working on redistribution and for a more general range of research workers in inorganic chemistry who require information on scrambling for a specific element.

Table of Contents


Preface

Conversion Table

Part I

1. Introduction

References

2. Experimental Techniques

I. Spectroscopy

II. X-Ray Crystallography

III. Mass Spectrometry

IV. Polarography

V. Gas Chromatography

VI. Phase Diagrams

VII. Use of Labels

References

Part II

3. Group I

I. Lithium Alkyls, Aryls, and Silyls

II. Alkali β-Diketonates

4. Group II

I. Beryllium

II. Magnesium

III. Zinc

IV. Cadmium

V. Mercury

VI. Exchange of Mixtures of Group II and Other Elements

References

5. Transition Metals

I. Carbonyls

II. Dithiolates, Salicylaldiminates, and Aminotroponiminates

III. β-Diketonates

IV. Miscellaneous Ligands

References

6. Group III

I. Boron

II. Aluminum

III. Gallium, Indium, and Thallium

References

7. Group IV

I. Silicon

II. Germanium

III. Tin

IV. Scrambling between Group IV and Other Central Atoms

References

8. Group V

I. Phosphorus

II. Arsenic

III. Nitrogen, Antimony, and Bismuth

References

9. Group VI

I. Sulfur

II. Selenium, Tellurium, Polonium, and Mixtures

10. Trends in Redistribution Reactions

Spinoff

References

Author Index

Subject Index

Details

No. of pages:
188
Language:
English
Copyright:
© Academic Press 1970
Published:
Imprint:
Academic Press
eBook ISBN:
9780323160483

About the Author

J.C. Lockhart