Redistribution Reactions

Redistribution Reactions

1st Edition - January 1, 1970

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  • Author: J.C. Lockhart
  • eBook ISBN: 9780323160483

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Redistribution Reactions is a comprehensive coverage of redistribution phenomena for the entire Periodic Table. This book is organized into two sections encompassing 10 chapters that tackle the concepts of structural reorganization. Part I provides first an overview of redistribution reactions, followed by a discussion on a series of techniques capable of detecting all compounds in a redistribution reaction, including electronic, vibrational, and nuclear magnetic spectroscopy, X-ray crystallography, mass spectroscopy, polarography, chromatography, and the use of phase diagram. Part II is devoted to the redistribution reactions of the elements under Periodic Group headings with available kinetics or thermodynamics information. This part also presents valuable structural information of the group elements, such as their vibrational frequencies and chemical shifts. This work will be of convenient reference for researchers already working on redistribution and for a more general range of research workers in inorganic chemistry who require information on scrambling for a specific element.

Table of Contents

  • Preface

    Conversion Table

    Part I

    1. Introduction


    2. Experimental Techniques

    I. Spectroscopy

    II. X-Ray Crystallography

    III. Mass Spectrometry

    IV. Polarography

    V. Gas Chromatography

    VI. Phase Diagrams

    VII. Use of Labels


    Part II

    3. Group I

    I. Lithium Alkyls, Aryls, and Silyls

    II. Alkali β-Diketonates

    4. Group II

    I. Beryllium

    II. Magnesium

    III. Zinc

    IV. Cadmium

    V. Mercury

    VI. Exchange of Mixtures of Group II and Other Elements


    5. Transition Metals

    I. Carbonyls

    II. Dithiolates, Salicylaldiminates, and Aminotroponiminates

    III. β-Diketonates

    IV. Miscellaneous Ligands


    6. Group III

    I. Boron

    II. Aluminum

    III. Gallium, Indium, and Thallium


    7. Group IV

    I. Silicon

    II. Germanium

    III. Tin

    IV. Scrambling between Group IV and Other Central Atoms


    8. Group V

    I. Phosphorus

    II. Arsenic

    III. Nitrogen, Antimony, and Bismuth


    9. Group VI

    I. Sulfur

    II. Selenium, Tellurium, Polonium, and Mixtures

    10. Trends in Redistribution Reactions



    Author Index

    Subject Index

Product details

  • No. of pages: 188
  • Language: English
  • Copyright: © Academic Press 1970
  • Published: January 1, 1970
  • Imprint: Academic Press
  • eBook ISBN: 9780323160483

About the Author

J.C. Lockhart

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